| R32 | 28 |  Nicolas MassuClay | 90 |  Christophe RochusClay | 6-4 6-2 | 3 | 96 | 6 | 1 | 60.0% | 69.4% | 54.2% | 5/6 |
| R32 | 74 |  Jose AcasusoClay | 558 |  Juan GinerClay | 6-3 6-2 | 3 | 57 | 2 | 0 | 55.6% | 84.0% | 80.0% | 0/0 |
| R32 | 98 |  Tomas BehrendClay | 101 | Martin Vassallo ArguelloClay | 6-3 6-4 | 3 | 97 | 1 | 3 | 63.3% | 77.4% | 27.8% | 3/6 |
| R32 | 93 | Albert MontanesClay | 73 | Ruben Ramirez HidalgoClay | 6-2 6-4 | 3 | 76 | 1 | 0 | 100.0% | 72.0% | NaN% | 1/2 |
| R32 | 89 | Oscar HernandezClay | 48 | David SanchezClay | 6-2 0-6 7-6(8) | 3 | 139 | 0 | 2 | 72.7% | 58.8% | 40.0% | 10/16 |
| R32 | 225 |  Tomas TenconiClay | 84 |  Irakli LabadzeClay | 6-0 6-2 | 3 | 51 | 4 | 3 | 55.8% | 66.7% | 63.2% | 2/3 |
| R32 | 105 | Mariano PuertaClay | 81 |  Jurgen MelzerClay | 6-2 4-6 6-4 | 3 | 110 | 3 | 4 | 51.3% | 77.5% | 44.7% | 2/6 |
| R32 | 72 |  Luis HornaClay | 128 |  Andrei PavelClay | 7-6(6) 7-5 | 3 | 106 | 4 | 1 | 58.4% | 77.8% | 50.0% | 2/4 |
| R32 | 61 | Alberto MartinClay | 82 | David FerrerClay | 7-6(4) 6-2 | 3 | 85 | 0 | 2 | 61.9% | 66.7% | 45.8% | 1/4 |
| R32 | 107 | Galo BlancoClay | 124 | Kristof VliegenClay | 7-5 7-5 | 3 | 100 | 3 | 1 | 85.1% | 65.1% | 54.5% | 7/10 |
| R32 | 103 | Franco SquillariClay | 161 | Alessio Di MauroClay | 6-4 6-3 | 3 | 94 | 3 | 3 | 50.0% | 90.0% | 46.7% | 6/7 |
| R32 | 47 | Filippo VolandriClay | 308 | Francesco AldiClay | 6-2 7-5 | 3 | 110 | 2 | 3 | 70.4% | 57.9% | 54.2% | 7/10 |
| R32 | 51 |  Paul-Henri MathieuClay | 78 | Albert PortasClay | 4-6 6-3 7-6(5) | 3 | 172 | 5 | 7 | 50.0% | 64.5% | 40.3% | 7/14 |
| R32 | 189 | Nicolas AlmagroClay | 121 | Alex CorretjaClay | 3-1 RET | 3 | 23 | 0 | 0 | 36.4% | 100.0% | 57.1% | 0/0 |
| R32 | 77 | Victor HanescuClay | 111 |  Igor AndreevClay | 6-3 6-3 | 3 | 79 | 3 | 0 | 65.7% | 69.6% | 58.3% | 10/10 |
| R32 | 232 | Diego VeronelliClay | 41 | Nikolay DavydenkoClay | 6-4 6-4 | 3 | 83 | 4 | 1 | 59.6% | 67.6% | 39.1% | 1/5 |
| R16 | 28 | Nicolas MassuClay | 74 | Jose AcasusoClay | 6-2 3-1 RET | 3 | 48 | 4 | 1 | 53.3% | 93.8% | 71.4% | 1/1 |
| R16 | 93 | Albert MontanesClay | 98 | Tomas BehrendClay | 6-0 6-4 | 3 | 55 | 4 | 0 | 70.2% | 72.7% | 71.4% | 1/1 |
| R16 | 89 | Oscar HernandezClay | 225 | Tomas TenconiClay | 7-6(3) 6-3 | 3 | 131 | 2 | 1 | 73.6% | 68.8% | 43.5% | 8/10 |
| R16 | 72 | Luis HornaClay | 105 | Mariano PuertaClay | 6-4 6-2 | 3 | 84 | 9 | 2 | 60.6% | 82.5% | 46.2% | 4/4 |
| R16 | 61 | Alberto MartinClay | 107 | Galo BlancoClay | 4-0 RET | 3 | 24 | 0 | 0 | 66.7% | 83.3% | 100.0% | 0/0 |
| R16 | 103 | Franco SquillariClay | 47 | Filippo VolandriClay | W/O | 3 | - | 0 | 0 | 66.7% | 83.3% | 100.0% | 0/0 |
| R16 | 51 | Paul-Henri MathieuClay | 189 | Nicolas AlmagroClay | 7-6(6) 3-6 6-3 | 3 | 24 | 0 | 0 | 66.7% | 83.3% | 100.0% | 0/0 |
| R16 | 232 | Diego VeronelliClay | 77 | Victor HanescuClay | 6-4 6-2 | 3 | 62 | 2 | 1 | 52.1% | 80.0% | 73.9% | 0/0 |
| QF | 28 | Nicolas MassuClay | 93 | Albert MontanesClay | 6-4 1-6 6-4 | 3 | 133 | 0 | 4 | 61.0% | 70.2% | 46.7% | 5/9 |
| QF | 72 | Luis HornaClay | 89 | Oscar HernandezClay | 3-6 7-6(7) 6-1 | 3 | 108 | 7 | 6 | 57.1% | 71.9% | 41.7% | 5/8 |
| QF | 61 | Alberto MartinClay | 103 | Franco SquillariClay | 7-6(3) 6-4 | 3 | 112 | 0 | 2 | 60.3% | 66.0% | 54.8% | 3/6 |
| QF | 51 | Paul-Henri MathieuClay | 232 | Diego VeronelliClay | 4-6 7-6(5) 6-3 | 3 | 158 | 7 | 3 | 58.1% | 72.2% | 43.6% | 3/8 |
| SF | 28 | Nicolas MassuClay | 72 | Luis HornaClay | 6-2 6-2 | 3 | 77 | 2 | 0 | 55.0% | 86.4% | 55.6% | 1/2 |
| SF | 51 | Paul-Henri MathieuClay | 61 | Alberto MartinClay | 7-6(5) 7-6(5) | 3 | 146 | 2 | 4 | 47.4% | 62.2% | 66.0% | 3/5 |
| F | 28 | Nicolas MassuClay | 51 | Paul-Henri MathieuClay | 1-6 6-2 7-6(0) | 3 | 169 | 2 | 1 | 59.0% | 53.1% | 47.1% | 3/9 |
