| R32 | 29 |  Ronald AgenorClay | 122 |  Jose Francisco AlturClay | 6-3 2-6 6-4 | 3 | 111 | 0 | 2 | 65.4% | 66.0% | 53.6% | 6/10 |
| R32 | 550 |  Andrei MedvedevClay | 108 |  Nuno MarquesClay | 7-5 2-0 RET | 3 | 71 | 3 | 3 | 60.0% | 70.4% | 38.9% | 1/3 |
| R32 | 95 |  Bart WuytsClay | 118 |  Pedro RebolledoClay | 7-6(6) 7-6(2) | 3 | 165 | 0 | 2 | 70.8% | 54.4% | 35.7% | 8/14 |
| R32 | 72 |  Carl-Uwe SteebClay | 121 |  Tarik BenhabilesClay | 6-4 4-6 6-2 | 3 | 125 | 2 | 2 | 44.3% | 71.8% | 53.1% | 2/5 |
| R32 | 44 | Fabrice SantoroClay | 188 |  Massimo CierroClay | 6-1 6-1 | 3 | 60 | 1 | 0 | 41.9% | 66.7% | 76.0% | 2/2 |
| R32 | 87 | Cedric PiolineClay | 665 | Andrea GaudenziClay | 6-1 6-4 | 3 | 72 | 2 | 4 | 66.1% | 82.9% | 28.6% | 6/7 |
| R32 | 116 |  Thomas MusterClay | 104 | Thierry ChampionClay | 4-6 6-0 6-3 | 3 | 112 | 0 | 2 | 78.8% | 65.1% | 58.8% | 5/8 |
| R32 | 94 | Stefano PescosolidoClay | 62 | Javier SanchezClay | 5-7 6-3 6-1 | 3 | 110 | 0 | 3 | 60.0% | 64.6% | 53.1% | 3/7 |
| R32 | 50 | Renzo FurlanClay | 201 | Andres VysandClay | 6-2 6-1 | 3 | 70 | 3 | 0 | 64.4% | 72.4% | 75.0% | 1/1 |
| R32 | 130 |  Roberto AzarClay | 146 |  Slava DosedelClay | 6-3 3-6 6-2 | 3 | 106 | 2 | 1 | 62.7% | 69.0% | 48.0% | 4/8 |
| R32 | 176 | Carlos CostaClay | 159 | Frederic FontangClay | 6-2 6-0 | 3 | 60 | 2 | 0 | 50.9% | 57.1% | 66.7% | 7/8 |
| R32 | 43 | Jordi ArreseClay | 111 | Joao Cunha-SilvaClay | 6-3 7-6(5) | 3 | 105 | 0 | 1 | 68.0% | 62.7% | 41.7% | 8/12 |
| R32 | 78 | Jean-Philippe FleurianClay | 202 | Markus NaewieClay | 6-1 7-5 | 3 | 90 | 0 | 2 | 60.3% | 71.4% | 56.5% | 1/3 |
| R32 | 89 |  Lars JonssonClay | 119 | Claudio PistolesiClay | 6-3 6-2 | 3 | 55 | 1 | 1 | 77.8% | 82.9% | 50.0% | 0/1 |
| R32 | 98 | Eduardo MassoClay | 234 | Francesco CancellottiClay | 6-2 7-5 | 3 | 77 | 1 | 1 | 91.5% | 59.3% | 40.0% | 1/4 |
| R32 | 40 |  Mark KoevermansClay | 114 | Gabriel MarkusClay | 6-2 6-7(2) 6-1 | 3 | 132 | 5 | 4 | 53.8% | 83.3% | 52.8% | 3/5 |
| R16 | 29 | Ronald AgenorClay | 550 | Andrei MedvedevClay | 3-6 6-0 7-6(7) | 3 | 116 | 1 | 2 | 65.2% | 56.7% | 46.9% | 1/7 |
| R16 | 72 | Carl-Uwe SteebClay | 95 | Bart WuytsClay | 6-3 2-6 6-1 | 3 | 130 | 5 | 2 | 51.4% | 63.6% | 40.4% | 9/14 |
| R16 | 87 | Cedric PiolineClay | 44 | Fabrice SantoroClay | 6-4 6-1 | 3 | 92 | 3 | 2 | 52.3% | 70.6% | 58.1% | 2/3 |
| R16 | 116 | Thomas MusterClay | 94 | Stefano PescosolidoClay | 6-4 6-3 | 3 | 80 | 3 | 0 | 79.6% | 74.4% | 63.6% | 3/3 |
| R16 | 130 | Roberto AzarClay | 50 | Renzo FurlanClay | 2-6 6-4 6-3 | 3 | 135 | 3 | 3 | 75.3% | 62.9% | 60.9% | 9/12 |
| R16 | 43 | Jordi ArreseClay | 176 | Carlos CostaClay | 3-6 6-2 6-3 | 3 | 120 | 0 | 2 | 75.0% | 70.4% | 61.1% | 2/4 |
| R16 | 78 | Jean-Philippe FleurianClay | 89 | Lars JonssonClay | 4-6 7-5 6-4 | 3 | 140 | 6 | 6 | 51.0% | 67.3% | 51.1% | 2/7 |
| R16 | 98 | Eduardo MassoClay | 40 | Mark KoevermansClay | 6-4 6-4 | 3 | 105 | 0 | 1 | 81.9% | 54.2% | 84.6% | 1/3 |
| QF | 72 | Carl-Uwe SteebClay | 29 | Ronald AgenorClay | 6-1 6-4 | 3 | 90 | 5 | 1 | 50.8% | 67.7% | 50.0% | 3/5 |
| QF | 116 | Thomas MusterClay | 87 | Cedric PiolineClay | 4-6 7-6(3) 6-2 | 3 | 169 | 0 | 4 | 78.5% | 62.7% | 39.3% | 11/16 |
| QF | 43 | Jordi ArreseClay | 130 | Roberto AzarClay | 6-4 7-5 | 3 | 116 | 0 | 2 | 67.1% | 64.7% | 52.0% | 7/10 |
| QF | 98 | Eduardo MassoClay | 78 | Jean-Philippe FleurianClay | 7-5 6-1 | 3 | 85 | 0 | 3 | 78.2% | 72.1% | 25.0% | 2/4 |
| SF | 72 | Carl-Uwe SteebClay | 116 | Thomas MusterClay | 7-5 6-4 | 3 | 110 | 6 | 0 | 50.8% | 63.6% | 43.8% | 2/6 |
| SF | 43 | Jordi ArreseClay | 98 | Eduardo MassoClay | 7-6(5) 6-3 | 3 | 113 | 0 | 2 | 78.8% | 58.2% | 55.6% | 8/12 |
| F | 72 | Carl-Uwe SteebClay | 43 | Jordi ArreseClay | 6-3 6-4 | 3 | 108 | 3 | 0 | 59.8% | 69.2% | 51.4% | 11/11 |
