| R16 | 61 |  Steve DarcisClay | 81 |  Filippo VolandriClay | 3-6 6-2 6-4 | 3 | 109 | 5 | 0 | 61.7% | 72.0% | 45.2% | 2/6 |
| R32 | 80 | Xavier MalisseClay | 59 |  Yen-Hsun LuClay | 7-5 6-4 | 3 | 112 | 7 | 2 | 63.6% | 77.6% | 57.1% | 1/1 |
| R32 | 44 |  Juan Carlos FerreroClay | 39 |  Robin HaaseClay | 4-6 7-6(6) 7-6(6) | 3 | 152 | 3 | 1 | 75.7% | 71.3% | 57.1% | 5/8 |
| R32 | 70 |  Thomaz BellucciClay | 50 |  Donald YoungClay | 6-7(5) 6-0 6-3 | 3 | 143 | 2 | 2 | 64.0% | 69.9% | 51.2% | 10/11 |
| R32 | 95 |  Grigor DimitrovClay | 94 |  Dudi SelaClay | 7-5 6-1 | 3 | 68 | 7 | 4 | 63.0% | 76.5% | 60.0% | 2/3 |
| R32 | 53 |  Nikolay DavydenkoClay | 76 |  Matthew EbdenClay | 6-3 6-3 | 3 | 102 | 1 | 1 | 76.8% | 54.7% | 50.0% | 9/12 |
| R32 | 42 |  Denis IstominClay | 51 |  Alejandro FallaClay | 7-6(3) 1-6 6-1 | 3 | 145 | 5 | 2 | 62.8% | 62.7% | 60.0% | 5/7 |
| R32 | 216 | Brian BakerClay | 84 |  Sergiy StakhovskyClay | 6-7(2) 6-4 7-5 | 3 | 153 | 4 | 2 | 62.0% | 65.7% | 58.5% | 5/9 |
| R32 | 55 |  Mikhail KukushkinClay | 71 | Sam QuerreyClay | 6-2 7-5 | 3 | 81 | 1 | 1 | 64.2% | 72.1% | 66.7% | 5/5 |
| R32 | 28 | Bernard TomicClay | 63 |  Lukas LackoClay | 6-2 6-3 | 3 | 65 | 3 | 1 | 63.2% | 69.4% | 57.1% | 1/2 |
| R32 | 61 | Steve DarcisClay | 45 | Fabio FogniniClay | 7-6(3) 7-5 | 3 | 108 | 3 | 1 | 51.2% | 86.0% | 46.3% | 6/8 |
| R32 | 81 | Filippo VolandriClay | 62 | Olivier RochusClay | 4-6 7-6(2) 6-2 | 3 | 145 | 2 | 0 | 84.0% | 61.9% | 50.0% | 4/8 |
| R32 | 83 |  Edouard Roger-VasselinClay | 66 | Benoit PaireClay | 6-4 7-6(2) | 3 | 109 | 2 | 4 | 63.4% | 68.8% | 54.1% | 8/9 |
| R16 | 11 | John IsnerClay | 80 | Xavier MalisseClay | 7-6(3) 7-6(5) | 3 | 92 | 13 | 0 | 75.0% | 85.2% | 61.1% | 0/0 |
| R16 | 53 | Nikolay DavydenkoClay | 42 | Denis IstominClay | 6-4 1-6 6-3 | 3 | 123 | 0 | 0 | 84.6% | 57.6% | 58.3% | 4/9 |
| R16 | 216 | Brian BakerClay | 13 | Gael MonfilsClay | 6-3 7-6(9) | 3 | 92 | 4 | 2 | 68.6% | 75.0% | 54.5% | 3/5 |
| R16 | 55 | Mikhail KukushkinClay | 28 | Bernard TomicClay | 3-6 6-2 7-5 | 3 | 139 | 5 | 4 | 62.1% | 61.1% | 47.7% | 16/20 |
| R16 | 14 | Nicolas AlmagroClay | 83 | Edouard Roger-VasselinClay | 7-6(5) 6-4 | 3 | 95 | 4 | 3 | 51.4% | 86.5% | 57.1% | 3/4 |
| R16 | 70 | Thomaz BellucciClay | 44 | Juan Carlos FerreroClay | 6-4 6-3 | 3 | 100 | 12 | 1 | 65.8% | 70.0% | 53.8% | 7/8 |
| R16 | 12 | Gilles SimonClay | 95 | Grigor DimitrovClay | 6-3 6-3 | 3 | 80 | 3 | 1 | 56.6% | 76.7% | 65.2% | 2/2 |
| QF | 53 | Nikolay DavydenkoClay | 11 | John IsnerClay | 6-4 7-6(4) | 3 | 101 | 0 | 1 | 83.1% | 79.7% | 46.2% | 3/3 |
| QF | 216 | Brian BakerClay | 55 | Mikhail KukushkinClay | 4-6 6-3 7-6(4) | 3 | 136 | 2 | 2 | 61.1% | 65.2% | 57.1% | 6/10 |
| QF | 14 | Nicolas AlmagroClay | 61 | Steve DarcisClay | 6-4 6-4 | 3 | 83 | 13 | 3 | 59.3% | 90.6% | 59.1% | 1/1 |
| QF | 12 | Gilles SimonClay | 70 | Thomaz BellucciClay | 7-5 6-0 | 3 | 91 | 1 | 0 | 48.9% | 87.0% | 66.7% | 0/0 |
| SF | 216 | Brian BakerClay | 53 | Nikolay DavydenkoClay | 6-7(5) 6-4 6-2 | 3 | 152 | 7 | 2 | 62.1% | 61.1% | 43.2% | 9/14 |
| SF | 14 | Nicolas AlmagroClay | 12 | Gilles SimonClay | 6-1 6-3 | 3 | 68 | 8 | 1 | 49.1% | 81.5% | 53.6% | 4/4 |
| F | 14 | Nicolas AlmagroClay | 216 | Brian BakerClay | 6-3 6-2 | 3 | 70 | 11 | 1 | 70.2% | 87.9% | 42.9% | 1/1 |
