| R32 | 310 |  Alejandro FallaClay | 122 |  Alessandro GiannessiClay | 6-4 6-3 | 3 | 86 | 2 | 2 | 65.2% | 66.7% | 45.8% | 4/6 |
| R32 | 144 |  Roberto Carballes BaenaClay | 88 |  Rogerio Dutra SilvaClay | 6-3 6-1 | 3 | 76 | 8 | 7 | 49.1% | 71.4% | 62.1% | 4/4 |
| R32 | 641 |  Giovanni LapenttiClay | 85 | Thiago MonteiroClay | 6-3 6-2 | 3 | 66 | 7 | 2 | 59.2% | 82.8% | 60.0% | 2/2 |
| R32 | 564 |  Matthew EbdenClay | 184 |  Agustin VelottiClay | 2-6 6-4 6-3 | 3 | 97 | 12 | 7 | 60.8% | 79.7% | 42.1% | 7/9 |
| R32 | 116 | Nicolas KickerClay | 117 | Guido AndreozziClay | 4-6 6-3 6-4 | 3 | 112 | 4 | 7 | 58.9% | 82.1% | 48.7% | 8/9 |
| R32 | 137 |  Rajeev RamClay | 67 |  Alexandr DolgopolovClay | 3-6 7-6(4) 6-3 | 3 | 108 | 13 | 6 | 55.4% | 78.4% | 41.5% | 4/7 |
| R32 | 103 | Renzo OlivoClay | 290 | Emilio GomezClay | 5-7 6-2 7-6(5) | 3 | 144 | 5 | 3 | 53.1% | 71.2% | 56.5% | 5/9 |
| R32 | 97 | Santiago GiraldoClay | 126 |  Benjamin BeckerClay | 6-4 6-4 | 3 | 69 | 3 | 5 | 58.3% | 77.1% | 40.0% | 5/7 |
| R32 | 101 |  Janko TipsarevicClay | 114 | Daniel Gimeno-TraverClay | 4-1 RET | 3 | 20 | 0 | 1 | 40.0% | 100.0% | 66.7% | 0/0 |
| R32 | 106 |  Gerald MelzerClay | 69 | Horacio ZeballosClay | 6-7(4) 6-3 7-6(4) | 3 | 141 | 14 | 7 | 66.3% | 84.6% | 66.7% | 2/2 |
| R32 | 179 | Federico GaioClay | 129 | Joao SouzaClay | 5-7 6-4 7-5 | 3 | 139 | 11 | 11 | 48.5% | 85.4% | 56.9% | 6/7 |
| R32 | 156 |  Victor Estrella BurgosClay | 145 |  Andrej MartinClay | 3-6 6-2 6-4 | 3 | 112 | 1 | 5 | 65.3% | 70.2% | 60.0% | 3/6 |
| R16 | 30 | Albert Ramos-VinolasClay | 310 | Alejandro FallaClay | 6-2 7-5 | 3 | 87 | 2 | 2 | 66.7% | 80.0% | 40.0% | 3/5 |
| R16 | 144 | Roberto Carballes BaenaClay | 641 | Giovanni LapenttiClay | 6-3 6-4 | 3 | 82 | 0 | 5 | 61.3% | 76.3% | 45.8% | 1/2 |
| R16 | 46 | Paolo LorenziClay | 564 | Matthew EbdenClay | 6-4 6-4 | 3 | 66 | 5 | 1 | 49.1% | 88.5% | 63.0% | 0/0 |
| R16 | 137 | Rajeev RamClay | 116 | Nicolas KickerClay | 7-6(5) 6-3 | 3 | 79 | 5 | 3 | 63.2% | 86.0% | 60.0% | 3/3 |
| R16 | 103 | Renzo OlivoClay | 97 | Santiago GiraldoClay | 7-6(3) 2-6 6-3 | 3 | 107 | 4 | 8 | 51.8% | 75.0% | 53.7% | 6/10 |
| R16 | 100 | Thomaz BellucciClay | 101 | Janko TipsarevicClay | 7-6(8) 7-6(2) | 3 | 130 | 9 | 2 | 64.0% | 73.7% | 62.5% | 4/5 |
| R16 | 179 | Federico GaioClay | 106 | Gerald MelzerClay | 6-7(4) 6-3 7-6(2) | 3 | 150 | 11 | 10 | 52.3% | 78.9% | 63.5% | 4/5 |
| R16 | 156 | Victor Estrella BurgosClay | 18 |  Ivo KarlovicClay | 6-7(7) 7-6(5) 7-6(8) | 3 | 131 | 3 | 3 | 73.2% | 85.4% | 66.7% | 0/0 |
| QF | 30 | Albert Ramos-VinolasClay | 144 | Roberto Carballes BaenaClay | 7-5 4-6 6-2 | 3 | 174 | 4 | 8 | 52.2% | 79.7% | 44.4% | 4/5 |
| QF | 46 | Paolo LorenziClay | 137 | Rajeev RamClay | 6-3 6-4 | 3 | 66 | 6 | 3 | 41.1% | 87.0% | 69.7% | 3/3 |
| QF | 100 | Thomaz BellucciClay | 103 | Renzo OlivoClay | 6-2 6-1 | 3 | 53 | 6 | 2 | 51.4% | 100.0% | 82.4% | 0/0 |
| QF | 156 | Victor Estrella BurgosClay | 179 | Federico GaioClay | 6-4 6-4 | 3 | 79 | 6 | 1 | 65.6% | 82.5% | 57.1% | 2/2 |
| SF | 46 | Paolo LorenziClay | 30 | Albert Ramos-VinolasClay | 6-1 6-4 | 3 | 72 | 5 | 5 | 58.3% | 78.6% | 60.0% | 1/2 |
| SF | 156 | Victor Estrella BurgosClay | 100 | Thomaz BellucciClay | 7-6(4) 7-6(3) | 3 | 124 | 4 | 3 | 58.9% | 71.7% | 54.1% | 6/8 |
| F | 156 | Victor Estrella BurgosClay | 46 | Paolo LorenziClay | 6-7(2) 7-5 7-6(6) | 3 | 124 | 4 | 3 | 58.9% | 71.7% | 54.1% | 6/8 |
