| R32 | 12 |  Marcelo RiosClay | 91 |  Davide SanguinettiClay | 6-2 7-5 | 3 | 75 | 8 | 6 | 63.9% | 76.1% | 46.2% | 3/4 |
| R32 | 176 |  Sebastian PrietoClay | 61 |  Nicolas LapenttiClay | 6-4 6-4 | 3 | 87 | 2 | 1 | 57.3% | 74.4% | 50.0% | 10/11 |
| R32 | 70 |  Fernando MeligeniClay | 112 |  Jacobo DiazClay | 6-3 3-6 6-2 | 3 | 113 | 5 | 5 | 44.1% | 78.0% | 50.0% | 4/5 |
| R32 | 158 | Gabriel SilbersteinClay | 59 | Carlos CostaClay | 6-2 6-4 | 3 | 60 | 3 | 0 | 63.5% | 72.7% | 63.2% | 1/2 |
| R32 | 68 | Andrea GaudenziClay | 42 |  Tommy HaasClay | 6-3 6-2 | 3 | 48 | 4 | 1 | 59.0% | 87.0% | 62.5% | 1/2 |
| R32 | 99 |  Radomir VasekClay | 140 | Francisco CabelloClay | 6-4 7-6(3) | 3 | 92 | 2 | 8 | 63.7% | 64.7% | 48.3% | 1/4 |
| R32 | 107 | Alberto MartinClay | 509 | Hermes GamonalClay | 6-4 5-7 6-4 | 3 | 119 | 2 | 3 | 67.3% | 56.9% | 48.6% | 9/15 |
| R32 | 47 |  Marcelo FilippiniClay | 93 | Emilio Benfele AlvarezClay | 6-2 7-6(2) | 3 | 99 | 0 | 4 | 63.1% | 82.9% | 54.2% | 1/1 |
| R32 | 174 | Mariano PuertaClay | 50 | Galo BlancoClay | 6-4 6-3 | 3 | 61 | 5 | 2 | 64.3% | 80.6% | 65.0% | 1/1 |
| R32 | 77 | Juan Albert Viloca-PuigClay | 614 | Nicolas MassuClay | 6-7(4) 7-5 6-3 | 3 | 103 | 4 | 6 | 61.6% | 68.8% | 56.3% | 12/13 |
| R32 | 106 | Marcello CracaClay | 89 |  Juan Antonio MarinClay | 7-5 6-1 | 3 | 80 | 2 | 2 | 75.0% | 59.3% | 66.7% | 6/8 |
| R32 | 45 | Julian AlonsoClay | 85 |  Dinu PescariuClay | 6-4 6-7(1) 6-1 | 3 | 110 | 6 | 6 | 52.1% | 66.7% | 53.4% | 11/13 |
| R32 | 103 | Oliver GrossClay | 58 | MARKarim AlamiClay | 7-5 6-2 | 3 | 78 | 5 | 4 | 63.1% | 73.2% | 45.8% | 3/5 |
| R32 | 63 | Hernan GumyClay | 115 | Fernando VicenteClay | 6-2 6-2 | 3 | 69 | 1 | 5 | 51.1% | 70.8% | 56.5% | 0/2 |
| R32 | 110 | Jordi BurilloClay | 101 | Andrei PavelClay | 6-4 6-7(8) 7-6(8) | 3 | 164 | 14 | 2 | 53.2% | 77.1% | 49.3% | 18/18 |
| R32 | 33 | Francisco ClavetClay | 83 |  Vincent SpadeaClay | 7-6(4) 6-3 | 3 | 78 | 3 | 1 | 79.4% | 72.0% | 61.5% | 1/3 |
| R16 | 12 | Marcelo RiosClay | 176 | Sebastian PrietoClay | 5-7 6-1 6-4 | 3 | 108 | 6 | 0 | 59.8% | 63.8% | 53.8% | 5/9 |
| R16 | 70 | Fernando MeligeniClay | 158 | Gabriel SilbersteinClay | 4-6 6-3 6-2 | 3 | 98 | 10 | 4 | 68.3% | 78.6% | 46.2% | 2/4 |
| R16 | 99 | Radomir VasekClay | 68 | Andrea GaudenziClay | 6-4 7-5 | 3 | 89 | 0 | 2 | 62.3% | 65.8% | 56.5% | 2/5 |
| R16 | 47 | Marcelo FilippiniClay | 107 | Alberto MartinClay | 7-5 6-3 | 3 | 91 | 5 | 1 | 74.3% | 65.5% | 52.6% | 4/6 |
| R16 | 174 | Mariano PuertaClay | 77 | Juan Albert Viloca-PuigClay | 6-4 6-3 | 3 | 67 | 6 | 0 | 64.3% | 83.3% | 60.0% | 0/0 |
| R16 | 45 | Julian AlonsoClay | 106 | Marcello CracaClay | 6-4 1-6 7-5 | 3 | 96 | 7 | 4 | 60.7% | 76.5% | 39.4% | 3/6 |
| R16 | 103 | Oliver GrossClay | 63 | Hernan GumyClay | 5-7 6-1 6-3 | 3 | 121 | 4 | 2 | 58.6% | 64.7% | 52.8% | 8/12 |
| R16 | 110 | Jordi BurilloClay | 33 | Francisco ClavetClay | 7-6(5) 3-6 6-3 | 3 | 136 | 9 | 2 | 58.4% | 75.8% | 46.8% | 4/8 |
| QF | 12 | Marcelo RiosClay | 70 | Fernando MeligeniClay | 1-6 7-6(5) 6-1 | 3 | 93 | 1 | 2 | 59.5% | 65.9% | 60.0% | 2/5 |
| QF | 47 | Marcelo FilippiniClay | 99 | Radomir VasekClay | 6-1 7-5 | 3 | 94 | 3 | 1 | 68.4% | 56.4% | 50.0% | 6/10 |
| QF | 45 | Julian AlonsoClay | 174 | Mariano PuertaClay | 6-4 6-2 | 3 | 57 | 6 | 1 | 69.1% | 73.7% | 58.8% | 1/2 |
| QF | 110 | Jordi BurilloClay | 103 | Oliver GrossClay | 6-4 6-4 | 3 | 70 | 5 | 3 | 68.9% | 76.2% | 47.4% | 4/6 |
| SF | 12 | Marcelo RiosClay | 47 | Marcelo FilippiniClay | 6-1 6-4 | 3 | 50 | 4 | 0 | 46.7% | 71.4% | 70.8% | 2/3 |
| SF | 45 | Julian AlonsoClay | 110 | Jordi BurilloClay | 6-1 4-6 6-3 | 3 | 79 | 11 | 7 | 55.1% | 81.4% | 54.3% | 2/3 |
| F | 45 | Julian AlonsoClay | 12 | Marcelo RiosClay | 6-2 6-1 | 3 | 50 | 10 | 3 | 46.8% | 82.8% | 48.5% | 6/6 |
