| R32 | 3 |  Nikolay DavydenkoHard | 123 |  Michael BerrerHard | 6-3 6-4 | 3 | 75 | 9 | 0 | 66.1% | 70.7% | 66.7% | 1/1 |
| R32 | 44 |  Marc GicquelHard | 55 | Arnaud ClementHard | 6-4 6-3 | 3 | 82 | 6 | 0 | 41.7% | 85.0% | 64.3% | 1/2 |
| R32 | 58 | Philipp KohlschreiberHard | 42 | Gilles SimonHard | 6-3 3-1 RET | 3 | 56 | 7 | 1 | 47.6% | 90.0% | 54.5% | 0/0 |
| R32 | 19 |  Radek StepanekHard | 83 | Jan HernychHard | 6-2 7-5 | 3 | 107 | 4 | 1 | 79.7% | 69.1% | 57.1% | 5/6 |
| R32 | 8 |  Ivan LjubicicHard | 433 |  Thiemo de BakkerHard | 7-5 6-3 | 3 | 72 | 14 | 1 | 69.1% | 84.2% | 70.6% | 0/0 |
| R32 | 34 |  Olivier RochusHard | 91 |  Janko TipsarevicHard | 4-6 6-2 6-4 | 3 | 114 | 4 | 2 | 58.8% | 78.7% | 60.6% | 7/9 |
| R32 | 49 | Florian MayerHard | 23 |  Dominik HrbatyHard | 7-6(5) 2-6 7-5 | 3 | 125 | 7 | 2 | 53.8% | 66.1% | 58.3% | 4/9 |
| R32 | - | Dennis Van ScheppingenHard | 51 | Gael MonfilsHard | 6-7(3) 6-4 6-3 | 3 | 102 | 6 | 1 | 63.9% | 86.8% | 63.3% | 0/1 |
| R32 | 15 |  David FerrerHard | 76 | Christophe RochusHard | 6-3 6-0 | 3 | 63 | 6 | 4 | 76.1% | 77.1% | 45.5% | 3/3 |
| R32 | 43 | Kristof VliegenHard | 18 |  Jarkko NieminenHard | 6-1 6-4 | 3 | 69 | 3 | 1 | 64.4% | 81.6% | 47.6% | 4/4 |
| R32 | 164 | Robin HaaseHard | 158 | Roko KaranusicHard | 6-3 7-6(2) | 3 | 79 | 6 | 0 | 61.3% | 78.9% | 66.7% | 2/3 |
| R32 | 22 | Mikhail YouzhnyHard | 12 | Tomas BerdychHard | 6-4 6-7(5) 6-1 | 3 | 136 | 8 | 1 | 56.6% | 83.9% | 60.5% | 8/8 |
| R32 | 14 | Novak DjokovicHard | 67 | Florent SerraHard | 7-6(6) 6-4 | 3 | 88 | 5 | 0 | 73.1% | 77.6% | 61.1% | 0/0 |
| R32 | 120 |  Andrei PavelHard | 71 |  Daniele BraccialiHard | 6-1 6-1 | 3 | 50 | 4 | 1 | 68.4% | 88.5% | 50.0% | 1/1 |
| R32 | 135 |  Rik De VoestHard | 1533 | Martin VerkerkHard | 6-3 7-6(0) | 3 | 78 | 7 | 2 | 67.8% | 85.0% | 57.9% | 0/1 |
| R32 | 7 | Tommy RobredoHard | 114 | Simone BolelliHard | 6-2 6-2 | 3 | 79 | 8 | 1 | 59.5% | 88.0% | 58.8% | 0/0 |
| R16 | 3 | Nikolay DavydenkoHard | 44 | Marc GicquelHard | 6-3 6-3 | 3 | 71 | 7 | 1 | 69.4% | 85.3% | 53.3% | 0/0 |
| R16 | 58 | Philipp KohlschreiberHard | 19 | Radek StepanekHard | 7-6(12) 7-6(6) | 3 | 132 | 10 | 1 | 56.8% | 77.8% | 58.5% | 1/3 |
| R16 | 8 | Ivan LjubicicHard | 34 | Olivier RochusHard | 6-3 7-6(4) | 3 | 104 | 26 | 0 | 64.3% | 93.3% | 40.0% | 1/1 |
| R16 | 49 | Florian MayerHard | - | Dennis Van ScheppingenHard | 7-5 6-2 | 3 | 68 | 11 | 4 | 65.7% | 75.0% | 47.8% | 5/6 |
| R16 | 15 | David FerrerHard | 43 | Kristof VliegenHard | 6-4 6-2 | 3 | 79 | 0 | 3 | 67.3% | 82.9% | 47.1% | 0/1 |
| R16 | 22 | Mikhail YouzhnyHard | 164 | Robin HaaseHard | 6-2 6-4 | 3 | 96 | 5 | 0 | 71.7% | 76.7% | 47.1% | 4/4 |
| R16 | 14 | Novak DjokovicHard | 120 | Andrei PavelHard | 6-7(8) 6-1 6-3 | 3 | 129 | 9 | 2 | 76.3% | 78.7% | 63.2% | 1/2 |
| R16 | 7 | Tommy RobredoHard | 135 | Rik De VoestHard | 6-0 6-4 | 3 | 78 | 3 | 3 | 62.1% | 69.4% | 50.0% | 9/10 |
| QF | 3 | Nikolay DavydenkoHard | 58 | Philipp KohlschreiberHard | 6-7(6) 6-4 6-4 | 3 | 125 | 10 | 2 | 60.9% | 84.9% | 67.6% | 0/1 |
| QF | 8 | Ivan LjubicicHard | 49 | Florian MayerHard | 6-4 6-2 | 3 | 56 | 13 | 1 | 63.6% | 100.0% | 50.0% | 0/0 |
| QF | 22 | Mikhail YouzhnyHard | 15 | David FerrerHard | 6-2 7-5 | 3 | 81 | 6 | 0 | 60.7% | 82.4% | 45.5% | 3/5 |
| QF | 14 | Novak DjokovicHard | 7 | Tommy RobredoHard | 4-6 6-4 7-5 | 3 | 146 | 4 | 2 | 69.9% | 75.4% | 39.3% | 2/5 |
| SF | 8 | Ivan LjubicicHard | 3 | Nikolay DavydenkoHard | 4-6 7-6(4) 7-6(4) | 3 | 170 | 24 | 1 | 64.9% | 82.4% | 45.0% | 3/5 |
| SF | 22 | Mikhail YouzhnyHard | 14 | Novak DjokovicHard | 3-6 7-6(7) 7-5 | 3 | 170 | 24 | 1 | 64.9% | 82.4% | 45.0% | 3/5 |
| F | 22 | Mikhail YouzhnyHard | 8 | Ivan LjubicicHard | 6-2 6-4 | 3 | 65 | 14 | 0 | 61.7% | 96.6% | 50.0% | 0/0 |
