| R32 | 7 |  Alex CorretjaClay | 104 | Sergi BrugueraClay | 6-0 2-6 6-0 | 3 | 82 | 4 | 3 | 44.4% | 83.3% | 53.3% | 2/4 |
| R32 | 99 | Albert PortasClay | 67 |  Adrian VoineaClay | 6-3 7-5 | 3 | 83 | 4 | 3 | 64.9% | 66.0% | 51.9% | 2/4 |
| R32 | 75 |  Nicolas LapenttiClay | 81 |  Jiri NovakClay | 6-3 7-5 | 3 | 83 | 1 | 3 | 71.6% | 70.8% | 42.1% | 5/8 |
| R32 | 510 |  Massimo ValeriClay | 51 | Carlos CostaClay | 7-6(2) 6-4 | 3 | 99 | 4 | 1 | 52.7% | 79.5% | 40.0% | 3/5 |
| R32 | 24 |  Gustavo KuertenClay | 92 |  Guillermo CanasClay | 6-3 4-6 6-2 | 3 | 88 | 6 | 3 | 48.6% | 68.6% | 45.9% | 4/9 |
| R32 | 62 | Fernando VicenteClay | 101 | Dinu PescariuClay | 7-6(4) 6-4 | 3 | 88 | 2 | 2 | 66.7% | 64.0% | 44.0% | 5/9 |
| R32 | 58 | Mariano PuertaClay | 79 |  Juan Antonio MarinClay | 7-6(8) 6-1 | 3 | 81 | 4 | 2 | 72.9% | 79.1% | 62.5% | 0/1 |
| R32 | 25 | Francisco ClavetClay | 68 |  Andrei MedvedevClay | 6-2 6-2 | 3 | 54 | 2 | 2 | 57.4% | 70.4% | 75.0% | 2/2 |
| R32 | 43 |  Dominik HrbatyClay | 72 |  Oliver GrossClay | 6-3 6-4 | 3 | 64 | 3 | 4 | 50.0% | 75.9% | 55.2% | 2/4 |
| R32 | 54 | Franco SquillariClay | 437 | Federico LuzziClay | 6-2 6-3 | 3 | 65 | 1 | 0 | 48.2% | 77.8% | 65.5% | 2/2 |
| R32 | 83 | Mariano ZabaletaClay | 143 | Oscar SerranoClay | 6-2 4-6 7-6(3) | 3 | 130 | 8 | 6 | 45.4% | 77.3% | 56.6% | 5/7 |
| R32 | 138 | Marzio MartelliClay | 21 | Felix MantillaClay | 7-6(5) 6-3 | 3 | 105 | 11 | 3 | 47.6% | 76.9% | 46.5% | 5/7 |
| R32 | 85 | Galo BlancoClay | 46 | Davide SanguinettiClay | 6-3 6-2 | 3 | 70 | 1 | 4 | 44.8% | 73.3% | 54.1% | 4/5 |
| R32 | 187 |  Jean-Baptiste PerlantClay | 120 | Alex CalatravaClay | 6-2 6-2 | 3 | 53 | 7 | 2 | 69.8% | 83.3% | 61.5% | 0/0 |
| R32 | 100 | Arnaud Di PasqualeClay | 97 | Lucas Arnold KerClay | 6-3 3-1 RET | 3 | 56 | 3 | 1 | 66.7% | 71.4% | 78.6% | 4/4 |
| R32 | 172 | Javier SanchezClay | 20 | Alberto BerasateguiClay | 6-4 6-1 | 3 | 50 | 1 | 2 | 75.0% | 80.0% | 50.0% | 1/2 |
| R16 | 7 | Alex CorretjaClay | 99 | Albert PortasClay | 6-1 6-2 | 3 | 68 | 3 | 1 | 68.6% | 77.1% | 50.0% | 2/2 |
| R16 | 75 | Nicolas LapenttiClay | 510 | Massimo ValeriClay | 7-6(4) 7-5 | 3 | 110 | 3 | 2 | 61.8% | 73.8% | 53.8% | 0/3 |
| R16 | 62 | Fernando VicenteClay | 24 | Gustavo KuertenClay | 6-4 6-3 | 3 | 75 | 4 | 1 | 67.6% | 72.9% | 56.5% | 7/7 |
| R16 | 58 | Mariano PuertaClay | 25 | Francisco ClavetClay | 6-4 4-6 6-3 | 3 | 140 | 2 | 2 | 54.1% | 67.9% | 57.8% | 5/8 |
| R16 | 54 | Franco SquillariClay | 43 | Dominik HrbatyClay | 6-4 2-6 6-4 | 3 | 113 | 5 | 2 | 58.9% | 62.5% | 56.4% | 3/6 |
| R16 | 83 | Mariano ZabaletaClay | 138 | Marzio MartelliClay | 6-4 6-2 | 3 | 77 | 6 | 4 | 60.8% | 77.4% | 55.0% | 2/3 |
| R16 | 85 | Galo BlancoClay | 187 | Jean-Baptiste PerlantClay | 6-3 6-4 | 3 | 79 | 2 | 1 | 67.2% | 74.4% | 63.2% | 3/4 |
| R16 | 100 | Arnaud Di PasqualeClay | 172 | Javier SanchezClay | 6-0 7-6(3) | 3 | 79 | 2 | 1 | 67.2% | 74.4% | 63.2% | 3/4 |
| QF | 7 | Alex CorretjaClay | 75 | Nicolas LapenttiClay | 7-5 6-2 | 3 | 97 | 4 | 2 | 35.6% | 85.7% | 50.0% | 4/7 |
| QF | 58 | Mariano PuertaClay | 62 | Fernando VicenteClay | 6-4 6-4 | 3 | 85 | 1 | 0 | 73.1% | 59.2% | 61.1% | 5/8 |
| QF | 54 | Franco SquillariClay | 83 | Mariano ZabaletaClay | 5-7 6-4 6-3 | 3 | 133 | 1 | 5 | 54.1% | 61.7% | 47.1% | 3/9 |
| QF | 85 | Galo BlancoClay | 100 | Arnaud Di PasqualeClay | 7-6(7) 6-2 | 3 | 85 | 4 | 3 | 63.0% | 71.7% | 48.1% | 2/4 |
| SF | 58 | Mariano PuertaClay | 7 | Alex CorretjaClay | 7-5 6-2 | 3 | 102 | 3 | 1 | 66.7% | 69.4% | 77.8% | 0/1 |
| SF | 54 | Franco SquillariClay | 85 | Galo BlancoClay | 6-1 2-6 7-6(2) | 3 | 132 | 4 | 3 | 69.8% | 59.5% | 50.0% | 11/16 |
| F | 58 | Mariano PuertaClay | 54 | Franco SquillariClay | 6-3 6-2 | 3 | 62 | 2 | 1 | 77.6% | 60.5% | 45.5% | 4/7 |
