| R64 | 1 | Roger FedererClay | 30 | Juan Ignacio ChelaClay | 6-2 6-1 | 3 | 68 | 3 | 0 | 56.9% | 69.0% | 68.2% | 1/2 |
| R64 | 81 | Potito StaraceClay | 32 | Dmitry TursunovClay | 6-4 6-1 | 3 | 67 | 1 | 0 | 66.7% | 81.3% | 62.5% | 2/2 |
| R64 | 16 | Jarkko NieminenClay | 22 | Sebastien GrosjeanClay | 6-2 6-1 | 3 | 69 | 0 | 0 | 51.2% | 57.1% | 70.0% | 1/2 |
| R64 | 18 | Radek StepanekClay | 43 | Feliciano LopezClay | 6-4 6-4 | 3 | 88 | 7 | 8 | 54.7% | 68.3% | 50.0% | 10/12 |
| R64 | 34 | Jose AcasusoClay | 19 | David FerrerClay | 7-5 6-0 | 3 | 80 | 3 | 0 | 52.8% | 78.6% | 44.0% | 0/2 |
| R64 | 54 | Nicolas AlmagroClay | 31 | Nicolas MassuClay | 7-5 6-4 | 3 | 119 | 3 | 2 | 73.5% | 72.0% | 61.1% | 4/5 |
| R64 | 39 | Fernando VerdascoClay | 174 | Simone BolelliClay | 6-4 2-6 6-1 | 3 | 106 | 2 | 2 | 68.7% | 50.0% | 57.1% | 3/8 |
| R64 | 6 | Nikolay DavydenkoClay | 62 | Boris PashanskiClay | 6-1 6-4 | 3 | 83 | 3 | 4 | 68.3% | 67.4% | 40.0% | 9/11 |
| R64 | 3 | David NalbandianClay | 89 | Fernando VicenteClay | 6-2 3-6 6-3 | 3 | 117 | 1 | 4 | 58.5% | 79.2% | 52.9% | 7/8 |
| R64 | 40 | Paul-Henri MathieuClay | 27 | Juan Carlos FerreroClay | 6-1 6-3 | 3 | 68 | 5 | 3 | 64.0% | 90.6% | 44.4% | 2/2 |
| R64 | 77 | Alberto MartinClay | 66 | Davide SanguinettiClay | 6-4 6-2 | 3 | 77 | 0 | 0 | 54.4% | 71.0% | 65.4% | 5/6 |
| R64 | 12 | Nicolas KieferClay | 49 | Daniele BraccialiClay | 4-6 6-2 6-4 | 3 | 127 | 4 | 7 | 45.1% | 75.6% | 50.0% | 7/10 |
| R64 | 93 | Ruben Ramirez HidalgoClay | 13 | Guillermo CoriaClay | 6-3 6-2 | 3 | 88 | 2 | 1 | 47.3% | 80.8% | 34.5% | 3/6 |
| R64 | 51 | Marat SafinClay | 126 | Teymuraz GabashviliClay | 7-5 3-6 6-1 | 3 | 150 | 5 | 4 | 49.6% | 71.2% | 51.7% | 10/11 |
| R64 | 15 | Mario AncicClay | 48 | Luis HornaClay | 6-4 6-4 | 3 | 86 | 7 | 1 | 71.2% | 78.4% | 60.0% | 2/3 |
| R64 | 47 | Florent SerraClay | 7 | James BlakeClay | 6-4 7-6(3) | 3 | 101 | 1 | 2 | 63.3% | 63.2% | 54.5% | 7/10 |
| R64 | 5 | Andy RoddickClay | 59 | Victor HanescuClay | 6-1 6-0 | 3 | 51 | 3 | 2 | 36.4% | 100.0% | 61.9% | 2/2 |
| R64 | 20 | Marcos BaghdatisClay | 29 | Olivier RochusClay | 7-5 6-4 | 3 | 116 | 15 | 1 | 50.6% | 74.4% | 40.5% | 8/10 |
| R64 | 206 | Stefano GalvaniClay | 98 | Jiri NovakClay | 6-3 6-4 | 3 | 100 | 0 | 6 | 58.3% | 51.0% | 57.1% | 12/16 |
| R64 | 45 | Greg RusedskiClay | 10 | Tommy RobredoClay | 5-7 6-3 6-4 | 3 | 133 | 7 | 4 | 62.4% | 74.0% | 29.5% | 11/15 |
| R64 | 17 | Robby GinepriClay | 61 | Max MirnyiClay | 3-6 6-2 6-3 | 3 | 118 | 7 | 3 | 61.4% | 72.2% | 52.9% | 6/8 |
| R64 | 35 | Gael MonfilsClay | 25 | Tommy HaasClay | 6-2 3-6 6-4 | 3 | 126 | 4 | 6 | 45.4% | 65.9% | 45.3% | 5/9 |
| R64 | 53 | Fabrice SantoroClay | 124 | Juan MonacoClay | 4-6 6-2 6-3 | 3 | 137 | 1 | 3 | 53.6% | 69.2% | 40.0% | 6/10 |
| R64 | 24 | Dominik HrbatyClay | 4 | Ivan LjubicicClay | 5-7 7-6(4) 6-4 | 3 | 169 | 4 | 7 | 55.2% | 76.6% | 53.8% | 10/12 |
| R64 | 41 | Xavier MalisseClay | 8 | Gaston GaudioClay | 4-6 6-3 6-3 | 3 | 131 | 3 | 0 | 50.0% | 71.8% | 51.3% | 7/11 |
| R64 | 21 | Tomas BerdychClay | 36 | Paradorn SrichaphanClay | 6-1 6-3 | 3 | 59 | 5 | 1 | 65.9% | 88.9% | 71.4% | 3/3 |
| R64 | 38 | Mikhail YouzhnyClay | 55 | Andreas SeppiClay | 6-2 7-6(7) | 3 | 100 | 3 | 1 | 58.5% | 76.3% | 51.9% | 3/4 |
| R64 | 9 | Fernando GonzalezClay | 58 | Stan WawrinkaClay | 6-4 6-4 | 3 | 94 | 3 | 4 | 64.3% | 68.9% | 36.0% | 5/8 |
| R64 | 14 | Thomas JohanssonClay | 294 | Fabio FogniniClay | 7-6(3) 6-3 | 3 | 112 | 3 | 3 | 56.8% | 83.3% | 46.9% | 3/5 |
| R64 | 70 | Tim HenmanClay | 78 | Alessio Di MauroClay | 7-5 7-6(2) | 3 | 117 | 6 | 0 | 59.5% | 72.3% | 62.5% | 7/8 |
| R64 | 46 | Filippo VolandriClay | 44 | Andy MurrayClay | 6-4 6-4 | 3 | 95 | 0 | 1 | 52.4% | 63.6% | 50.0% | 0/3 |
| R64 | 2 | Rafael NadalClay | 33 | Carlos MoyaClay | 6-1 2-6 6-2 | 3 | 114 | 1 | 2 | 81.4% | 64.9% | 53.8% | 2/4 |
| R32 | 1 | Roger FedererClay | 81 | Potito StaraceClay | 6-3 7-6(2) | 3 | 111 | 2 | 2 | 48.8% | 71.8% | 51.2% | 0/3 |
| R32 | 18 | Radek StepanekClay | 16 | Jarkko NieminenClay | 6-4 7-6(5) | 3 | 103 | 4 | 2 | 60.0% | 71.4% | 50.0% | 1/3 |
| R32 | 54 | Nicolas AlmagroClay | 34 | Jose AcasusoClay | 6-4 2-6 6-4 | 3 | 124 | 3 | 3 | 71.3% | 65.7% | 51.9% | 13/16 |
| R32 | 6 | Nikolay DavydenkoClay | 39 | Fernando VerdascoClay | 6-1 3-6 6-0 | 3 | 103 | 1 | 3 | 72.0% | 55.9% | 65.2% | 6/9 |
| R32 | 3 | David NalbandianClay | 40 | Paul-Henri MathieuClay | 6-2 6-4 | 3 | 83 | 4 | 1 | 52.1% | 76.0% | 69.6% | 4/5 |
| R32 | 77 | Alberto MartinClay | 12 | Nicolas KieferClay | 6-3 7-6(3) | 3 | 110 | 1 | 3 | 67.1% | 63.3% | 70.8% | 2/4 |
| R32 | 93 | Ruben Ramirez HidalgoClay | 51 | Marat SafinClay | 0-6 7-6(6) 7-6(3) | 3 | 182 | 6 | 1 | 62.3% | 61.8% | 45.7% | 5/10 |
| R32 | 15 | Mario AncicClay | 47 | Florent SerraClay | 3-6 7-6(10) 6-0 | 3 | 140 | 13 | 5 | 60.6% | 68.3% | 56.1% | 6/10 |
| R32 | 5 | Andy RoddickClay | 20 | Marcos BaghdatisClay | 3-6 6-1 6-2 | 3 | 114 | 2 | 7 | 53.6% | 64.4% | 41.0% | 6/11 |
| R32 | 45 | Greg RusedskiClay | 206 | Stefano GalvaniClay | 7-6(4) 6-4 | 3 | 106 | 2 | 3 | 66.3% | 67.9% | 40.7% | 3/6 |
| R32 | 35 | Gael MonfilsClay | 17 | Robby GinepriClay | 6-1 4-6 6-4 | 3 | 113 | 1 | 9 | 58.4% | 71.2% | 59.5% | 4/6 |
| R32 | 53 | Fabrice SantoroClay | 24 | Dominik HrbatyClay | 7-6(2) 6-3 | 3 | 110 | 1 | 1 | 50.6% | 63.4% | 57.5% | 6/8 |
| R32 | 21 | Tomas BerdychClay | 41 | Xavier MalisseClay | 6-2 6-1 | 3 | 64 | 5 | 3 | 56.1% | 78.3% | 55.6% | 0/1 |
| R32 | 9 | Fernando GonzalezClay | 38 | Mikhail YouzhnyClay | 6-4 5-7 6-3 | 3 | 180 | 3 | 7 | 50.4% | 61.0% | 53.4% | 13/18 |
| R32 | 70 | Tim HenmanClay | 14 | Thomas JohanssonClay | 7-6(8) 6-1 | 3 | 97 | 4 | 1 | 69.3% | 69.2% | 56.5% | 3/5 |
| R32 | 2 | Rafael NadalClay | 46 | Filippo VolandriClay | 6-1 6-2 | 3 | 71 | 0 | 1 | 65.4% | 79.4% | 50.0% | 4/4 |
| R16 | 1 | Roger FedererClay | 18 | Radek StepanekClay | 6-1 6-4 | 3 | 57 | 2 | 2 | 52.2% | 95.8% | 63.6% | 3/3 |
| R16 | 54 | Nicolas AlmagroClay | 6 | Nikolay DavydenkoClay | 7-6(6) RET | 3 | 71 | 2 | 1 | 47.8% | 86.4% | 58.3% | 3/3 |
| R16 | 3 | David NalbandianClay | 77 | Alberto MartinClay | 7-5 6-4 | 3 | 108 | 1 | 1 | 63.9% | 61.5% | 50.0% | 3/7 |
| R16 | 15 | Mario AncicClay | 93 | Ruben Ramirez HidalgoClay | 6-3 6-7(4) 7-5 | 3 | 190 | 6 | 4 | 63.6% | 70.6% | 48.7% | 5/8 |
| R16 | 5 | Andy RoddickClay | 45 | Greg RusedskiClay | 7-6(4) 6-2 | 3 | 75 | 5 | 0 | 62.7% | 87.5% | 84.2% | 0/0 |
| R16 | 35 | Gael MonfilsClay | 53 | Fabrice SantoroClay | 7-6(7) 6-2 | 3 | 121 | 5 | 5 | 51.3% | 75.0% | 26.3% | 3/7 |
| R16 | 9 | Fernando GonzalezClay | 21 | Tomas BerdychClay | 6-2 6-4 | 3 | 89 | 4 | 1 | 58.9% | 72.7% | 69.6% | 3/3 |
| R16 | 2 | Rafael NadalClay | 70 | Tim HenmanClay | 6-2 6-2 | 3 | 71 | 1 | 0 | 78.0% | 78.1% | 77.8% | 0/0 |
| QF | 1 | Roger FedererClay | 54 | Nicolas AlmagroClay | 6-3 6-7(2) 7-5 | 3 | 153 | 9 | 2 | 62.2% | 71.0% | 57.1% | 7/9 |
| QF | 3 | David NalbandianClay | 15 | Mario AncicClay | 6-3 6-3 | 3 | 84 | 0 | 1 | 41.8% | 78.3% | 62.5% | 2/3 |
| QF | 35 | Gael MonfilsClay | 5 | Andy RoddickClay | 6-2 6-3 | 3 | 71 | 4 | 5 | 63.3% | 71.0% | 50.0% | 5/7 |
| QF | 2 | Rafael NadalClay | 9 | Fernando GonzalezClay | 6-4 6-3 | 3 | 102 | 0 | 1 | 84.9% | 68.9% | 50.0% | 2/4 |
| SF | 1 | Roger FedererClay | 3 | David NalbandianClay | 6-3 3-6 7-6(5) | 3 | 163 | 9 | 2 | 47.9% | 69.6% | 44.3% | 11/16 |
| SF | 2 | Rafael NadalClay | 35 | Gael MonfilsClay | 6-2 6-2 | 3 | 77 | 0 | 0 | 76.5% | 61.5% | 58.3% | 2/3 |
| F | 2 | Rafael NadalClay | 1 | Roger FedererClay | 6-7(0) 7-6(5) 6-4 2-6 7-6(5) | 5 | 305 | 4 | 1 | 85.0% | 68.7% | 53.8% | 6/10 |