| R32 | 46 |  Julien BenneteauClay | 183 |  Alexander PeyaClay | 2-6 7-6(5) 7-5 | 3 | 152 | 3 | 3 | 69.4% | 66.2% | 43.3% | 3/8 |
| R32 | 141 |  Daniel BrandsClay | 215 | Stefan KoubekClay | 6-3 7-6(2) | 3 | 76 | 6 | 1 | 75.0% | 82.2% | 73.3% | 6/6 |
| R32 | 50 |  Simone BolelliClay | 177 |  Stephane BohliClay | 3-6 6-2 6-3 | 3 | 138 | 3 | 3 | 67.4% | 71.9% | 48.4% | 8/9 |
| R32 | 95 | Potito StaraceClay | 37 |  Igor KunitsynClay | 7-5 5-7 6-3 | 3 | 131 | 2 | 1 | 82.7% | 67.9% | 47.1% | 6/10 |
| R32 | 26 |  Nicolas AlmagroClay | 66 |  Jan HernychClay | 6-3 6-4 | 3 | 74 | 3 | 0 | 72.7% | 72.5% | 60.0% | 2/3 |
| R32 | 64 | Mikhail YouzhnyClay | 81 | Ivo MinarClay | 6-3 7-6(5) | 3 | 95 | 0 | 1 | 61.7% | 64.9% | 47.8% | 0/3 |
| R32 | 164 | Denis GremelmayrClay | 47 |  Martin Vassallo ArguelloClay | 5-1 RET | 3 | 30 | 1 | 1 | 60.0% | 77.8% | 83.3% | 0/0 |
| R32 | 39 | Paul-Henri MathieuClay | 140 | MARLamine OuahabClay | 6-3 6-2 | 3 | 66 | 4 | 1 | 63.8% | 90.0% | 52.9% | 0/0 |
| R32 | 236 |  Thiemo de BakkerClay | 30 | Rainer SchuettlerClay | 6-3 6-3 | 3 | 69 | 5 | 0 | 78.3% | 66.0% | 61.5% | 2/3 |
| R32 | 55 |  Lleyton HewittClay | 70 | Philipp PetzschnerClay | 6-2 6-7(2) 7-6(8) | 3 | 157 | 2 | 5 | 48.8% | 66.7% | 54.0% | 7/11 |
| R32 | 58 | Andreas BeckClay | 56 | Mischa ZverevClay | 6-3 6-4 | 3 | 87 | 1 | 1 | 52.6% | 70.0% | 55.6% | 2/4 |
| R32 | 28 | Tomas BerdychClay | 495 | Sascha KloerClay | 7-6(0) 6-4 | 3 | 91 | 6 | 1 | 66.7% | 72.7% | 77.3% | 3/4 |
| R32 | 29 | Nicolas KieferClay | 42 |  Ernests GulbisClay | 2-6 6-3 6-2 | 3 | 93 | 7 | 5 | 50.0% | 75.0% | 45.0% | 4/7 |
| R32 | 40 | Jeremy ChardyClay | 84 |  Evgeny KorolevClay | 6-3 6-3 | 3 | 57 | 6 | 1 | 62.8% | 85.2% | 81.3% | 0/0 |
| R32 | 41 | Philipp KohlschreiberClay | 77 | Bjorn PhauClay | 6-2 2-1 RET | 3 | 45 | 3 | 2 | 73.7% | 67.9% | 60.0% | 2/3 |
| R32 | 15 |  Marin CilicClay | 210 | Dieter KindlmannClay | 6-3 6-2 | 3 | 75 | 4 | 1 | 56.8% | 88.0% | 57.9% | 0/0 |
| R16 | 141 | Daniel BrandsClay | 46 | Julien BenneteauClay | 6-4 3-6 7-6(6) | 3 | 135 | 3 | 3 | 64.4% | 67.2% | 46.9% | 3/8 |
| R16 | 95 | Potito StaraceClay | 50 | Simone BolelliClay | 6-4 7-6(5) | 3 | 114 | 3 | 1 | 85.9% | 73.8% | 40.0% | 2/3 |
| R16 | 64 | Mikhail YouzhnyClay | 26 | Nicolas AlmagroClay | 7-6(2) 6-4 | 3 | 86 | 4 | 0 | 64.1% | 80.5% | 69.6% | 2/3 |
| R16 | 39 | Paul-Henri MathieuClay | 164 | Denis GremelmayrClay | 6-1 6-4 | 3 | 75 | 5 | 0 | 63.9% | 66.7% | 63.6% | 2/3 |
| R16 | 55 | Lleyton HewittClay | 236 | Thiemo de BakkerClay | 6-3 6-4 | 3 | 94 | 7 | 2 | 64.6% | 78.6% | 34.8% | 3/5 |
| R16 | 28 | Tomas BerdychClay | 58 | Andreas BeckClay | 1-6 6-4 7-6(4) | 3 | 151 | 7 | 4 | 54.2% | 80.8% | 47.7% | 5/8 |
| R16 | 40 | Jeremy ChardyClay | 29 | Nicolas KieferClay | 6-4 7-6(8) | 3 | 95 | 7 | 2 | 59.2% | 78.6% | 62.1% | 3/4 |
| R16 | 15 | Marin CilicClay | 41 | Philipp KohlschreiberClay | 6-0 6-4 | 3 | 77 | 3 | 2 | 61.0% | 75.0% | 52.2% | 3/3 |
| QF | 141 | Daniel BrandsClay | 95 | Potito StaraceClay | 6-4 1-1 RET | 3 | 36 | 5 | 1 | 69.0% | 90.0% | 66.7% | 0/0 |
| QF | 64 | Mikhail YouzhnyClay | 39 | Paul-Henri MathieuClay | 7-5 3-6 6-3 | 3 | 138 | 10 | 3 | 60.5% | 78.8% | 58.8% | 4/5 |
| QF | 28 | Tomas BerdychClay | 55 | Lleyton HewittClay | 4-6 6-3 7-6(4) | 3 | 138 | 8 | 4 | 67.0% | 69.9% | 52.8% | 4/7 |
| QF | 40 | Jeremy ChardyClay | 15 | Marin CilicClay | 3-6 7-5 6-4 | 3 | 118 | 3 | 1 | 69.4% | 81.4% | 53.8% | 4/5 |
| SF | 64 | Mikhail YouzhnyClay | 141 | Daniel BrandsClay | 3-6 6-3 6-4 | 3 | 117 | 1 | 2 | 74.7% | 82.3% | 47.6% | 6/7 |
| SF | 28 | Tomas BerdychClay | 40 | Jeremy ChardyClay | 6-1 5-7 6-2 | 3 | 105 | 10 | 1 | 64.8% | 78.0% | 50.0% | 4/5 |
| F | 28 | Tomas BerdychClay | 64 | Mikhail YouzhnyClay | 6-4 4-6 7-6(5) | 3 | 154 | 7 | 7 | 62.4% | 84.5% | 40.0% | 2/5 |
