| R32 | 13 |  Nikolay DavydenkoClay | 145 |  Michal MertinakClay | 6-3 6-2 | 3 | 73 | 3 | 2 | 71.7% | 66.7% | 69.2% | 1/2 |
| R32 | 92 |  Sjeng SchalkenClay | 68 |  Kevin KimClay | 6-3 2-6 6-3 | 3 | 113 | 1 | 3 | 63.9% | 56.5% | 60.0% | 9/13 |
| R32 | 89 |  Felix MantillaClay | 333 | Francisco FoguesClay | 7-6(10) 7-5 | 3 | 113 | 1 | 3 | 51.3% | 82.1% | 51.4% | 2/4 |
| R32 | 39 |  Mariano PuertaClay | 87 | Alex CalatravaClay | 7-5 6-2 | 3 | 77 | 3 | 2 | 63.6% | 80.0% | 50.0% | 3/5 |
| R32 | 69 | Jose AcasusoClay | 38 | Igor AndreevClay | 3-6 6-3 6-2 | 3 | 105 | 4 | 2 | 54.1% | 77.5% | 44.1% | 4/7 |
| R32 | 78 | Nicolas AlmagroClay | 79 |  Ivo KarlovicClay | 7-6(2) 7-6(3) | 3 | 80 | 2 | 2 | 72.5% | 77.6% | 68.2% | 6/7 |
| R32 | 82 |  Victor HanescuClay | 66 |  Jan HernychClay | 4-6 6-1 6-3 | 3 | 114 | 3 | 2 | 66.2% | 66.7% | 65.4% | 3/5 |
| R32 | 287 |  Michael KohlmannClay | 61 | Tomas ZibClay | 2-6 7-6(7) 6-4 | 3 | 126 | 6 | 7 | 67.5% | 63.9% | 40.0% | 11/17 |
| R32 | 63 |  Potito StaraceClay | 74 | Philipp KohlschreiberClay | 6-3 7-6(2) | 3 | 91 | 3 | 6 | 74.4% | 67.2% | 38.1% | 3/6 |
| R32 | 129 | David SanchezClay | 72 | Robby GinepriClay | 3-6 7-6(5) 6-4 | 3 | 134 | 4 | 5 | 66.7% | 61.5% | 46.2% | 7/13 |
| R32 | 70 |  Gilles MullerClay | 106 | Albert MontanesClay | 6-2 RET | 3 | 35 | 3 | 1 | 58.8% | 100.0% | 85.7% | 0/0 |
| R32 | 47 |  Jurgen MelzerClay | 306 | Marco MirneggClay | 6-3 6-1 | 3 | 66 | 4 | 0 | 46.9% | 78.3% | 57.7% | 4/5 |
| R32 | 60 |  Luis HornaClay | 216 | Daniel KoellererClay | 4-6 6-2 6-4 | 3 | 159 | 8 | 3 | 62.4% | 69.8% | 52.6% | 7/8 |
| R32 | 75 | Guillermo Garcia-LopezClay | 102 |  Jean-Rene LisnardClay | 6-3 7-5 | 3 | 100 | 1 | 2 | 69.7% | 73.9% | 40.0% | 2/4 |
| R32 | 65 | Davide SanguinettiClay | 81 | Jiri VanekClay | 6-4 6-2 | 3 | 58 | 9 | 5 | 59.1% | 84.6% | 55.6% | 0/1 |
| R32 | 48 |  Christophe RochusClay | 36 |  Paradorn SrichaphanClay | 6-1 6-3 | 3 | 56 | 2 | 0 | 56.3% | 70.4% | 52.4% | 1/3 |
| R16 | 13 | Nikolay DavydenkoClay | 92 | Sjeng SchalkenClay | 6-3 6-1 | 3 | 74 | 5 | 4 | 52.8% | 82.1% | 60.0% | 7/7 |
| R16 | 89 | Felix MantillaClay | 39 | Mariano PuertaClay | 7-6(2) 4-6 7-5 | 3 | 157 | 11 | 8 | 52.7% | 79.7% | 51.6% | 8/9 |
| R16 | 69 | Jose AcasusoClay | 78 | Nicolas AlmagroClay | 6-4 6-4 | 3 | 86 | 2 | 2 | 59.0% | 83.3% | 56.0% | 4/4 |
| R16 | 287 | Michael KohlmannClay | 82 | Victor HanescuClay | 6-3 2-6 7-6(2) | 3 | 107 | 7 | 2 | 66.7% | 69.0% | 51.7% | 1/5 |
| R16 | 129 | David SanchezClay | 63 | Potito StaraceClay | 6-4 6-4 | 3 | 77 | 3 | 1 | 59.1% | 69.2% | 63.0% | 4/5 |
| R16 | 47 | Jurgen MelzerClay | 70 | Gilles MullerClay | 6-2 6-7(5) 7-5 | 3 | 147 | 4 | 4 | 62.6% | 75.8% | 48.6% | 5/7 |
| R16 | 75 | Guillermo Garcia-LopezClay | 60 | Luis HornaClay | 6-1 6-4 | 3 | 82 | 0 | 3 | 67.6% | 62.5% | 56.5% | 8/10 |
| R16 | 48 | Christophe RochusClay | 65 | Davide SanguinettiClay | 6-3 6-3 | 3 | 61 | 0 | 3 | 54.2% | 65.4% | 68.2% | 2/4 |
| QF | 13 | Nikolay DavydenkoClay | 89 | Felix MantillaClay | 6-3 7-5 | 3 | 93 | 6 | 5 | 50.0% | 83.3% | 33.3% | 1/4 |
| QF | 69 | Jose AcasusoClay | 287 | Michael KohlmannClay | 6-2 7-6(5) | 3 | 82 | 5 | 2 | 56.7% | 81.6% | 58.6% | 2/2 |
| QF | 47 | Jurgen MelzerClay | 129 | David SanchezClay | 5-7 6-4 6-4 | 3 | 127 | 3 | 5 | 56.8% | 60.3% | 50.0% | 9/14 |
| QF | 48 | Christophe RochusClay | 75 | Guillermo Garcia-LopezClay | 6-3 6-4 | 3 | 75 | 0 | 2 | 61.9% | 74.4% | 54.2% | 1/2 |
| SF | 13 | Nikolay DavydenkoClay | 69 | Jose AcasusoClay | 6-4 6-2 | 3 | 80 | 6 | 2 | 56.9% | 72.4% | 68.2% | 1/2 |
| SF | 47 | Jurgen MelzerClay | 48 | Christophe RochusClay | 6-4 6-3 | 3 | 71 | 3 | 1 | 60.4% | 65.6% | 57.1% | 1/4 |
| F | 13 | Nikolay DavydenkoClay | 47 | Jurgen MelzerClay | 6-3 2-6 6-4 | 3 | 135 | 2 | 4 | 72.5% | 65.5% | 36.4% | 8/12 |
