| R32 | 105 |  Alejandro GonzalezClay | 116 |  Facundo BagnisClay | 6-2 6-4 | 3 | 75 | 3 | 6 | 53.6% | 76.7% | 57.7% | 1/2 |
| R32 | 72 |  Thomaz BellucciClay | 307 |  Giovanni LapenttiClay | 6-3 6-7(4) 6-2 | 3 | 145 | 14 | 5 | 57.9% | 78.2% | 55.0% | 6/7 |
| R32 | 124 | Horacio ZeballosClay | 156 |  Austin KrajicekClay | 7-6(3) 6-4 | 3 | 125 | 10 | 4 | 58.5% | 84.2% | 66.7% | 4/4 |
| R32 | 102 |  Albert MontanesClay | 146 | Facundo ArguelloClay | 6-1 6-3 | 3 | 66 | 1 | 2 | 68.8% | 69.7% | 73.3% | 2/3 |
| R32 | 219 |  Nicolas JarryClay | 309 | Gonzalo EscobarClay | 2-6 6-4 6-3 | 3 | 117 | 19 | 4 | 62.2% | 70.5% | 56.8% | 7/9 |
| R32 | 80 |  Dusan LajovicClay | 145 |  Luca VanniClay | 7-6(3) 6-4 | 3 | 102 | 6 | 2 | 68.7% | 71.7% | 57.1% | 3/5 |
| R32 | 154 |  Gerald MelzerClay | 74 | Andreas Haider-MaurerClay | 1-6 7-6(1) 7-6(6) | 3 | 143 | 8 | 4 | 62.0% | 74.6% | 36.6% | 12/17 |
| R32 | 122 | Alejandro FallaClay | 113 | Joao SouzaClay | 6-7(3) 6-1 6-4 | 3 | 147 | 4 | 10 | 50.5% | 71.4% | 49.1% | 3/6 |
| R32 | 68 | Paolo LorenziClay | 130 | Adrian Menendez-MaceirasClay | 4-6 6-4 7-6(1) | 3 | 139 | 3 | 4 | 54.3% | 78.0% | 57.1% | 1/3 |
| R32 | 73 |  Victor Estrella BurgosClay | 172 | Andre GhemClay | 6-4 6-4 | 3 | 69 | 2 | 0 | 61.8% | 76.5% | 61.9% | 0/1 |
| R32 | 265 | Renzo OlivoClay | 129 |  Evgeny DonskoyClay | 7-6(5) 3-6 6-1 | 3 | 139 | 2 | 13 | 51.9% | 72.2% | 58.0% | 9/11 |
| R32 | 89 | Daniel Gimeno-TraverClay | 160 |  Marton FucsovicsClay | 3-6 6-4 6-4 | 3 | 113 | 5 | 2 | 59.1% | 63.6% | 55.3% | 5/9 |
| R16 | 14 | Feliciano LopezClay | 105 | Alejandro GonzalezClay | 7-5 6-2 | 3 | 82 | 10 | 2 | 57.4% | 83.9% | 69.6% | 1/1 |
| R16 | 80 | Dusan LajovicClay | 219 | Nicolas JarryClay | 6-4 3-6 6-3 | 3 | 98 | 3 | 5 | 53.8% | 86.0% | 54.1% | 3/4 |
| R16 | 32 | Fernando VerdascoClay | 154 | Gerald MelzerClay | 7-6(2) 6-4 | 3 | 103 | 3 | 5 | 63.5% | 76.6% | 63.0% | 8/8 |
| R16 | 68 | Paolo LorenziClay | 122 | Alejandro FallaClay | 7-5 6-1 | 3 | 73 | 2 | 1 | 54.2% | 76.9% | 72.7% | 2/3 |
| R16 | 73 | Victor Estrella BurgosClay | 265 | Renzo OlivoClay | 7-6(5) 6-4 | 3 | 104 | 5 | 0 | 65.8% | 72.9% | 56.0% | 4/5 |
| R16 | 38 |  Martin KlizanClay | 89 | Daniel Gimeno-TraverClay | 6-3 5-7 7-5 | 3 | 129 | 6 | 7 | 65.4% | 70.6% | 38.9% | 7/12 |
| R16 | 72 | Thomaz BellucciClay | 124 | Horacio ZeballosClay | 6-2 3-6 7-6(6) | 3 | 143 | 5 | 5 | 49.6% | 70.7% | 49.2% | 13/15 |
| R16 | 102 | Albert MontanesClay | 31 | Santiago GiraldoClay | 7-6(1) 7-5 | 3 | 94 | 3 | 4 | 66.2% | 78.7% | 50.0% | 4/6 |
| QF | 14 | Feliciano LopezClay | 80 | Dusan LajovicClay | 4-6 7-5 6-1 | 3 | 117 | 6 | 3 | 52.7% | 75.0% | 62.8% | 5/6 |
| QF | 32 | Fernando VerdascoClay | 68 | Paolo LorenziClay | 6-1 6-2 | 3 | 49 | 4 | 3 | 75.6% | 90.3% | 50.0% | 0/0 |
| QF | 73 | Victor Estrella BurgosClay | 38 | Martin KlizanClay | 6-2 6-2 | 3 | 60 | 3 | 1 | 65.8% | 80.0% | 61.5% | 0/1 |
| QF | 72 | Thomaz BellucciClay | 102 | Albert MontanesClay | 6-3 7-6(6) | 3 | 97 | 10 | 3 | 54.4% | 83.8% | 54.8% | 3/4 |
| SF | 14 | Feliciano LopezClay | 32 | Fernando VerdascoClay | 7-6(5) 7-6(1) | 3 | 111 | 8 | 4 | 66.3% | 73.1% | 44.1% | 10/12 |
| SF | 73 | Victor Estrella BurgosClay | 72 | Thomaz BellucciClay | 7-6(5) 7-5 | 3 | 117 | 3 | 2 | 63.1% | 73.6% | 48.4% | 4/6 |
| F | 73 | Victor Estrella BurgosClay | 14 | Feliciano LopezClay | 6-2 6-7(5) 7-6(5) | 3 | 137 | 3 | 2 | 72.5% | 75.9% | 60.0% | 5/6 |
