| R32 | 46 |  Andreas SeppiClay | 113 |  Roko KaranusicClay | 6-3 6-3 | 3 | 75 | 3 | 4 | 63.1% | 73.2% | 45.8% | 6/8 |
| R32 | 48 |  Steve DarcisClay | 108 |  Benjamin BeckerClay | 6-3 6-4 | 3 | 66 | 6 | 1 | 67.3% | 82.9% | 64.7% | 0/0 |
| R32 | 295 | MARYounes El AynaouiClay | 317 |  Alexandre SidorenkoClay | 6-4 7-6(6) | 3 | 92 | 14 | 3 | 63.7% | 78.4% | 51.7% | 1/1 |
| R32 | 75 |  Juan Martin del PotroClay | 90 | Arnaud ClementClay | 6-3 6-1 | 3 | 76 | 12 | 3 | 50.9% | 75.9% | 60.7% | 7/7 |
| R32 | 25 |  Igor AndreevClay | 53 | Gael MonfilsClay | 6-3 6-4 | 3 | 90 | 0 | 0 | 60.7% | 70.3% | 75.0% | 4/4 |
| R32 | 65 | Michael BerrerClay | 271 |  Ivo KlecClay | 6-1 7-6(6) | 3 | 111 | 2 | 4 | 63.5% | 68.5% | 51.6% | 3/4 |
| R32 | 84 | Marat SafinClay | 91 | Carlos BerlocqClay | 6-3 3-6 6-4 | 3 | 126 | 10 | 4 | 57.1% | 73.2% | 47.6% | 8/10 |
| R32 | 88 | Kristof VliegenClay | 80 | Sergio RoitmanClay | 7-6(3) 6-3 | 3 | 98 | 10 | 2 | 54.9% | 80.0% | 51.4% | 6/6 |
| R32 | 15 |  Fernando GonzalezClay | 57 |  Dudi SelaClay | 6-3 6-4 | 3 | 75 | 5 | 1 | 50.8% | 83.3% | 65.5% | 4/4 |
| R16 | 18 | Paul-Henri MathieuClay | 305 | Gianluca NasoClay | 6-3 6-4 | 3 | 93 | 12 | 2 | 56.3% | 88.9% | 50.0% | 2/2 |
| R16 | 50 | Marin CilicClay | 121 | Philipp PetzschnerClay | 6-4 7-6(7) | 3 | 114 | 6 | 7 | 59.8% | 70.5% | 51.2% | 13/14 |
| R16 | 55 |  Hyung-Taik LeeClay | 184 |  Julio SilvaClay | 6-1 6-4 | 3 | 69 | 2 | 0 | 70.7% | 68.3% | 64.7% | 2/3 |
| R16 | 58 | Simone BolelliClay | 46 | Andreas SeppiClay | 6-4 7-5 | 3 | 94 | 6 | 1 | 76.0% | 73.7% | 61.1% | 6/6 |
| R16 | 295 | MARYounes El AynaouiClay | 48 | Steve DarcisClay | 6-4 3-6 6-3 | 3 | 98 | 7 | 1 | 71.9% | 76.6% | 44.0% | 4/5 |
| R16 | 75 | Juan Martin del PotroClay | 25 | Igor AndreevClay | 1-6 6-0 6-4 | 3 | 109 | 2 | 4 | 57.4% | 74.4% | 34.5% | 4/8 |
| R16 | 84 | Marat SafinClay | 65 | Michael BerrerClay | 7-6(4) 6-7(5) 6-3 | 3 | 161 | 12 | 2 | 49.1% | 69.6% | 67.2% | 2/4 |
| R16 | 15 | Fernando GonzalezClay | 88 | Kristof VliegenClay | 1-6 7-5 6-3 | 3 | 111 | 5 | 5 | 63.8% | 63.3% | 44.1% | 11/16 |
| QF | 18 | Paul-Henri MathieuClay | 50 | Marin CilicClay | 6-2 4-6 6-3 | 3 | 122 | 3 | 0 | 54.2% | 82.2% | 55.3% | 3/5 |
| QF | 58 | Simone BolelliClay | 55 | Hyung-Taik LeeClay | 6-4 7-6(3) | 3 | 87 | 7 | 1 | 73.3% | 84.1% | 68.8% | 3/4 |
| QF | 295 | MARYounes El AynaouiClay | 75 | Juan Martin del PotroClay | 6-4 6-4 | 3 | 80 | 7 | 1 | 62.3% | 87.9% | 55.0% | 1/2 |
| QF | 15 | Fernando GonzalezClay | 84 | Marat SafinClay | 6-3 7-5 | 3 | 129 | 2 | 2 | 62.3% | 70.8% | 58.6% | 5/6 |
| SF | 58 | Simone BolelliClay | 18 | Paul-Henri MathieuClay | 7-6(1) 4-6 7-6(4) | 3 | 186 | 15 | 3 | 68.8% | 69.3% | 50.0% | 4/7 |
| SF | 15 | Fernando GonzalezClay | 295 | MARYounes El AynaouiClay | 3-6 6-4 6-3 | 3 | 112 | 2 | 3 | 63.9% | 77.4% | 53.3% | 3/5 |
| F | 15 | Fernando GonzalezClay | 58 | Simone BolelliClay | 7-6(4) 6-7(4) 6-3 | 3 | 156 | 4 | 3 | 65.7% | 79.7% | 61.1% | 3/3 |
| R32 | 18 | Paul-Henri MathieuClay | 209 | Daniel BrandsClay | 6-3 6-3 | 3 | 72 | 4 | 1 | 57.4% | 82.9% | 53.8% | 2/2 |
| R32 | 305 | Gianluca NasoClay | 92 | Rainer SchuettlerClay | 6-7(2) 6-3 6-4 | 3 | 154 | 6 | 4 | 48.5% | 69.2% | 55.1% | 9/10 |
| R32 | 121 | Philipp PetzschnerClay | 98 |  Evgeny KorolevClay | 6-4 0-6 6-2 | 3 | 102 | 1 | 4 | 67.2% | 62.2% | 54.5% | 4/8 |
| R32 | 50 | Marin CilicClay | 66 | Olivier RochusClay | 6-4 6-4 | 3 | 84 | 10 | 0 | 56.1% | 81.3% | 60.0% | 1/2 |
| R32 | 184 | Julio SilvaClay | 178 | Matthias BachingerClay | 3-6 6-2 6-3 | 3 | 87 | 7 | 0 | 73.7% | 66.1% | 65.0% | 8/11 |
| R32 | 55 | Hyung-Taik LeeClay | 278 |  Rainer EitzingerClay | 1-6 7-5 6-2 | 3 | 120 | 0 | 3 | 65.3% | 60.6% | 54.3% | 10/13 |
| R32 | 58 | Simone BolelliClay | 61 | Marc GicquelClay | 6-4 6-2 | 3 | 75 | 5 | 1 | 73.1% | 73.7% | 64.3% | 0/0 |
