| R32 | 28 |  Fernando VerdascoClay | 65 |  Daniele BraccialiClay | 5-7 6-4 6-4 | 3 | 145 | 4 | 3 | 77.0% | 67.5% | 52.2% | 5/8 |
| R32 | 79 |  Jan HajekClay | 362 | Bohdan UlihrachClay | 6-3 7-6(2) | 3 | 79 | 5 | 3 | 59.2% | 68.9% | 35.5% | 10/14 |
| R32 | 398 | Gianluca NasoClay | 91 | Jiri VanekClay | 1-2 RET | 3 | 17 | 0 | 1 | 45.5% | 80.0% | 33.3% | 1/2 |
| R32 | 60 | Ruben Ramirez HidalgoClay | 94 | Alessio Di MauroClay | 7-6(7) 6-3 | 3 | 127 | 2 | 1 | 52.7% | 71.8% | 54.3% | 3/5 |
| R32 | 46 |  Gilles SimonClay | 69 | Andreas SeppiClay | 6-0 6-7(6) 6-2 | 3 | 125 | 4 | 1 | 50.0% | 58.7% | 67.4% | 6/8 |
| R32 | 357 |  Mariano ZabaletaClay | 101 | Olivier PatienceClay | 7-5 3-6 6-3 | 3 | 136 | 4 | 3 | 64.7% | 71.2% | 50.0% | 2/4 |
| R32 | 242 | Fabio FogniniClay | 156 |  Juan Antonio MarinClay | 7-6(3) 6-3 | 3 | 124 | 3 | 4 | 55.4% | 80.5% | 42.4% | 0/2 |
| R32 | 84 |  Nicolas LapenttiClay | 52 | Paul-Henri MathieuClay | 3-6 6-2 6-3 | 3 | 142 | 4 | 3 | 61.6% | 73.6% | 39.4% | 5/8 |
| R32 | 153 | Oscar HernandezClay | 63 |  Philipp KohlschreiberClay | 6-1 6-1 | 3 | 61 | 1 | 1 | 66.7% | 78.6% | 57.1% | 3/3 |
| R32 | 102 | Martin Vassallo ArguelloClay | 180 | Juan-Pablo GuzmanClay | 2-6 6-3 7-5 | 3 | 115 | 0 | 5 | 70.9% | 72.1% | 56.0% | 5/8 |
| R32 | 1554 | Frantisek CermakClay | 90 |  Andrei PavelClay | 6-3 2-6 7-5 | 3 | 128 | 5 | 7 | 52.9% | 69.1% | 46.9% | 5/9 |
| R32 | 47 | Nicolas AlmagroClay | 98 |  Oliver MarachClay | 6-1 6-4 | 3 | 71 | 8 | 4 | 63.6% | 89.3% | 75.0% | 0/0 |
| R32 | 82 | Albert MontanesClay | 56 |  Luis HornaClay | 5-2 RET | 3 | 30 | 4 | 0 | 76.9% | 90.0% | 100.0% | 0/0 |
| R32 | 103 | Potito StaraceClay | 150 | Federico LuzziClay | 6-1 6-2 | 3 | 76 | 0 | 1 | 78.4% | 62.5% | 63.6% | 7/8 |
| R32 | 105 | Sergio RoitmanClay | 406 | Francesco AldiClay | 6-0 6-1 | 3 | 94 | 1 | 1 | 56.0% | 71.4% | 54.5% | 3/3 |
| R32 | 38 | Filippo VolandriClay | 78 | Guillermo Garcia-LopezClay | 7-6(3) 3-6 6-3 | 3 | 163 | 2 | 5 | 63.7% | 69.2% | 45.9% | 11/15 |
| R16 | 28 | Fernando VerdascoClay | 79 | Jan HajekClay | 6-2 6-2 | 3 | 66 | 1 | 0 | 75.0% | 66.7% | 61.5% | 3/4 |
| R16 | 60 | Ruben Ramirez HidalgoClay | 398 | Gianluca NasoClay | 6-2 6-2 | 3 | 160 | 4 | 1 | 59.0% | 78.3% | 62.5% | 0/1 |
| R16 | 46 | Gilles SimonClay | 357 | Mariano ZabaletaClay | 7-5 6-3 | 3 | 100 | 0 | 0 | 71.9% | 78.0% | 56.3% | 1/3 |
| R16 | 84 | Nicolas LapenttiClay | 242 | Fabio FogniniClay | 2-6 6-1 7-6(4) | 3 | 138 | 4 | 1 | 49.5% | 69.4% | 62.0% | 4/7 |
| R16 | 102 | Martin Vassallo ArguelloClay | 153 | Oscar HernandezClay | 2-6 6-4 6-4 | 3 | 125 | 5 | 3 | 56.9% | 73.2% | 51.6% | 2/6 |
| R16 | 47 | Nicolas AlmagroClay | 1554 | Frantisek CermakClay | 6-1 6-2 | 3 | 59 | 2 | 4 | 54.0% | 88.9% | 47.8% | 2/2 |
| R16 | 82 | Albert MontanesClay | 103 | Potito StaraceClay | 6-2 6-2 | 3 | 65 | 2 | 3 | 69.0% | 72.4% | 69.2% | 0/1 |
| R16 | 38 | Filippo VolandriClay | 105 | Sergio RoitmanClay | 6-7(6) 6-1 6-4 | 3 | 139 | 0 | 2 | 73.5% | 65.3% | 50.0% | 1/3 |
| QF | 60 | Ruben Ramirez HidalgoClay | 28 | Fernando VerdascoClay | 6-3 6-4 | 3 | 80 | 5 | 3 | 52.5% | 83.9% | 57.1% | 2/3 |
| QF | 84 | Nicolas LapenttiClay | 46 | Gilles SimonClay | 6-0 6-1 | 3 | 72 | 2 | 0 | 53.7% | 68.2% | 57.9% | 4/5 |
| QF | 47 | Nicolas AlmagroClay | 102 | Martin Vassallo ArguelloClay | 6-2 6-2 | 3 | 97 | 6 | 1 | 55.4% | 74.2% | 64.0% | 3/3 |
| QF | 38 | Filippo VolandriClay | 82 | Albert MontanesClay | 6-4 6-2 | 3 | 82 | 1 | 3 | 73.8% | 64.6% | 41.2% | 9/11 |
| SF | 84 | Nicolas LapenttiClay | 60 | Ruben Ramirez HidalgoClay | 6-2 6-1 | 3 | 63 | 3 | 0 | 60.6% | 95.0% | 69.2% | 0/0 |
| SF | 38 | Filippo VolandriClay | 47 | Nicolas AlmagroClay | 6-0 2-1 RET | 3 | 51 | 0 | 2 | 63.3% | 89.5% | 36.4% | 0/0 |
| F | 38 | Filippo VolandriClay | 84 | Nicolas LapenttiClay | 5-7 6-1 6-3 | 3 | 135 | 1 | 1 | 65.3% | 53.1% | 76.9% | 1/6 |
