| QF | 111 |  Andrei PavelClay | 97 |  Oliver MarachClay | 6-4 6-2 | 3 | 88 | 5 | 0 | 79.4% | 68.0% | 69.2% | 4/4 |
| R32 | 80 |  Ruben Ramirez HidalgoClay | 128 |  Nicolas LapenttiClay | 4-6 6-4 6-3 | 3 | 191 | 2 | 3 | 62.4% | 66.2% | 46.3% | 7/10 |
| R32 | 6 |  Nikolay DavydenkoClay | 106 |  Tomas ZibClay | 6-3 6-0 | 3 | 66 | 8 | 0 | 78.8% | 80.8% | 14.3% | 1/3 |
| R32 | 78 |  Potito StaraceClay | 68 | Alberto MartinClay | 7-5 7-6(5) | 3 | 80 | 1 | 1 | 80.9% | 89.1% | 53.8% | 2/2 |
| R32 | 42 | Nicolas AlmagroClay | 76 |  Christophe RochusClay | 6-3 6-4 | 3 | 61 | 5 | 1 | 69.8% | 89.2% | 56.3% | 0/0 |
| R32 | 43 |  Richard GasquetClay | 24 |  Dominik HrbatyClay | 6-0 4-6 6-3 | 3 | 86 | 11 | 0 | 68.8% | 71.7% | 66.7% | 0/1 |
| R32 | 75 | Jurgen MelzerClay | 123 | Stefan KoubekClay | 6-4 7-5 | 3 | 98 | 3 | 4 | 57.1% | 61.5% | 53.8% | 8/11 |
| R32 | 127 | Jiri NovakClay | 62 |  Bjorn PhauClay | 6-3 6-3 | 3 | 61 | 3 | 0 | 69.6% | 81.3% | 57.1% | 1/2 |
| R32 | 38 |  Juan Ignacio ChelaClay | 88 |  Jimmy WangClay | 6-3 6-1 | 3 | 66 | 2 | 3 | 50.0% | 84.6% | 42.3% | 3/5 |
| R32 | 53 |  Luis HornaClay | 73 |  Wesley MoodieClay | 7-6(3) 6-3 | 3 | 84 | 4 | 0 | 72.7% | 79.2% | 77.8% | 1/1 |
| R32 | 69 | Andreas SeppiClay | 85 | Lukas DlouhyClay | 6-3 6-4 | 3 | 68 | 2 | 2 | 56.7% | 70.6% | 57.7% | 3/5 |
| R32 | 66 |  Gilles MullerClay | 309 | Leonardo AzzaroClay | 6-3 7-6(6) | 3 | 93 | 14 | 2 | 63.4% | 78.8% | 50.0% | 8/8 |
| R32 | 114 | Juan MonacoClay | 34 | Dmitry TursunovClay | 7-6(4) 6-2 | 3 | 93 | 1 | 3 | 56.7% | 73.7% | 62.1% | 1/2 |
| R32 | 48 | Gilles SimonClay | 289 | Torsten PoppClay | 7-5 6-4 | 3 | 241 | 6 | 2 | 63.4% | 62.2% | 57.7% | 2/5 |
| R32 | 97 | Oliver MarachClay | 71 |  Vincent SpadeaClay | 6-4 6-3 | 3 | 96 | 9 | 2 | 62.1% | 73.2% | 48.0% | 7/8 |
| R32 | 111 | Andrei PavelClay | 82 | Carlos BerlocqClay | 7-5 6-2 | 3 | 83 | 2 | 1 | 72.3% | 74.5% | 44.4% | 7/9 |
| R32 | 89 |  Marcos DanielClay | 14 |  Lleyton HewittClay | 3-6 6-3 7-6(3) | 3 | 153 | 5 | 3 | 60.2% | 70.8% | 39.5% | 9/14 |
| R16 | 6 | Nikolay DavydenkoClay | 80 | Ruben Ramirez HidalgoClay | 6-2 6-4 | 3 | 68 | 6 | 1 | 62.0% | 80.6% | 52.6% | 3/4 |
| R16 | 78 | Potito StaraceClay | 42 | Nicolas AlmagroClay | 4-6 6-4 6-1 | 3 | 106 | 2 | 1 | 80.2% | 61.2% | 61.9% | 8/10 |
| R16 | 75 | Jurgen MelzerClay | 43 | Richard GasquetClay | 6-0 1-1 RET | 3 | 29 | 4 | 0 | 65.2% | 86.7% | 62.5% | 1/1 |
| R16 | 127 | Jiri NovakClay | 38 | Juan Ignacio ChelaClay | 6-1 3-6 6-2 | 3 | 89 | 5 | 2 | 67.5% | 66.7% | 57.7% | 2/4 |
| R16 | 53 | Luis HornaClay | 69 | Andreas SeppiClay | 6-1 6-1 | 3 | 58 | 7 | 1 | 68.2% | 70.0% | 64.3% | 2/2 |
| R16 | 114 | Juan MonacoClay | 66 | Gilles MullerClay | 6-2 6-0 | 3 | 53 | 1 | 2 | 56.8% | 72.0% | 68.4% | 1/1 |
| R16 | 97 | Oliver MarachClay | 48 | Gilles SimonClay | 7-6(3) 6-1 | 3 | 97 | 4 | 0 | 63.2% | 81.4% | 48.0% | 2/3 |
| R16 | 111 | Andrei PavelClay | 89 | Marcos DanielClay | 7-5 6-0 | 3 | 70 | 3 | 1 | 60.7% | 70.6% | 54.5% | 3/5 |
| QF | 6 | Nikolay DavydenkoClay | 78 | Potito StaraceClay | 6-2 6-1 | 3 | 49 | 6 | 1 | 69.2% | 88.9% | 66.7% | 0/0 |
| QF | 127 | Jiri NovakClay | 75 | Jurgen MelzerClay | 6-7(7) 6-4 6-4 | 3 | 141 | 9 | 3 | 71.5% | 65.6% | 45.9% | 13/16 |
| QF | 53 | Luis HornaClay | 114 | Juan MonacoClay | 6-3 6-4 | 3 | 89 | 7 | 0 | 57.1% | 75.0% | 66.7% | 7/7 |
| SF | 6 | Nikolay DavydenkoClay | 127 | Jiri NovakClay | 6-2 6-2 | 3 | 66 | 3 | 0 | 68.9% | 74.2% | 57.1% | 2/3 |
| SF | 111 | Andrei PavelClay | 53 | Luis HornaClay | W/O | 3 | - | 3 | 0 | 68.9% | 74.2% | 57.1% | 2/3 |
| F | 6 | Nikolay DavydenkoClay | 111 | Andrei PavelClay | 6-0 6-3 | 3 | 63 | 5 | 1 | 52.8% | 78.9% | 76.5% | 0/0 |
