| R32 | 8 |  Gaston GaudioClay | 93 |  Jiri VanekClay | 7-6(6) 6-2 | 3 | 83 | 3 | 6 | 56.0% | 81.0% | 51.5% | 6/7 |
| R32 | 76 |  David SanchezClay | 97 | Albert MontanesClay | 5-7 6-4 6-4 | 3 | 148 | 3 | 2 | 68.3% | 71.0% | 37.5% | 2/6 |
| R32 | 113 |  Flavio SarettaClay | 943 |  Felipe ParadaClay | 6-4 4-6 6-3 | 3 | 149 | 11 | 2 | 56.1% | 72.7% | 41.9% | 8/12 |
| R32 | 59 | Jose AcasusoClay | 145 |  Olivier PatienceClay | 6-1 3-6 7-6(6) | 3 | 115 | 6 | 6 | 62.1% | 71.2% | 55.6% | 7/9 |
| R32 | 53 | David FerrerClay | 175 | Albert PortasClay | 6-4 6-4 | 3 | 92 | 3 | 2 | 72.6% | 73.3% | 47.1% | 3/4 |
| R32 | 119 | Mariano PuertaClay | 83 | Juan MonacoClay | 6-3 6-7(6) 7-5 | 3 | 149 | 4 | 0 | 65.7% | 76.1% | 54.3% | 3/5 |
| R32 | 206 |  Federico LuzziClay | 102 |  Janko TipsarevicClay | 7-6(6) 6-0 | 3 | 92 | 6 | 4 | 47.5% | 82.8% | 53.1% | 4/5 |
| R32 | 62 | Agustin CalleriClay | 85 | Alex CalatravaClay | 6-3 6-2 | 3 | 59 | 4 | 2 | 51.1% | 83.3% | 65.2% | 1/2 |
| R32 | 127 | Ruben Ramirez HidalgoClay | 65 | Potito StaraceClay | 6-1 6-2 | 3 | 60 | 4 | 3 | 57.4% | 77.8% | 65.0% | 2/2 |
| R32 | 121 | Felix MantillaClay | 117 | Adrian GarciaClay | 6-4 3-2 RET | 3 | 64 | 2 | 2 | 56.9% | 69.0% | 59.1% | 1/3 |
| R32 | 112 | Paul-Henri MathieuClay | 84 | Oscar HernandezClay | 6-2 7-6(3) | 3 | 91 | 4 | 3 | 62.5% | 77.5% | 75.0% | 0/0 |
| R32 | 43 | Filippo VolandriClay | 90 | Guillermo Garcia-LopezClay | 6-1 6-3 | 3 | 75 | 1 | 6 | 57.8% | 64.9% | 44.4% | 4/6 |
| R32 | 49 | Mariano ZabaletaClay | 138 |  Nicolas LapenttiClay | 6-1 6-2 | 3 | 58 | 5 | 1 | 55.6% | 80.0% | 70.0% | 1/1 |
| R32 | 88 | Santiago VenturaClay | 610 | Phillip HarboeClay | 6-3 4-6 6-2 | 3 | 126 | 7 | 4 | 56.1% | 76.1% | 58.3% | 4/6 |
| R32 | 101 | Nicolas AlmagroClay | 126 | Alex CorretjaClay | 7-5 6-2 | 3 | 93 | 2 | 1 | 61.4% | 85.7% | 59.1% | 2/2 |
| R32 | 14 | Fernando GonzalezClay | 152 |  Peter LuczakClay | 6-3 5-7 6-4 | 3 | 110 | 16 | 7 | 64.0% | 76.4% | 45.2% | 2/5 |
| R16 | 8 | Gaston GaudioClay | 76 | David SanchezClay | 6-4 6-2 | 3 | 77 | 3 | 0 | 58.0% | 72.4% | 66.7% | 4/5 |
| R16 | 59 | Jose AcasusoClay | 113 | Flavio SarettaClay | 6-2 7-6(2) | 3 | 101 | 7 | 2 | 58.2% | 76.9% | 53.6% | 1/2 |
| R16 | 53 | David FerrerClay | 119 | Mariano PuertaClay | 6-2 6-0 | 3 | 72 | 4 | 1 | 66.7% | 69.0% | 38.1% | 1/2 |
| R16 | 62 | Agustin CalleriClay | 206 | Federico LuzziClay | 6-3 3-6 6-3 | 3 | 122 | 7 | 1 | 57.8% | 71.2% | 52.6% | 4/6 |
| R16 | 127 | Ruben Ramirez HidalgoClay | 121 | Felix MantillaClay | 6-4 6-3 | 3 | 88 | 4 | 2 | 43.1% | 72.7% | 58.6% | 0/2 |
| R16 | 43 | Filippo VolandriClay | 112 | Paul-Henri MathieuClay | 6-4 6-4 | 3 | 81 | 0 | 1 | 67.8% | 67.5% | 47.4% | 2/4 |
| R16 | 49 | Mariano ZabaletaClay | 88 | Santiago VenturaClay | 6-4 6-3 | 3 | 75 | 4 | 2 | 54.5% | 66.7% | 63.3% | 5/7 |
| R16 | 14 | Fernando GonzalezClay | 101 | Nicolas AlmagroClay | 7-6(4) 7-5 | 3 | 96 | 8 | 0 | 46.6% | 82.4% | 66.7% | 1/2 |
| QF | 8 | Gaston GaudioClay | 59 | Jose AcasusoClay | 6-2 3-6 6-1 | 3 | 92 | 4 | 2 | 59.5% | 70.5% | 63.3% | 1/2 |
| QF | 53 | David FerrerClay | 62 | Agustin CalleriClay | 6-1 6-3 | 3 | 60 | 1 | 0 | 66.7% | 78.1% | 56.3% | 0/0 |
| QF | 43 | Filippo VolandriClay | 127 | Ruben Ramirez HidalgoClay | 6-4 6-2 | 3 | 81 | 0 | 0 | 73.1% | 73.5% | 61.1% | 4/4 |
| QF | 14 | Fernando GonzalezClay | 49 | Mariano ZabaletaClay | 4-6 7-6(4) 7-6(2) | 3 | 176 | 9 | 6 | 53.3% | 70.8% | 61.4% | 6/9 |
| SF | 8 | Gaston GaudioClay | 53 | David FerrerClay | 6-3 4-6 6-2 | 3 | 135 | 2 | 2 | 63.0% | 58.8% | 60.0% | 8/12 |
| SF | 14 | Fernando GonzalezClay | 43 | Filippo VolandriClay | 6-4 5-7 6-2 | 3 | 109 | 4 | 1 | 63.7% | 78.4% | 62.1% | 3/5 |
| F | 8 | Gaston GaudioClay | 14 | Fernando GonzalezClay | 6-3 6-4 | 3 | 98 | 3 | 6 | 72.5% | 69.0% | 36.4% | 5/6 |
