| R32 | 52 |  Lorenzo SonegoClay | 109 |  Leonardo MayerClay | 6-1 5-7 6-4 | 3 | 171 | 6 | 4 | 57.6% | 70.2% | 59.5% | 6/7 |
| R32 | 206 |  Thiago Seyboth WildClay | 90 |  Alejandro Davidovich FokinaClay | 5-7 7-6(3) 7-5 | 3 | 229 | 5 | 6 | 50.8% | 65.7% | 46.2% | 6/12 |
| R32 | 99 | Jaume MunarClay | 97 | Salvatore CarusoClay | 7-5 6-4 | 3 | 124 | 2 | 0 | 54.7% | 68.6% | 48.3% | 2/5 |
| R32 | 133 | Pedro MartinezClay | 78 |  Hugo DellienClay | 3-6 6-2 7-5 | 3 | 155 | 0 | 2 | 78.1% | 60.0% | 42.9% | 4/9 |
| R32 | 169 |  Joao DominguesClay | 127 | Federico GaioClay | 7-6(8) 6-4 | 3 | 106 | 2 | 2 | 66.7% | 62.5% | 58.3% | 2/4 |
| R32 | 86 | Federico DelbonisClay | 93 | Roberto Carballes BaenaClay | 6-2 6-4 | 3 | 113 | 3 | 2 | 57.6% | 79.4% | 40.0% | 6/8 |
| R32 | 116 | Federico CoriaClay | 77 |  Corentin MoutetClay | 1-6 7-6(1) 7-6(3) | 3 | 177 | 1 | 2 | 69.7% | 60.5% | 48.5% | 7/12 |
| R32 | 106 |  Attila BalazsClay | 46 |  Pablo CuevasClay | 6-4 6-3 | 3 | 91 | 4 | 6 | 55.4% | 83.3% | 55.2% | 2/2 |
| R32 | 59 | Pablo AndujarClay | 49 | Fernando VerdascoClay | 6-3 6-3 | 3 | 88 | 1 | 1 | 67.8% | 65.0% | 63.2% | 2/4 |
| R32 | 128 | Gianluca MagerClay | 34 |  Casper RuudClay | 7-6(4) 7-5 | 3 | 111 | 8 | 0 | 74.1% | 76.7% | 71.4% | 7/7 |
| R32 | 406 | Carlos AlcarazClay | 41 | Albert Ramos-VinolasClay | 7-6(2) 4-6 7-6(2) | 3 | 216 | 2 | 5 | 68.0% | 62.5% | 44.9% | 10/15 |
| R32 | 32 |  Borna CoricClay | 61 | Juan Ignacio LonderoClay | 7-6(5) 7-5 | 3 | 117 | 9 | 2 | 58.8% | 80.0% | 53.6% | 0/2 |
| R32 | 88 | Thiago MonteiroClay | 26 | Guido PellaClay | 5-7 6-4 7-6(3) | 3 | 183 | 8 | 5 | 62.0% | 70.1% | 51.2% | 6/11 |
| R32 | 25 |  Cristian GarinClay | 94 |  Andrej MartinClay | 4-6 7-5 7-6(5) | 3 | 189 | 3 | 5 | 55.8% | 75.9% | 50.0% | 4/8 |
| R32 | 23 |  Dusan LajovicClay | 111 | Marco CecchinatoClay | 6-4 6-7(4) 6-1 | 3 | 136 | 7 | 3 | 64.1% | 84.7% | 54.5% | 3/3 |
| R32 | 4 |  Dominic ThiemClay | 341 | Felipe Meligeni AlvesClay | 6-2 4-6 6-1 | 3 | 124 | 3 | 2 | 54.7% | 73.2% | 67.6% | 0/1 |
| R16 | 133 | Pedro MartinezClay | 59 | Pablo AndujarClay | 6-1 6-4 | 3 | 86 | 4 | 0 | 74.5% | 73.2% | 57.1% | 3/3 |
| R16 | 128 | Gianluca MagerClay | 169 | Joao DominguesClay | 6-3 7-6(5) | 3 | 102 | 6 | 3 | 67.6% | 70.0% | 41.7% | 3/5 |
| R16 | 116 | Federico CoriaClay | 406 | Carlos AlcarazClay | 6-4 4-6 6-4 | 3 | 137 | 0 | 2 | 79.3% | 61.4% | 43.5% | 10/14 |
| R16 | 106 | Attila BalazsClay | 88 | Thiago MonteiroClay | 1-6 6-1 6-4 | 3 | 111 | 2 | 4 | 52.1% | 70.3% | 47.1% | 4/8 |
| R16 | 32 | Borna CoricClay | 206 | Thiago Seyboth WildClay | 6-3 1-6 7-6(5) | 3 | 139 | 7 | 2 | 59.6% | 75.5% | 47.2% | 9/12 |
| R16 | 25 | Cristian GarinClay | 86 | Federico DelbonisClay | 6-4 6-3 | 3 | 96 | 6 | 1 | 57.1% | 82.1% | 61.9% | 0/0 |
| R16 | 52 | Lorenzo SonegoClay | 23 | Dusan LajovicClay | 7-6(5) 7-6(5) | 3 | 129 | 4 | 2 | 66.7% | 75.9% | 44.8% | 2/4 |
| R16 | 4 | Dominic ThiemClay | 99 | Jaume MunarClay | 6-7(5) 6-3 6-4 | 3 | 161 | 4 | 5 | 74.7% | 67.6% | 52.0% | 6/8 |
| QF | 106 | Attila BalazsClay | 133 | Pedro MartinezClay | 2-6 6-4 6-2 | 3 | 148 | 4 | 5 | 52.6% | 60.0% | 46.7% | 9/14 |
| QF | 32 | Borna CoricClay | 52 | Lorenzo SonegoClay | 7-6(5) 6-3 | 3 | 129 | 4 | 1 | 57.0% | 81.6% | 45.9% | 8/8 |
| QF | 25 | Cristian GarinClay | 116 | Federico CoriaClay | 2-6 6-3 7-5 | 3 | 134 | 4 | 7 | 57.4% | 75.9% | 37.5% | 3/7 |
| QF | 128 | Gianluca MagerClay | 4 | Dominic ThiemClay | 7-6(4) 7-5 | 3 | 115 | 4 | 1 | 77.4% | 66.2% | 63.2% | 5/7 |
| SF | 128 | Gianluca MagerClay | 106 | Attila BalazsClay | 7-6(4) 4-6 7-6(2) | 3 | 172 | 6 | 2 | 68.9% | 70.2% | 44.7% | 8/12 |
| SF | 25 | Cristian GarinClay | 32 | Borna CoricClay | 6-4 7-5 | 3 | 104 | 2 | 5 | 60.7% | 78.4% | 37.5% | 1/4 |
| F | 25 | Cristian GarinClay | 128 | Gianluca MagerClay | 7-6(3) 7-5 | 3 | 94 | 8 | 0 | 75.6% | 62.9% | 65.0% | 4/6 |
