| R32 | 102 |  Guillaume RufinClay | 66 |  Paolo LorenziClay | 6-3 6-1 | 3 | 75 | 2 | 0 | 57.6% | 67.6% | 52.0% | 8/9 |
| R32 | 55 |  Victor HanescuClay | 63 |  Albert Ramos-VinolasClay | 6-3 5-7 6-4 | 3 | 163 | 0 | 2 | 73.8% | 63.3% | 53.1% | 5/8 |
| R32 | 72 |  Yen-Hsun LuClay | 22 | Andreas SeppiClay | 7-5 1-6 6-4 | 3 | 133 | 1 | 7 | 66.3% | 61.5% | 42.4% | 6/11 |
| R32 | 53 | Pablo AndujarClay | 85 |  Lleyton HewittClay | 6-3 4-6 6-3 | 3 | 130 | 0 | 3 | 59.6% | 60.7% | 52.6% | 7/11 |
| R32 | 64 |  Carlos BerlocqClay | 62 | Leonardo MayerClay | 6-2 6-1 | 3 | 59 | 2 | 0 | 76.7% | 100.0% | 71.4% | 0/0 |
| R32 | 76 | Paul-Henri MathieuClay | 87 |  Ryan HarrisonClay | 6-4 6-4 | 3 | 88 | 0 | 0 | 54.7% | 80.0% | 55.2% | 4/5 |
| R32 | 100 |  Sergiy StakhovskyClay | 94 |  Rogerio Dutra SilvaClay | 6-2 6-3 | 3 | 61 | 0 | 2 | 66.7% | 70.6% | 70.6% | 0/1 |
| R32 | 75 | Edouard Roger-VasselinClay | 70 |  Alejandro FallaClay | 7-5 RET | 3 | 41 | 5 | 0 | 67.7% | 81.0% | 50.0% | 1/2 |
| R32 | 67 |  Ricardas BerankisClay | 43 |  Denis IstominClay | 6-2 6-2 | 3 | 54 | 1 | 0 | 63.6% | 75.0% | 68.8% | 2/3 |
| R32 | 29 | Fabio FogniniClay | 357 | Marco CecchinatoClay | 1-6 6-1 6-2 | 3 | 93 | 3 | 0 | 57.5% | 76.2% | 32.3% | 2/5 |
| R32 | 109 | Gael MonfilsClay | 78 | Santiago GiraldoClay | 4-6 6-3 6-3 | 3 | 117 | 6 | 5 | 63.6% | 76.8% | 46.9% | 6/8 |
| R32 | 69 |  Robin HaaseClay | 61 | Marinko MatosevicClay | 6-1 6-4 | 3 | 61 | 4 | 0 | 64.6% | 71.0% | 52.9% | 2/4 |
| R16 | 82 | Albert MontanesClay | 55 | Victor HanescuClay | 7-5 7-6(2) | 3 | 108 | 3 | 3 | 57.3% | 78.7% | 54.3% | 6/7 |
| R16 | 76 | Paul-Henri MathieuClay | 64 | Carlos BerlocqClay | 7-5 3-6 6-3 | 3 | 133 | 1 | 1 | 64.2% | 68.9% | 41.2% | 4/8 |
| R16 | 20 | Sam QuerreyClay | 100 | Sergiy StakhovskyClay | 7-5 6-3 | 3 | 83 | 4 | 1 | 55.3% | 71.4% | 58.8% | 6/7 |
| R16 | 75 | Edouard Roger-VasselinClay | 67 | Ricardas BerankisClay | 2-6 6-4 6-2 | 3 | 111 | 1 | 0 | 63.6% | 71.4% | 50.0% | 2/4 |
| R16 | 109 | Gael MonfilsClay | 29 | Fabio FogniniClay | 6-2 7-6(5) | 3 | 91 | 2 | 2 | 67.7% | 79.5% | 47.6% | 2/3 |
| R16 | 69 | Robin HaaseClay | 21 | John IsnerClay | 6-4 1-6 7-5 | 3 | 114 | 5 | 1 | 60.4% | 65.5% | 52.8% | 6/10 |
| R16 | 53 | Pablo AndujarClay | 72 | Yen-Hsun LuClay | 6-2 6-0 | 3 | 74 | 0 | 1 | 61.2% | 70.0% | 73.7% | 7/7 |
| R16 | 17 | Gilles SimonClay | 102 | Guillaume RufinClay | 6-4 6-3 | 3 | 96 | 1 | 3 | 54.4% | 64.5% | 57.7% | 5/7 |
| QF | 82 | Albert MontanesClay | 76 | Paul-Henri MathieuClay | 6-4 6-1 | 3 | 67 | 6 | 2 | 57.5% | 87.0% | 82.4% | 1/1 |
| QF | 75 | Edouard Roger-VasselinClay | 20 | Sam QuerreyClay | 3-6 7-6(2) 6-1 | 3 | 112 | 3 | 4 | 64.9% | 69.4% | 59.0% | 9/11 |
| QF | 109 | Gael MonfilsClay | 69 | Robin HaaseClay | 6-2 6-3 | 3 | 67 | 1 | 0 | 66.0% | 74.2% | 56.3% | 2/3 |
| QF | 53 | Pablo AndujarClay | 17 | Gilles SimonClay | 6-4 7-5 | 3 | 103 | 1 | 2 | 62.7% | 69.0% | 68.0% | 6/7 |
| SF | 82 | Albert MontanesClay | 75 | Edouard Roger-VasselinClay | 6-4 4-6 6-0 | 3 | 113 | 11 | 4 | 68.5% | 77.8% | 48.3% | 15/16 |
| SF | 109 | Gael MonfilsClay | 53 | Pablo AndujarClay | 7-5 6-4 | 3 | 100 | 2 | 4 | 52.9% | 72.2% | 56.3% | 1/3 |
| F | 82 | Albert MontanesClay | 109 | Gael MonfilsClay | 6-0 7-6(3) | 3 | 74 | 2 | 2 | 72.1% | 72.7% | 58.8% | 0/1 |
