| R32 | 24 |  Fernando GonzalezClay | 100 | Paul CapdevilleClay | 7-5 6-3 | 3 | 75 | 5 | 2 | 66.7% | 73.7% | 47.4% | 1/4 |
| R32 | 102 |  Diego HartfieldClay | 118 | Mariano ZabaletaClay | 6-3 7-5 | 3 | 91 | 2 | 4 | 64.8% | 69.6% | 52.0% | 5/7 |
| R32 | 78 | Carlos BerlocqClay | 108 |  Nicolas DevilderClay | 7-5 6-2 | 3 | 128 | 5 | 2 | 47.0% | 80.6% | 54.3% | 3/4 |
| R32 | 76 |  Luis HornaClay | 41 | Agustin CalleriClay | 6-4 6-4 | 3 | 82 | 2 | 2 | 71.9% | 85.4% | 56.3% | 4/4 |
| R32 | 29 |  Fernando VerdascoClay | 734 | Hans Podlipnik-CastilloClay | 6-4 6-3 | 3 | 82 | 6 | 0 | 66.7% | 75.0% | 62.5% | 1/2 |
| R32 | 111 |  Pablo CuevasClay | - | Guillermo CoriaClay | 6-4 4-6 6-3 | 3 | 124 | 4 | 2 | 58.9% | 66.0% | 45.9% | 5/9 |
| R32 | 167 | Daniel Gimeno-TraverClay | 160 | Eduardo SchwankClay | 6-4 1-6 6-1 | 3 | 79 | 4 | 0 | 67.3% | 73.0% | 77.8% | 0/2 |
| R32 | 58 | Jose AcasusoClay | 84 |  Peter LuczakClay | 6-2 6-4 | 3 | 86 | 6 | 2 | 45.0% | 92.6% | 54.5% | 4/4 |
| R32 | 106 | Juan Pablo BrzezickiClay | 52 | Oscar HernandezClay | 7-6(4) 6-1 | 3 | 123 | 1 | 3 | 63.2% | 55.8% | 60.0% | 2/6 |
| R32 | 125 | Marcel GranollersClay | 96 |  Boris PashanskiClay | 7-6(4) 6-2 | 3 | 104 | 7 | 2 | 64.1% | 82.9% | 43.5% | 3/4 |
| R32 | 86 | Martin Vassallo ArguelloClay | 105 | Olivier PatienceClay | 6-4 6-1 | 3 | 73 | 1 | 1 | 72.9% | 80.0% | 53.8% | 1/1 |
| R32 | 21 | Juan MonacoClay | 113 |  Nicolas LapenttiClay | 2-6 6-3 6-4 | 3 | 153 | 6 | 1 | 70.6% | 62.5% | 56.7% | 9/12 |
| R32 | 72 | Sergio RoitmanClay | 70 | Nicolas MassuClay | 6-7(3) 7-6(4) 6-3 | 3 | 199 | 3 | 1 | 57.0% | 66.7% | 53.8% | 9/13 |
| R32 | 88 | Santiago VenturaClay | 183 | Gaston GaudioClay | 6-3 6-0 | 3 | 66 | 9 | 3 | 44.4% | 87.5% | 43.3% | 3/5 |
| R32 | 289 | David MarreroClay | 213 | Adrian GarciaClay | 6-7(2) 7-6(3) 6-4 | 3 | 172 | 11 | 5 | 65.5% | 68.9% | 64.1% | 3/4 |
| R32 | 104 |  Fabio FogniniClay | 25 | Juan Ignacio ChelaClay | 7-6(0) 6-2 | 3 | 86 | 3 | 0 | 54.1% | 78.8% | 71.4% | 2/2 |
| R16 | 24 | Fernando GonzalezClay | 102 | Diego HartfieldClay | 6-3 6-4 | 3 | 67 | 6 | 6 | 59.4% | 76.3% | 46.2% | 2/4 |
| R16 | 78 | Carlos BerlocqClay | 76 | Luis HornaClay | 7-6(3) 3-6 7-6(3) | 3 | 184 | 12 | 2 | 52.7% | 70.7% | 59.6% | 4/8 |
| R16 | 111 | Pablo CuevasClay | 29 | Fernando VerdascoClay | 7-5 6-3 | 3 | 87 | 4 | 1 | 61.3% | 71.7% | 65.5% | 6/6 |
| R16 | 58 | Jose AcasusoClay | 167 | Daniel Gimeno-TraverClay | 6-2 6-2 | 3 | 60 | 1 | 0 | 75.6% | 83.9% | 60.0% | 0/0 |
| R16 | 106 | Juan Pablo BrzezickiClay | 125 | Marcel GranollersClay | 6-2 6-2 | 3 | 88 | 1 | 0 | 59.2% | 79.3% | 60.0% | 1/1 |
| R16 | 21 | Juan MonacoClay | 86 | Martin Vassallo ArguelloClay | 6-3 4-6 7-5 | 3 | 165 | 7 | 2 | 60.4% | 70.3% | 50.0% | 9/12 |
| R16 | 88 | Santiago VenturaClay | 72 | Sergio RoitmanClay | 4-6 6-3 7-6(4) | 3 | 138 | 2 | 6 | 50.5% | 69.4% | 37.5% | 8/15 |
| R16 | 104 | Fabio FogniniClay | 289 | David MarreroClay | 6-4 6-7(5) 6-3 | 3 | 132 | 9 | 4 | 50.0% | 78.8% | 59.6% | 7/8 |
| QF | 24 | Fernando GonzalezClay | 78 | Carlos BerlocqClay | 7-5 6-0 | 3 | 83 | 4 | 1 | 64.9% | 70.3% | 70.0% | 3/3 |
| QF | 111 | Pablo CuevasClay | 58 | Jose AcasusoClay | 6-3 6-3 | 3 | 91 | 5 | 2 | 63.4% | 71.1% | 46.2% | 3/4 |
| QF | 21 | Juan MonacoClay | 106 | Juan Pablo BrzezickiClay | 6-2 6-3 | 3 | 84 | 3 | 0 | 50.9% | 81.5% | 53.8% | 1/2 |
| QF | 88 | Santiago VenturaClay | 104 | Fabio FogniniClay | 6-3 6-3 | 3 | 80 | 6 | 1 | 57.7% | 80.0% | 63.6% | 1/1 |
| SF | 24 | Fernando GonzalezClay | 111 | Pablo CuevasClay | 6-7(4) 7-6(6) 6-2 | 3 | 168 | 10 | 2 | 57.0% | 72.1% | 56.5% | 7/10 |
| SF | 21 | Juan MonacoClay | 88 | Santiago VenturaClay | 6-2 6-4 | 3 | 75 | 1 | 1 | 63.5% | 69.7% | 63.2% | 2/3 |
| F | 24 | Fernando GonzalezClay | 21 | Juan MonacoClay | W/O | 3 | - | 1 | 1 | 63.5% | 69.7% | 63.2% | 2/3 |
