| R32 | 8 |  Gaston GaudioClay | 385 |  Felipe ParadaClay | 6-1 6-4 | 3 | 70 | 8 | 0 | 58.7% | 81.5% | 78.9% | 0/0 |
| R32 | 106 |  Ruben Ramirez HidalgoClay | 103 | Nicolas AlmagroClay | 0-6 6-3 6-1 | 3 | 93 | 4 | 1 | 57.4% | 82.1% | 41.4% | 5/8 |
| R32 | 164 | Santiago VenturaClay | 135 | Paul CapdevilleClay | 6-3 0-6 6-3 | 3 | 101 | 1 | 1 | 62.3% | 58.1% | 57.7% | 6/10 |
| R32 | 75 | Albert MontanesClay | 79 | Juan MonacoClay | 6-4 6-2 | 3 | 104 | 0 | 0 | 63.2% | 61.1% | 61.9% | 5/7 |
| R32 | 46 | Jose AcasusoClay | 131 | Ivan NavarroClay | 6-3 6-2 | 3 | 76 | 4 | 1 | 41.8% | 82.6% | 56.3% | 0/1 |
| R32 | 486 | Gustavo MarcaccioClay | 70 |  Luis HornaClay | 7-6(6) 0-6 6-3 | 3 | 128 | 9 | 4 | 59.0% | 69.5% | 48.8% | 10/14 |
| R32 | 397 | Jorge AguilarClay | 621 | Guillermo HormazabalClay | 6-4 6-2 | 3 | 66 | 0 | 3 | 67.9% | 68.4% | 77.8% | 0/0 |
| R32 | - |  Leos FriedlClay | 80 | Carlos BerlocqClay | 6-7(5) 6-3 6-1 | 3 | 164 | 1 | 3 | 64.4% | 60.3% | 46.9% | 1/5 |
| R32 | 69 | Nicolas MassuClay | 94 |  Marcos DanielClay | 6-3 6-3 | 3 | 72 | 5 | 1 | 65.6% | 70.0% | 47.6% | 0/1 |
| R32 | 111 |  Juan Antonio MarinClay | 178 |  Hugo ArmandoClay | 6-2 6-3 | 3 | 67 | 4 | 0 | 55.1% | 92.6% | 54.5% | 1/1 |
| R32 | 308 | Carlos CuadradoClay | 98 |  Tomas BehrendClay | 7-5 6-0 | 3 | 61 | 1 | 1 | 66.7% | 83.3% | 53.3% | 0/1 |
| R32 | 187 | Daniel Gimeno-TraverClay | 56 | Agustin CalleriClay | 1-6 6-3 6-3 | 3 | 101 | 3 | 0 | 62.5% | 68.3% | 36.1% | 5/9 |
| R32 | 65 |  Boris PashanskiClay | 83 | Flavio SarettaClay | 1-6 7-5 6-3 | 3 | 144 | 4 | 3 | 67.3% | 63.6% | 43.8% | 6/11 |
| R32 | 122 |  Alessio Di MauroClay | 181 | Adrian GarciaClay | 6-7(6) 6-1 6-4 | 3 | 148 | 6 | 1 | 64.7% | 60.6% | 47.2% | 7/12 |
| R32 | 159 | Juan Martin del PotroClay | 117 | Albert PortasClay | 6-2 6-2 | 3 | 55 | 2 | 1 | 60.0% | 63.3% | 80.0% | 3/4 |
| R32 | 14 | Fernando GonzalezClay | 120 |  Vasilis MazarakisClay | 6-1 6-2 | 3 | 52 | 7 | 2 | 55.8% | 83.3% | 52.6% | 4/5 |
| R16 | 106 | Ruben Ramirez HidalgoClay | 8 | Gaston GaudioClay | 6-7(6) 6-1 6-4 | 3 | 157 | 11 | 2 | 56.5% | 77.1% | 45.9% | 3/7 |
| R16 | 75 | Albert MontanesClay | 164 | Santiago VenturaClay | 4-6 6-4 6-3 | 3 | 103 | 9 | 5 | 47.2% | 82.4% | 55.3% | 2/5 |
| R16 | 46 | Jose AcasusoClay | 486 | Gustavo MarcaccioClay | 6-1 6-1 | 3 | 58 | 7 | 1 | 67.4% | 72.4% | 71.4% | 1/1 |
| R16 | - | Leos FriedlClay | 397 | Jorge AguilarClay | 7-6(4) 6-3 | 3 | 98 | 6 | 3 | 69.2% | 64.4% | 55.0% | 4/7 |
| R16 | 69 | Nicolas MassuClay | 111 | Juan Antonio MarinClay | 6-3 6-4 | 3 | 91 | 5 | 0 | 54.4% | 74.2% | 76.9% | 0/0 |
| R16 | 308 | Carlos CuadradoClay | 187 | Daniel Gimeno-TraverClay | 6-3 6-3 | 3 | 62 | 2 | 3 | 75.5% | 77.5% | 61.5% | 3/3 |
| R16 | 65 | Boris PashanskiClay | 122 | Alessio Di MauroClay | 6-7(2) 7-6(4) 6-0 | 3 | 166 | 5 | 3 | 59.8% | 67.2% | 55.8% | 3/6 |
| R16 | 14 | Fernando GonzalezClay | 159 | Juan Martin del PotroClay | 6-3 7-6(4) | 3 | 95 | 2 | 2 | 50.0% | 72.5% | 45.0% | 7/11 |
| QF | 106 | Ruben Ramirez HidalgoClay | 75 | Albert MontanesClay | 6-2 2-6 6-2 | 3 | 109 | 6 | 0 | 51.9% | 80.5% | 42.1% | 9/12 |
| QF | 46 | Jose AcasusoClay | - | Leos FriedlClay | 3-6 6-1 7-5 | 3 | 143 | 12 | 1 | 50.0% | 78.7% | 46.8% | 4/7 |
| QF | 69 | Nicolas MassuClay | 308 | Carlos CuadradoClay | 4-6 7-6(4) 6-3 | 3 | 171 | 9 | 3 | 69.2% | 81.0% | 67.9% | 4/5 |
| QF | 14 | Fernando GonzalezClay | 65 | Boris PashanskiClay | 6-4 6-3 | 3 | 89 | 9 | 1 | 52.6% | 83.3% | 51.9% | 3/3 |
| SF | 46 | Jose AcasusoClay | 106 | Ruben Ramirez HidalgoClay | 6-2 6-4 | 3 | 96 | 7 | 0 | 75.5% | 83.8% | 58.3% | 1/1 |
| SF | 69 | Nicolas MassuClay | 14 | Fernando GonzalezClay | 3-6 7-6(3) 6-4 | 3 | 192 | 3 | 1 | 71.2% | 70.9% | 40.6% | 6/8 |
| F | 46 | Jose AcasusoClay | 69 | Nicolas MassuClay | 6-4 6-3 | 3 | 96 | 4 | 0 | 50.9% | 74.1% | 65.4% | 0/0 |
