| R32 | 75 |  Gael MonfilsClay | 66 |  Sam QuerreyClay | 6-4 7-5 | 3 | 81 | 9 | 1 | 75.0% | 78.6% | 78.6% | 0/0 |
| R32 | 4 |  Nikolay DavydenkoClay | 60 |  Ruben Ramirez HidalgoClay | 6-3 6-0 | 3 | 79 | 6 | 3 | 68.4% | 80.8% | 50.0% | 0/1 |
| R32 | 65 |  Nicolas LapenttiClay | 711 |  Martin VerkerkClay | 6-4 7-6(4) | 3 | 116 | 7 | 2 | 58.2% | 76.1% | 39.4% | 6/8 |
| R32 | 71 | Michael RussellClay | 59 |  Martin Vassallo ArguelloClay | 6-1 7-6(4) | 3 | 109 | 2 | 2 | 67.2% | 72.1% | 52.4% | 3/5 |
| R32 | 47 | Juan MonacoClay | 30 |  Jurgen MelzerClay | 6-3 6-1 | 3 | 73 | 5 | 0 | 62.5% | 65.7% | 61.9% | 5/6 |
| R32 | 7 |  Ivan LjubicicClay | 67 |  Amer DelicClay | 7-6(7) 7-6(8) | 3 | 112 | 14 | 1 | 50.6% | 79.1% | 61.9% | 1/2 |
| R32 | 82 |  Luis HornaClay | 224 |  Alexandr DolgopolovClay | 6-3 6-0 | 3 | 43 | 10 | 3 | 65.0% | 92.3% | 57.1% | 0/0 |
| R32 | 51 | Albert MontanesClay | 111 |  Daniele BraccialiClay | 6-0 6-4 | 3 | 75 | 4 | 1 | 58.9% | 72.7% | 60.9% | 6/6 |
| R32 | 141 | Mathieu MontcourtClay | 54 |  Max MirnyiClay | 6-4 6-4 | 3 | 79 | 1 | 0 | 62.5% | 83.3% | 61.1% | 0/2 |
| R32 | 64 | Vincent SpadeaClay | 27 |  Dominik HrbatyClay | 6-1 7-5 | 3 | 96 | 4 | 0 | 52.3% | 67.6% | 67.7% | 5/6 |
| R32 | 97 | Diego HartfieldClay | 43 |  Stan WawrinkaClay | 6-2 6-4 | 3 | 75 | 3 | 2 | 66.0% | 71.4% | 72.2% | 2/2 |
| R32 | 53 | Potito StaraceClay | 68 | Stefan KoubekClay | 6-4 6-4 | 3 | 83 | 2 | 2 | 77.1% | 70.4% | 56.3% | 6/6 |
| R32 | 16 |  Lleyton HewittClay | 83 | Sergio RoitmanClay | 6-2 6-2 | 3 | 67 | 3 | 0 | 54.2% | 69.2% | 59.1% | 2/3 |
| R32 | 41 |  Hyung-Taik LeeClay | 104 |  Danai UdomchokeClay | 6-3 6-0 | 3 | 51 | 3 | 2 | 72.1% | 77.4% | 58.3% | 0/1 |
| R32 | 81 |  Kristian PlessClay | 98 | Carlos BerlocqClay | 6-3 6-3 | 3 | 70 | 5 | 1 | 57.8% | 80.8% | 68.4% | 3/4 |
| R32 | 3 | Andy RoddickClay | 99 | Alexander PeyaClay | 6-4 7-5 | 3 | 80 | 2 | 0 | 68.0% | 88.2% | 87.5% | 0/0 |
| R16 | 4 | Nikolay DavydenkoClay | 65 | Nicolas LapenttiClay | 6-4 6-2 | 3 | 85 | 2 | 1 | 76.0% | 81.6% | 58.3% | 5/5 |
| R16 | 47 | Juan MonacoClay | 71 | Michael RussellClay | 6-3 6-1 | 3 | 62 | 5 | 0 | 76.3% | 86.2% | 77.8% | 0/0 |
| R16 | 82 | Luis HornaClay | 7 | Ivan LjubicicClay | 7-6(5) 6-4 | 3 | 89 | 5 | 0 | 69.4% | 86.0% | 68.4% | 1/1 |
| R16 | 51 | Albert MontanesClay | 141 | Mathieu MontcourtClay | 7-6(6) 6-1 | 3 | 103 | 5 | 5 | 50.0% | 72.7% | 48.5% | 1/3 |
| R16 | 97 | Diego HartfieldClay | 64 | Vincent SpadeaClay | 6-4 7-6(5) | 3 | 101 | 3 | 3 | 66.3% | 67.9% | 48.1% | 2/4 |
| R16 | 16 | Lleyton HewittClay | 53 | Potito StaraceClay | 6-4 6-4 | 3 | 90 | 4 | 0 | 51.5% | 82.9% | 57.6% | 5/5 |
| R16 | 75 | Gael MonfilsClay | 41 | Hyung-Taik LeeClay | 7-6(5) 6-4 | 3 | 99 | 6 | 2 | 68.1% | 77.6% | 43.5% | 1/3 |
| R16 | 3 | Andy RoddickClay | 81 | Kristian PlessClay | 6-4 6-3 | 3 | 66 | 6 | 2 | 69.4% | 88.2% | 66.7% | 0/0 |
| QF | 47 | Juan MonacoClay | 4 | Nikolay DavydenkoClay | 6-2 6-7(5) 6-4 | 3 | 159 | 5 | 2 | 66.1% | 62.5% | 48.8% | 10/14 |
| QF | 82 | Luis HornaClay | 51 | Albert MontanesClay | 7-6(4) 6-7(2) 6-1 | 3 | 133 | 5 | 1 | 59.0% | 76.3% | 58.5% | 5/6 |
| QF | 16 | Lleyton HewittClay | 97 | Diego HartfieldClay | 6-2 6-2 | 3 | 73 | 6 | 0 | 51.1% | 73.9% | 68.2% | 2/3 |
| QF | 75 | Gael MonfilsClay | 3 | Andy RoddickClay | 7-5 6-3 | 3 | 164 | 7 | 4 | 45.6% | 80.6% | 56.8% | 5/6 |
| SF | 47 | Juan MonacoClay | 82 | Luis HornaClay | 6-4 6-4 | 3 | 78 | 2 | 1 | 58.5% | 61.3% | 72.7% | 2/4 |
| SF | 75 | Gael MonfilsClay | 16 | Lleyton HewittClay | 6-4 7-5 | 3 | 100 | 5 | 4 | 49.3% | 78.4% | 39.5% | 6/8 |
| F | 47 | Juan MonacoClay | 75 | Gael MonfilsClay | 7-6(3) 6-0 | 3 | 81 | 1 | 0 | 60.8% | 77.4% | 70.0% | 0/1 |
