| R32 | 53 |  Adrian MannarinoClay | 66 |  Somdev DevvarmanClay | 6-3 7-6(7) | 3 | 116 | 2 | 1 | 48.9% | 64.4% | 59.6% | 5/7 |
| R16 | 7 |  David FerrerClay | 51 |  Andreas SeppiClay | 6-3 6-2 | 3 | 71 | 6 | 2 | 51.1% | 95.7% | 63.6% | 0/0 |
| R16 | 23 |  Alexandr DolgopolovClay | 65 | Pere RibaClay | 7-6(5) 7-6(5) | 3 | 105 | 8 | 1 | 51.2% | 81.4% | 51.2% | 1/3 |
| R16 | 69 |  Victor HanescuClay | 91 |  Michael RussellClay | 7-5 6-2 | 3 | 76 | 4 | 2 | 75.5% | 87.5% | 38.5% | 0/1 |
| R16 | 59 |  Robin HaaseClay | 34 | Sergiy StakhovskyClay | 6-2 6-4 | 3 | 83 | 4 | 1 | 57.1% | 75.0% | 33.3% | 3/6 |
| R16 | 49 | Pablo AndujarClay | 83 | Julien BenneteauClay | 6-3 6-4 | 3 | 90 | 3 | 1 | 60.9% | 73.8% | 59.3% | 3/3 |
| R16 | 12 | Nicolas AlmagroClay | 68 |  Carlos BerlocqClay | 6-7(5) 6-4 6-3 | 3 | 143 | 5 | 6 | 57.6% | 77.4% | 43.6% | 4/6 |
| R16 | 85 |  Ernests GulbisClay | 58 |  Denis IstominClay | 6-3 4-6 6-3 | 3 | 125 | 3 | 2 | 55.3% | 76.6% | 63.2% | 2/3 |
| R16 | 6 |  Tomas BerdychClay | 53 | Adrian MannarinoClay | 6-1 6-4 | 3 | 64 | 3 | 2 | 71.4% | 80.0% | 71.4% | 1/1 |
| QF | 23 | Alexandr DolgopolovClay | 7 | David FerrerClay | 6-4 1-6 7-5 | 3 | 112 | 6 | 3 | 52.3% | 65.2% | 59.5% | 3/7 |
| QF | 69 | Victor HanescuClay | 59 | Robin HaaseClay | 6-2 2-0 RET | 3 | 56 | 2 | 0 | 72.4% | 85.7% | 37.5% | 0/0 |
| QF | 12 | Nicolas AlmagroClay | 49 | Pablo AndujarClay | 6-1 6-4 | 3 | 82 | 6 | 3 | 50.8% | 76.7% | 48.3% | 6/7 |
| QF | 6 | Tomas BerdychClay | 85 | Ernests GulbisClay | 6-1 6-4 | 3 | 84 | 5 | 0 | 60.0% | 77.8% | 72.2% | 0/1 |
| SF | 69 | Victor HanescuClay | 23 | Alexandr DolgopolovClay | 6-3 6-3 | 3 | 73 | 0 | 2 | 70.0% | 76.2% | 44.4% | 3/4 |
| SF | 12 | Nicolas AlmagroClay | 6 | Tomas BerdychClay | 6-4 6-4 | 3 | 88 | 6 | 1 | 49.1% | 88.9% | 53.6% | 2/3 |
| F | 12 | Nicolas AlmagroClay | 69 | Victor HanescuClay | 6-7(5) 6-3 6-3 | 3 | 139 | 10 | 4 | 47.7% | 73.8% | 50.0% | 4/8 |
| R32 | 51 | Andreas SeppiClay | 137 | Edouard Roger-VasselinClay | 3-6 6-3 6-2 | 3 | 112 | 7 | 2 | 64.5% | 75.5% | 59.3% | 3/4 |
| R32 | 65 | Pere RibaClay | 255 | Guillaume RufinClay | 6-2 6-2 | 3 | 70 | 5 | 1 | 56.4% | 77.3% | 47.1% | 1/3 |
| R32 | 23 | Alexandr DolgopolovClay | 74 | Filippo VolandriClay | 7-5 6-3 | 3 | 81 | 3 | 4 | 43.5% | 73.3% | 59.0% | 7/9 |
| R32 | 69 | Victor HanescuClay | 106 | Benoit PaireClay | 6-0 6-1 | 3 | 55 | 2 | 1 | 58.3% | 60.7% | 80.0% | 6/6 |
| R32 | 59 | Robin HaaseClay | 56 |  Yen-Hsun LuClay | 6-3 6-4 | 3 | 84 | 5 | 2 | 59.3% | 78.1% | 50.0% | 2/4 |
| R32 | 34 | Sergiy StakhovskyClay | 81 |  Teymuraz GabashviliClay | 7-6(5) 6-3 | 3 | 108 | 6 | 3 | 64.3% | 75.6% | 48.0% | 3/4 |
| R32 | 83 | Julien BenneteauClay | 29 |  Marcos BaghdatisClay | 7-6(3) 6-2 | 3 | 95 | 1 | 3 | 69.0% | 71.4% | 54.5% | 2/3 |
| R32 | 49 | Pablo AndujarClay | 63 |  Grigor DimitrovClay | 5-0 RET | 3 | 19 | 2 | 0 | 45.5% | 80.0% | 66.7% | 0/0 |
| R32 | 68 | Carlos BerlocqClay | 90 |  Andreas Haider-MaurerClay | 5-7 6-3 6-0 | 3 | 125 | 3 | 0 | 58.6% | 68.3% | 72.4% | 4/6 |
| R32 | 85 | Ernests GulbisClay | 48 | Fabio FogniniClay | 3-6 6-3 6-3 | 3 | 118 | 5 | 4 | 51.1% | 80.0% | 46.5% | 9/11 |
| R32 | 58 | Denis IstominClay | 73 |  Olivier RochusClay | 6-2 7-6(5) | 3 | 100 | 10 | 4 | 59.7% | 74.4% | 44.8% | 3/5 |
