| R32 | 6 |  Andy RoddickClay | 61 |  Alberto MartinClay | 6-1 7-6(5) | 3 | 86 | 5 | 2 | 66.7% | 81.6% | 47.4% | 2/4 |
| R32 | 354 |  Philipp KohlschreiberClay | 89 |  Jurgen MelzerClay | 6-4 0-6 6-2 | 3 | 95 | 1 | 4 | 64.9% | 66.0% | 40.7% | 4/8 |
| R32 | 75 | Brian VahalyClay | 68 |  Kenneth CarlsenClay | 7-5 5-7 6-3 | 3 | 150 | 2 | 0 | 76.5% | 64.0% | 73.9% | 3/7 |
| R32 | 77 |  Richard KrajicekClay | 38 | Jan-Michael GambillClay | 7-5 3-6 6-3 | 3 | 118 | 13 | 2 | 52.3% | 77.8% | 48.8% | 4/7 |
| R32 | 78 |  Mario AncicClay | 40 | Taylor DentClay | 2-6 7-6(3) 6-4 | 3 | 130 | 6 | 3 | 53.5% | 66.7% | 51.1% | 5/9 |
| R32 | 101 |  Jean-Rene LisnardClay | 85 |  Michel KratochvilClay | 6-3 6-4 | 3 | 79 | 1 | 2 | 47.1% | 66.7% | 51.9% | 2/5 |
| R32 | 87 |  Davide SanguinettiClay | 67 |  Sargis SargsianClay | 7-5 7-6(5) | 3 | 121 | 1 | 1 | 59.8% | 71.4% | 51.5% | 4/6 |
| R32 | 57 | David SanchezClay | 251 | Markus HipflClay | 6-1 6-0 | 3 | 57 | 2 | 0 | 68.4% | 69.2% | 75.0% | 3/4 |
| R32 | 56 | Martin VerkerkClay | 48 |  Karol KuceraClay | 6-2 6-1 | 3 | 60 | 4 | 6 | 58.7% | 74.1% | 47.4% | 4/5 |
| R32 | 63 | Dominik HrbatyClay | 88 |  Luis HornaClay | 6-3 7-5 | 3 | 105 | 4 | 6 | 53.0% | 80.0% | 41.9% | 5/7 |
| R32 | 71 |  Flavio SarettaClay | 86 | Andre SaClay | 6-2 6-2 | 3 | 70 | 2 | 0 | 44.9% | 63.6% | 59.3% | 4/6 |
| R32 | 105 |  Irakli LabadzeClay | 342 | Jan WeinzierlClay | 6-4 4-6 6-4 | 3 | 118 | 5 | 12 | 69.3% | 67.1% | 25.8% | 12/17 |
| R32 | 36 |  Nikolay DavydenkoClay | 72 | Karol BeckClay | 6-4 6-2 | 3 | 66 | 5 | 0 | 57.1% | 78.6% | 61.9% | 1/2 |
| R32 | 60 |  Hyung-Taik LeeClay | 495 | Hugo ArmandoClay | 4-6 6-4 6-3 | 3 | 124 | 4 | 2 | 65.4% | 73.6% | 39.3% | 2/6 |
| R32 | 82 |  Antony DupuisClay | 80 | Olivier MutisClay | 6-3 6-1 | 3 | 58 | 2 | 0 | 71.1% | 65.6% | 76.9% | 0/1 |
| R32 | 9 | Albert CostaClay | 725 |  Nenad ZimonjicClay | 6-7(4) 6-1 6-3 | 3 | 117 | 3 | 1 | 61.3% | 71.4% | 77.4% | 2/3 |
| R16 | 6 | Andy RoddickClay | 354 | Philipp KohlschreiberClay | 6-3 6-4 | 3 | 54 | 11 | 0 | 60.0% | 86.7% | 60.0% | 0/1 |
| R16 | 77 | Richard KrajicekClay | 75 | Brian VahalyClay | 6-2 2-6 6-3 | 3 | 102 | 6 | 4 | 49.4% | 72.1% | 47.7% | 7/10 |
| R16 | 78 | Mario AncicClay | 101 | Jean-Rene LisnardClay | 6-4 7-5 | 3 | 104 | 3 | 3 | 59.2% | 64.4% | 48.4% | 6/9 |
| R16 | 57 | David SanchezClay | 87 | Davide SanguinettiClay | 6-4 6-4 | 3 | 102 | 1 | 0 | 63.6% | 58.9% | 50.0% | 6/9 |
| R16 | 56 | Martin VerkerkClay | 63 | Dominik HrbatyClay | 6-4 7-5 | 3 | 81 | 6 | 4 | 53.8% | 74.3% | 53.3% | 3/5 |
| R16 | 71 | Flavio SarettaClay | 105 | Irakli LabadzeClay | 6-1 6-1 | 3 | 67 | 5 | 2 | 55.1% | 77.8% | 63.6% | 3/3 |
| R16 | 36 | Nikolay DavydenkoClay | 60 | Hyung-Taik LeeClay | 6-4 6-3 | 3 | 81 | 3 | 3 | 61.2% | 68.3% | 61.5% | 10/11 |
| R16 | 82 | Antony DupuisClay | 9 | Albert CostaClay | 6-4 2-6 6-2 | 3 | 123 | 9 | 1 | 63.6% | 77.6% | 50.0% | 3/5 |
| QF | 6 | Andy RoddickClay | 77 | Richard KrajicekClay | 7-5 6-1 | 3 | 64 | 9 | 1 | 74.6% | 70.5% | 66.7% | 3/4 |
| QF | 57 | David SanchezClay | 78 | Mario AncicClay | 6-1 6-4 | 3 | 64 | 1 | 3 | 59.2% | 65.5% | 40.0% | 1/4 |
| QF | 56 | Martin VerkerkClay | 71 | Flavio SarettaClay | 7-6(4) 7-6(2) | 3 | 113 | 7 | 4 | 55.8% | 76.7% | 67.6% | 1/2 |
| QF | 36 | Nikolay DavydenkoClay | 82 | Antony DupuisClay | 7-5 6-1 | 3 | 100 | 5 | 2 | 67.2% | 68.9% | 40.9% | 6/8 |
| SF | 6 | Andy RoddickClay | 57 | David SanchezClay | 6-2 2-0 RET | 3 | 49 | 1 | 0 | 54.3% | 84.2% | 56.3% | 0/0 |
| SF | 36 | Nikolay DavydenkoClay | 56 | Martin VerkerkClay | 7-5 6-1 | 3 | 93 | 2 | 3 | 71.9% | 67.4% | 66.7% | 4/4 |
| F | 6 | Andy RoddickClay | 36 | Nikolay DavydenkoClay | 6-3 6-2 | 3 | 64 | 3 | 1 | 63.5% | 75.8% | 57.9% | 1/2 |
