| R64 | 57 | Ruben Ramirez HidalgoHard | 66 | Christophe RochusHard | 6-3 7-5 | 3 | 81 | 13 | 7 | 52.1% | 73.7% | 54.3% | 2/3 |
| R64 | 85 | Robin VikHard | 49 | Fabrice SantoroHard | 6-4 6-2 | 3 | 62 | 3 | 0 | 66.0% | 78.8% | 70.6% | 2/2 |
| R64 | 71 | Andreas SeppiHard | 68 | Bjorn PhauHard | 6-1 6-1 | 3 | 53 | 7 | 3 | 67.9% | 72.2% | 58.8% | 3/3 |
| R64 | 67 | Nicolas MahutHard | 65 | Daniele BraccialiHard | 7-5 7-6(2) | 3 | 92 | 12 | 3 | 62.1% | 85.4% | 80.0% | 2/2 |
| R64 | 138 | Greg RusedskiHard | 69 | Ivo KarlovicHard | 7-6(2) 6-7(7) 6-2 | 3 | 141 | 15 | 7 | 42.9% | 85.7% | 69.6% | 3/4 |
| R64 | 89 | Boris PashanskiHard | 93 | Gilles MullerHard | 6-3 2-6 7-6(3) | 3 | 118 | 4 | 11 | 41.9% | 88.9% | 50.0% | 1/3 |
| R64 | 55 | Max MirnyiHard | 59 | Paul-Henri MathieuHard | 6-2 7-6(6) | 3 | 95 | 11 | 2 | 65.1% | 72.2% | 37.9% | 9/10 |
| R64 | 60 | Mardy FishHard | 56 | Davide SanguinettiHard | 6-3 6-3 | 3 | 70 | 6 | 2 | 56.3% | 77.8% | 60.7% | 8/8 |
| R64 | 51 | Julien BenneteauHard | 61 | Luis HornaHard | 7-6(3) 2-6 6-1 | 3 | 138 | 6 | 6 | 66.3% | 80.7% | 51.7% | 8/10 |
| R64 | 64 | Feliciano LopezHard | 53 | Filippo VolandriHard | 6-3 6-4 | 3 | 68 | 12 | 1 | 68.3% | 87.8% | 26.3% | 4/5 |
| R64 | 177 | Sam QuerreyHard | 50 | Alberto MartinHard | 6-3 6-2 | 3 | 61 | 11 | 3 | 65.5% | 77.8% | 57.9% | 2/2 |
| R64 | 129 | Michael BerrerHard | 562 | Ryan SweetingHard | 7-5 6-2 | 3 | 70 | 5 | 3 | 63.3% | 74.2% | 66.7% | 1/3 |
| R64 | 52 | Gilles SimonHard | 74 | Justin GimelstobHard | 4-6 7-5 6-1 | 3 | 133 | 4 | 3 | 58.8% | 75.4% | 52.5% | 6/8 |
| R64 | 83 | Marc GicquelHard | 84 | Jan HajekHard | 7-6(3) 6-3 | 3 | 75 | 5 | 2 | 46.3% | 87.1% | 47.2% | 4/7 |
| R64 | 47 | Stan WawrinkaHard | 45 | Nicolas AlmagroHard | 6-3 6-7(5) 6-4 | 3 | 132 | 12 | 4 | 60.0% | 73.3% | 70.0% | 2/3 |
| R64 | 46 | Arnaud ClementHard | 44 | Florent SerraHard | 6-4 6-1 | 3 | 80 | 4 | 1 | 57.5% | 69.0% | 41.9% | 5/7 |
| R32 | 57 | Ruben Ramirez HidalgoHard | 5 | James BlakeHard | 2-6 7-6(6) 7-6(4) | 3 | 142 | 7 | 8 | 55.6% | 72.5% | 50.9% | 13/18 |
| R32 | 39 | Xavier MalisseHard | 85 | Robin VikHard | 6-1 4-6 6-3 | 3 | 109 | 10 | 1 | 52.3% | 76.1% | 45.2% | 4/7 |
| R32 | 35 | Juan Ignacio ChelaHard | 71 | Andreas SeppiHard | 6-3 6-2 | 3 | 68 | 3 | 1 | 56.6% | 76.7% | 69.6% | 1/1 |
| R32 | 27 | Jose AcasusoHard | 67 | Nicolas MahutHard | 7-5 3-3 RET | 3 | 75 | 7 | 4 | 53.7% | 89.7% | 48.0% | 0/0 |
| R32 | 15 | Jarkko NieminenHard | 138 | Greg RusedskiHard | 7-6(2) 6-4 | 3 | 87 | 6 | 1 | 60.9% | 78.6% | 59.3% | 3/4 |
| R32 | 40 | Nicolas MassuHard | 89 | Boris PashanskiHard | 6-3 7-6(4) | 3 | 78 | 17 | 2 | 73.7% | 85.7% | 73.3% | 1/2 |
| R32 | 32 | Agustin CalleriHard | 55 | Max MirnyiHard | 7-6(4) 6-3 | 3 | 91 | 13 | 3 | 67.6% | 80.4% | 72.7% | 2/2 |
| R32 | 13 | David FerrerHard | 60 | Mardy FishHard | 6-2 2-6 7-6(5) | 3 | 127 | 1 | 3 | 59.6% | 69.6% | 50.0% | 4/7 |
| R32 | 25 | Fernando VerdascoHard | 51 | Julien BenneteauHard | 7-6(4) 6-4 | 3 | 80 | 9 | 3 | 81.0% | 82.4% | 58.3% | 2/2 |
| R32 | 73 | Jurgen MelzerHard | 64 | Feliciano LopezHard | 6-7(3) 7-6(1) 6-4 | 3 | 140 | 10 | 4 | 68.1% | 70.1% | 61.1% | 7/9 |
| R32 | 41 | Robin SoderlingHard | 177 | Sam QuerreyHard | 6-3 4-6 6-1 | 3 | 78 | 3 | 1 | 66.2% | 77.8% | 69.6% | 3/4 |
| R32 | 8 | Marcos BaghdatisHard | 129 | Michael BerrerHard | 7-6(5) 7-6(6) | 3 | 108 | 5 | 3 | 57.3% | 76.7% | 59.4% | 0/2 |
| R32 | 30 | Olivier RochusHard | 52 | Gilles SimonHard | 4-6 6-4 6-3 | 3 | 124 | 2 | 3 | 51.1% | 77.1% | 47.8% | 6/9 |
| R32 | 31 | Gael MonfilsHard | 83 | Marc GicquelHard | 7-6(6) 6-4 | 3 | 88 | 11 | 3 | 60.3% | 74.5% | 61.3% | 6/7 |
| R32 | 43 | Paradorn SrichaphanHard | 47 | Stan WawrinkaHard | 7-6(2) 4-6 6-4 | 3 | 138 | 8 | 8 | 53.3% | 73.7% | 54.0% | 7/10 |
| R32 | 7 | Nikolay DavydenkoHard | 46 | Arnaud ClementHard | 6-2 6-1 | 3 | 64 | 0 | 1 | 60.0% | 95.2% | 64.3% | 2/2 |
| R16 | 39 | Xavier MalisseHard | 57 | Ruben Ramirez HidalgoHard | 6-1 6-3 | 3 | 66 | 5 | 0 | 63.2% | 87.5% | 78.6% | 0/0 |
| R16 | 35 | Juan Ignacio ChelaHard | 27 | Jose AcasusoHard | 7-6(1) 6-2 | 3 | 84 | 4 | 0 | 62.1% | 80.5% | 48.0% | 1/2 |
| R16 | 40 | Nicolas MassuHard | 15 | Jarkko NieminenHard | 6-3 6-4 | 3 | 88 | 6 | 5 | 44.6% | 86.2% | 58.3% | 2/2 |
| R16 | 32 | Agustin CalleriHard | 13 | David FerrerHard | 6-3 6-1 | 3 | 78 | 7 | 3 | 62.2% | 71.7% | 39.3% | 11/12 |
| R16 | 73 | Jurgen MelzerHard | 25 | Fernando VerdascoHard | 6-4 4-1 RET | 3 | 55 | 6 | 3 | 62.0% | 77.4% | 52.6% | 3/3 |
| R16 | 41 | Robin SoderlingHard | 8 | Marcos BaghdatisHard | 6-3 6-7(3) 7-5 | 3 | 137 | 9 | 5 | 65.3% | 80.3% | 51.4% | 3/4 |
| R16 | 30 | Olivier RochusHard | 31 | Gael MonfilsHard | 6-4 6-3 | 3 | 71 | 0 | 1 | 49.1% | 75.0% | 72.4% | 2/2 |
| R16 | 7 | Nikolay DavydenkoHard | 43 | Paradorn SrichaphanHard | 6-4 6-1 | 3 | 62 | 4 | 3 | 65.1% | 85.7% | 53.3% | 0/0 |
| QF | 39 | Xavier MalisseHard | 35 | Juan Ignacio ChelaHard | 4-6 6-4 6-2 | 3 | 118 | 3 | 3 | 56.5% | 76.9% | 42.5% | 6/9 |
| QF | 32 | Agustin CalleriHard | 40 | Nicolas MassuHard | 6-3 3-6 6-4 | 3 | 113 | 11 | 4 | 58.2% | 84.8% | 51.5% | 2/4 |
| QF | 41 | Robin SoderlingHard | 73 | Jurgen MelzerHard | 6-3 6-2 | 3 | 54 | 7 | 1 | 75.5% | 83.8% | 50.0% | 2/2 |
| QF | 7 | Nikolay DavydenkoHard | 30 | Olivier RochusHard | 6-4 6-2 | 3 | 75 | 3 | 1 | 67.3% | 66.7% | 62.5% | 2/4 |
| SF | 32 | Agustin CalleriHard | 39 | Xavier MalisseHard | 6-2 RET | 3 | 37 | 6 | 0 | 68.6% | 83.3% | 36.4% | 2/2 |
| SF | 7 | Nikolay DavydenkoHard | 41 | Robin SoderlingHard | 7-6(6) 6-2 | 3 | 98 | 5 | 1 | 79.2% | 63.9% | 37.5% | 3/6 |
| F | 7 | Nikolay DavydenkoHard | 32 | Agustin CalleriHard | 6-4 6-3 | 3 | 82 | 5 | 2 | 62.5% | 80.0% | 45.8% | 6/6 |