| R32 | 154 |  Joao SouzaClay | 137 |  Facundo ArguelloClay | 6-3 7-6(7) | 3 | 91 | 11 | 1 | 67.7% | 84.1% | 57.1% | 1/1 |
| R32 | 81 |  Rajeev RamClay | 118 | Horacio ZeballosClay | 6-4 7-6(6) | 3 | 82 | 15 | 0 | 70.3% | 80.0% | 73.7% | 2/2 |
| R32 | 55 |  Albert Ramos-VinolasClay | 74 |  Dusan LajovicClay | 6-4 7-6(7) | 3 | 90 | 2 | 0 | 65.6% | 78.6% | 86.4% | 0/0 |
| R32 | 158 | Renzo OlivoClay | 151 |  Alejandro GonzalezClay | 6-7(1) 6-3 6-3 | 3 | 143 | 8 | 12 | 51.4% | 71.9% | 57.4% | 7/8 |
| R32 | 141 |  Andrej MartinClay | 83 | Marcel GranollersClay | 7-6(7) 6-2 | 3 | 104 | 4 | 3 | 60.3% | 76.3% | 52.0% | 4/7 |
| R32 | 58 |  Victor Estrella BurgosClay | 68 | Guido PellaClay | 6-4 6-4 | 3 | 76 | 3 | 2 | 66.1% | 76.9% | 60.0% | 2/2 |
| R32 | 67 | Pablo Carreno BustaClay | 115 | Rogerio Dutra SilvaClay | 6-3 6-1 | 3 | 57 | 3 | 0 | 58.1% | 84.0% | 66.7% | 1/1 |
| R32 | 76 | Inigo CervantesClay | 228 | Pere RibaClay | 6-7(6) 6-4 6-3 | 3 | 123 | 8 | 12 | 46.6% | 83.3% | 50.9% | 8/9 |
| R32 | 114 | Albert MontanesClay | 217 | Jozef KovalikClay | 6-3 3-6 6-4 | 3 | 108 | 6 | 7 | 57.6% | 81.6% | 47.2% | 3/5 |
| R32 | 59 |  Paolo LorenziClay | 364 |  Gonzalo EscobarClay | 6-1 6-2 | 3 | 92 | 5 | 1 | 50.8% | 68.8% | 64.5% | 8/8 |
| R32 | 126 | Alejandro FallaClay | 222 | Giovanni LapenttiClay | 6-2 6-3 | 3 | 73 | 3 | 0 | 64.0% | 75.0% | 55.6% | 1/2 |
| R32 | 129 | Roberto Carballes BaenaClay | 95 | Austin KrajicekClay | 6-4 6-3 | 3 | 72 | 9 | 1 | 62.5% | 83.3% | 66.7% | 1/1 |
| R16 | 22 | Feliciano LopezClay | 154 | Joao SouzaClay | 4-6 7-6(5) 6-2 | 3 | 118 | 14 | 4 | 58.0% | 84.3% | 64.9% | 3/4 |
| R16 | 55 | Albert Ramos-VinolasClay | 81 | Rajeev RamClay | 6-7(5) 6-3 7-5 | 3 | 140 | 6 | 5 | 60.0% | 73.0% | 71.4% | 4/5 |
| R16 | 158 | Renzo OlivoClay | 47 | Fernando VerdascoClay | 7-6(5) 3-6 6-3 | 3 | 117 | 15 | 7 | 48.9% | 82.2% | 51.1% | 6/10 |
| R16 | 58 | Victor Estrella BurgosClay | 141 | Andrej MartinClay | 7-5 6-1 | 3 | 71 | 4 | 1 | 66.7% | 70.0% | 80.0% | 6/6 |
| R16 | 67 | Pablo Carreno BustaClay | 76 | Inigo CervantesClay | 6-7(5) 7-6(2) 6-2 | 3 | 134 | 7 | 4 | 60.4% | 82.8% | 60.5% | 1/3 |
| R16 | 35 | Thomaz BellucciClay | 114 | Albert MontanesClay | 6-2 6-4 | 3 | 60 | 11 | 3 | 51.9% | 85.2% | 56.0% | 1/2 |
| R16 | 59 | Paolo LorenziClay | 126 | Alejandro FallaClay | 6-3 6-2 | 3 | 66 | 1 | 2 | 51.9% | 82.1% | 53.8% | 1/2 |
| R16 | 20 |  Bernard TomicClay | 129 | Roberto Carballes BaenaClay | 6-3 2-6 6-4 | 3 | 97 | 9 | 3 | 66.3% | 69.5% | 40.0% | 5/9 |
| QF | 55 | Albert Ramos-VinolasClay | 22 | Feliciano LopezClay | 7-5 4-3 RET | 3 | 88 | 4 | 1 | 72.0% | 83.3% | 50.0% | 1/2 |
| QF | 58 | Victor Estrella BurgosClay | 158 | Renzo OlivoClay | 6-4 6-7(5) 6-4 | 3 | 135 | 5 | 2 | 59.0% | 74.6% | 63.4% | 1/2 |
| QF | 35 | Thomaz BellucciClay | 67 | Pablo Carreno BustaClay | 7-6(0) 4-6 6-2 | 3 | 127 | 15 | 10 | 56.3% | 81.6% | 50.0% | 4/7 |
| QF | 59 | Paolo LorenziClay | 20 | Bernard TomicClay | 6-7(5) 7-5 6-3 | 3 | 128 | 25 | 3 | 53.8% | 91.2% | 55.1% | 3/3 |
| SF | 58 | Victor Estrella BurgosClay | 55 | Albert Ramos-VinolasClay | 6-2 7-6(5) | 3 | 84 | 7 | 2 | 57.7% | 90.0% | 63.6% | 0/1 |
| SF | 35 | Thomaz BellucciClay | 59 | Paolo LorenziClay | 3-6 6-2 6-3 | 3 | 114 | 4 | 6 | 58.4% | 68.9% | 71.9% | 5/7 |
| F | 58 | Victor Estrella BurgosClay | 35 | Thomaz BellucciClay | 4-6 7-6(5) 6-2 | 3 | 114 | 4 | 6 | 58.4% | 68.9% | 71.9% | 5/7 |
