| R32 | 129 |  Dusan LajovicClay | 54 |  Daniel AltmaierClay | 6-4 7-6(7) | 3 | 121 | 2 | 1 | 76.7% | 78.6% | 41.2% | 1/2 |
| R32 | 92 |  Thiago Agustin TiranteClay | 89 |  Cristian GarinClay | 7-5 6-3 | 3 | 113 | 12 | 0 | 55.1% | 71.1% | 54.8% | 5/7 |
| R32 | 90 | Yannick HanfmannClay | 207 |  Joao Lucas Reis Da SilvaClay | 7-6(3) 6-4 | 3 | 117 | 6 | 1 | 72.5% | 80.0% | 42.1% | 2/4 |
| R32 | 91 |  Ignacio BuseClay | 348 | Igor MarcondesClay | 4-6 7-5 6-4 | 3 | 162 | 3 | 1 | 67.3% | 72.4% | 48.6% | 12/14 |
| R32 | 87 |  Vit KoprivaClay | 258 | Gustavo HeideClay | 6-2 7-6(5) | 3 | 109 | 2 | 1 | 64.6% | 71.4% | 73.9% | 7/8 |
| R32 | 68 | Alejandro TabiloClay | 76 |  Emilio NavaClay | 6-3 6-3 | 3 | 63 | 3 | 0 | 83.3% | 82.9% | 100.0% | 0/0 |
| R32 | 38 | Joao FonsecaClay | 208 | Thiago MonteiroClay | 7-6(1) 6-1 | 3 | 94 | 7 | 1 | 71.7% | 83.7% | 58.8% | 0/0 |
| R32 | 19 | Francisco CerundoloClay | 74 | Mariano NavoneClay | 6-3 6-4 | 3 | 91 | 1 | 2 | 63.2% | 72.1% | 48.0% | 10/12 |
| R32 | 78 | Juan Manuel CerundoloClay | 21 |  Luciano DarderiClay | 6-1 3-6 6-4 | 3 | 137 | 4 | 2 | 73.3% | 66.7% | 54.2% | 6/8 |
| R32 | 102 | Roman Andres BurruchagaClay | 46 | Camilo Ugo CarabelliClay | 6-3 6-4 | 3 | 96 | 5 | 3 | 69.8% | 77.3% | 57.9% | 3/3 |
| R32 | 51 | Tomas Martin EtcheverryClay | 63 | Francisco ComesanaClay | 3-6 6-3 6-4 | 3 | 156 | 6 | 2 | 66.7% | 72.2% | 63.0% | 3/4 |
| R32 | 57 | Matteo BerrettiniClay | 107 | Tomas Barrios VeraClay | 7-6(1) 7-5 | 3 | 145 | 6 | 2 | 64.0% | 79.2% | 66.7% | 5/5 |
| R32 | 163 | Francesco PassaroClay | 122 |  Dino PrizmicClay | 6-3 6-4 | 3 | 106 | 3 | 0 | 58.2% | 78.1% | 52.2% | 3/4 |
| R32 | 147 |  Jaime FariaClay | 32 | Sebastian BaezClay | 7-5 6-1 | 3 | 95 | 2 | 2 | 64.8% | 80.0% | 42.1% | 1/3 |
| R32 | 62 |  Damir DzumhurClay | 101 |  Pedro MartinezClay | 0-6 7-6(5) 6-4 | 3 | 159 | 1 | 0 | 71.4% | 56.9% | 38.5% | 6/12 |
| R32 | 126 |  Vilius GaubasClay | 1593 | Luis Guto MiguelClay | 6-3 2-6 6-2 | 3 | 131 | 0 | 2 | 76.3% | 59.0% | 63.2% | 1/3 |
| R16 | 68 | Alejandro TabiloClay | 163 | Francesco PassaroClay | 4-6 7-6(0) 6-2 | 3 | 141 | 4 | 0 | 64.1% | 86.0% | 53.6% | 4/6 |
| R16 | 147 | Jaime FariaClay | 62 | Damir DzumhurClay | 7-6(1) 6-4 | 3 | 123 | 2 | 2 | 56.9% | 83.8% | 60.7% | 1/2 |
| R16 | 91 | Ignacio BuseClay | 38 | Joao FonsecaClay | 5-7 6-3 6-4 | 3 | 146 | 8 | 5 | 61.5% | 76.3% | 56.8% | 8/9 |
| R16 | 92 | Thiago Agustin TiranteClay | 19 | Francisco CerundoloClay | 6-2 3-1 RET | 3 | 73 | 7 | 0 | 64.9% | 79.2% | 61.5% | 1/1 |
| R16 | 78 | Juan Manuel CerundoloClay | 90 | Yannick HanfmannClay | 6-4 6-7(1) 6-4 | 3 | 169 | 9 | 3 | 70.3% | 65.6% | 55.6% | 1/4 |
| R16 | 87 | Vit KoprivaClay | 102 | Roman Andres BurruchagaClay | 6-3 6-1 | 3 | 88 | 3 | 2 | 64.4% | 68.4% | 66.7% | 6/6 |
| R16 | 51 | Tomas Martin EtcheverryClay | 126 | Vilius GaubasClay | 7-6(1) 6-4 | 3 | 127 | 7 | 0 | 70.1% | 68.1% | 60.0% | 0/2 |
| R16 | 57 | Matteo BerrettiniClay | 129 | Dusan LajovicClay | 3-6 6-4 6-2 | 3 | 129 | 7 | 3 | 71.8% | 78.6% | 40.9% | 4/6 |
| QF | 87 | Vit KoprivaClay | 78 | Juan Manuel CerundoloClay | 6-4 6-4 | 3 | 97 | 6 | 4 | 68.5% | 86.5% | 47.1% | 0/0 |
| QF | 68 | Alejandro TabiloClay | 92 | Thiago Agustin TiranteClay | 7-6(2) 6-7(6) 6-1 | 3 | 172 | 7 | 3 | 67.0% | 81.5% | 53.1% | 0/2 |
| QF | 51 | Tomas Martin EtcheverryClay | 147 | Jaime FariaClay | 7-6(4) 6-4 | 3 | 123 | 9 | 1 | 68.5% | 80.0% | 43.5% | 5/5 |
| QF | 91 | Ignacio BuseClay | 57 | Matteo BerrettiniClay | 6-3 2-6 6-3 | 3 | 139 | 3 | 1 | 65.4% | 72.5% | 63.0% | 4/6 |
| SF | 51 | Tomas Martin EtcheverryClay | 87 | Vit KoprivaClay | 4-6 7-6(2) 7-6(4) | 3 | 237 | 9 | 2 | 57.9% | 83.9% | 55.6% | 0/1 |
| SF | 68 | Alejandro TabiloClay | 91 | Ignacio BuseClay | 6-3 6-3 | 3 | 72 | 2 | 0 | 61.4% | 85.2% | 64.7% | 1/2 |
| F | 51 | Tomas Martin EtcheverryClay | 68 | Alejandro TabiloClay | 3-6 7-6(3) 6-4 | 3 | 184 | 14 | 4 | 63.8% | 71.6% | 42.1% | 6/9 |
