| R32 | 9 |  Alex CorretjaClay | 128 |  Marzio MartelliClay | 5-7 6-3 6-2 | 3 | 131 | 2 | 7 | 51.1% | 76.6% | 55.6% | 6/9 |
| R32 | 65 |  Richard FrombergClay | 84 |  Nicolas LapenttiClay | 6-1 6-7(3) 6-3 | 3 | 129 | 7 | 5 | 56.7% | 76.5% | 51.3% | 4/7 |
| R32 | 91 |  Vincent SpadeaClay | 341 | Massimo ValeriClay | 2-6 6-4 6-0 | 3 | 122 | 1 | 1 | 58.9% | 62.3% | 45.9% | 8/12 |
| R32 | 45 | Francisco ClavetClay | 93 | Davide SanguinettiClay | 6-3 6-1 | 3 | 68 | 3 | 2 | 66.7% | 64.7% | 64.7% | 1/2 |
| R32 | 33 | Albert PortasClay | 110 |  Marcello CracaClay | 5-7 6-4 6-3 | 3 | 123 | 3 | 0 | 67.3% | 64.5% | 51.4% | 7/11 |
| R32 | 326 | Filippo MessoriClay | 133 |  Adrian VoineaClay | 6-4 6-3 | 3 | 76 | 2 | 1 | 43.9% | 64.0% | 59.4% | 5/7 |
| R32 | 66 |  Hernan GumyClay | 95 | Hendrik DreekmannClay | 6-3 7-6(3) | 3 | 125 | 3 | 3 | 44.9% | 71.4% | 58.1% | 4/4 |
| R32 | 44 |  Dominik HrbatyClay | 97 |  Juan Antonio MarinClay | 6-4 6-3 | 3 | 82 | 1 | 3 | 56.9% | 75.6% | 51.6% | 6/7 |
| R32 | 40 |  Marcelo FilippiniClay | 54 | Galo BlancoClay | 6-1 6-2 | 3 | 62 | 4 | 2 | 69.6% | 71.9% | 57.1% | 0/1 |
| R32 | 63 |  Christian RuudClay | 100 | Emilio Benfele AlvarezClay | 7-6(7) 7-5 | 3 | 120 | 6 | 5 | 66.3% | 76.4% | 42.9% | 5/7 |
| R32 | 57 | Julian AlonsoClay | 92 |  Gilbert SchallerClay | 6-4 6-7(6) 7-5 | 3 | 142 | 3 | 5 | 56.9% | 60.6% | 50.0% | 6/12 |
| R32 | 51 | Javier SanchezClay | 37 | MARHicham AraziClay | 7-5 6-3 | 3 | 79 | 4 | 3 | 63.2% | 74.4% | 44.0% | 5/7 |
| R32 | 75 | MARKarim AlamiClay | 70 | Andrea GaudenziClay | 6-3 2-0 RET | 3 | 49 | 1 | 0 | 60.6% | 80.0% | 53.8% | 1/1 |
| R32 | 85 | Dinu PescariuClay | 136 | Davide ScalaClay | 7-5 6-3 | 3 | 75 | 6 | 1 | 69.0% | 60.0% | 66.7% | 1/4 |
| R32 | 81 | Carlos CostaClay | 87 | Juan Albert Viloca-PuigClay | 6-4 6-4 | 3 | 83 | 5 | 0 | 51.0% | 84.6% | 60.0% | 0/1 |
| R32 | 27 | Alberto BerasateguiClay | 102 | Fernando VicenteClay | 6-4 5-7 6-4 | 3 | 142 | 0 | 2 | 88.7% | 55.5% | 57.1% | 12/18 |
| R16 | 9 | Alex CorretjaClay | 65 | Richard FrombergClay | 6-1 6-4 | 3 | 78 | 3 | 1 | 66.0% | 80.6% | 75.0% | 1/1 |
| R16 | 45 | Francisco ClavetClay | 91 | Vincent SpadeaClay | 6-3 6-3 | 3 | 83 | 0 | 2 | 65.1% | 70.7% | 54.5% | 3/4 |
| R16 | 33 | Albert PortasClay | 326 | Filippo MessoriClay | 6-1 6-3 | 3 | 59 | 1 | 2 | 76.8% | 69.8% | 38.5% | 1/2 |
| R16 | 44 | Dominik HrbatyClay | 66 | Hernan GumyClay | 6-3 3-2 RET | 3 | 63 | 2 | 1 | 47.2% | 76.5% | 78.9% | 0/0 |
| R16 | 40 | Marcelo FilippiniClay | 63 | Christian RuudClay | 7-6(4) 6-7(3) 7-5 | 3 | 190 | 3 | 5 | 57.5% | 65.2% | 49.0% | 8/13 |
| R16 | 51 | Javier SanchezClay | 57 | Julian AlonsoClay | 6-4 6-4 | 3 | 75 | 2 | 2 | 75.9% | 70.5% | 35.7% | 3/5 |
| R16 | 75 | MARKarim AlamiClay | 85 | Dinu PescariuClay | 6-4 6-3 | 3 | 66 | 5 | 2 | 55.9% | 81.8% | 50.0% | 4/5 |
| R16 | 27 | Alberto BerasateguiClay | 81 | Carlos CostaClay | 6-4 4-6 6-3 | 3 | 102 | 1 | 4 | 82.5% | 60.0% | 47.1% | 6/10 |
| QF | 9 | Alex CorretjaClay | 45 | Francisco ClavetClay | 7-6(4) 6-2 | 3 | 116 | 3 | 1 | 56.6% | 81.4% | 39.4% | 5/7 |
| QF | 44 | Dominik HrbatyClay | 33 | Albert PortasClay | 7-5 6-4 | 3 | 74 | 7 | 2 | 50.0% | 75.0% | 46.9% | 4/7 |
| QF | 51 | Javier SanchezClay | 40 | Marcelo FilippiniClay | 6-3 1-6 6-4 | 3 | 127 | 1 | 4 | 59.8% | 57.7% | 51.4% | 6/11 |
| QF | 27 | Alberto BerasateguiClay | 75 | MARKarim AlamiClay | 7-6(2) 6-2 | 3 | 71 | 0 | 0 | 81.0% | 78.4% | 66.7% | 0/0 |
| SF | 44 | Dominik HrbatyClay | 9 | Alex CorretjaClay | 6-4 6-4 | 3 | 72 | 5 | 3 | 50.0% | 88.5% | 57.7% | 1/2 |
| SF | 27 | Alberto BerasateguiClay | 51 | Javier SanchezClay | 6-2 6-3 | 3 | 57 | 2 | 0 | 83.7% | 80.6% | 71.4% | 0/1 |
| F | 27 | Alberto BerasateguiClay | 44 | Dominik HrbatyClay | 6-4 6-2 | 3 | 60 | 3 | 2 | 81.6% | 65.0% | 44.4% | 0/2 |
