| R64 | 67 | Florent SerraClay | 64 | Stephane RobertClay | 7-6(6) 3-6 6-4 | 3 | 122 | 6 | 5 | 57.7% | 60.6% | 55.8% | 7/12 |
| R64 | 44 | Ernests GulbisClay | 59 | Marco ChiudinelliClay | 6-3 6-2 | 3 | 71 | 5 | 0 | 58.8% | 70.0% | 66.7% | 0/0 |
| R64 | 20 | Stan WawrinkaClay | 39 | Victor HanescuClay | 6-2 6-4 | 3 | 69 | 11 | 1 | 66.0% | 90.9% | 52.9% | 3/3 |
| R64 | 23 | Tommy RobredoClay | 47 | Horacio ZeballosClay | 6-3 6-3 | 3 | 69 | 3 | 3 | 72.3% | 76.5% | 53.8% | 0/1 |
| R64 | 37 | Viktor TroickiClay | 41 | Lukasz KubotClay | 4-6 6-2 6-2 | 3 | 111 | 6 | 0 | 66.7% | 68.5% | 48.1% | 2/5 |
| R64 | 151 | David NalbandianClay | 55 | Andreas BeckClay | 6-3 6-1 | 3 | 68 | 8 | 1 | 51.2% | 77.3% | 81.0% | 1/1 |
| R64 | 50 | Igor AndreevClay | 114 | Simone BolelliClay | 6-3 6-4 | 3 | 92 | 3 | 4 | 58.1% | 72.1% | 51.6% | 5/6 |
| R64 | 46 | Andreas SeppiClay | 56 | Olivier RochusClay | 7-6(3) RET | 3 | 68 | 1 | 0 | 79.1% | 64.7% | 44.4% | 1/2 |
| R64 | 32 | Albert MontanesClay | 29 | Marcos BaghdatisClay | 6-4 6-2 | 3 | 75 | 2 | 1 | 80.9% | 67.3% | 46.2% | 8/8 |
| R64 | 15 | Tomas BerdychClay | 35 | Feliciano LopezClay | 6-3 6-1 | 3 | 65 | 7 | 3 | 61.9% | 80.8% | 62.5% | 0/1 |
| R64 | 75 | Richard GasquetClay | 100 | Daniel Gimeno-TraverClay | 6-2 4-6 6-2 | 3 | 126 | 2 | 5 | 57.1% | 81.3% | 47.2% | 7/9 |
| R64 | 36 | Julien BenneteauClay | 72 | Alexandr DolgopolovClay | 6-4 5-7 6-2 | 3 | 148 | 5 | 4 | 71.3% | 59.7% | 51.6% | 11/15 |
| R64 | 66 | Michael LlodraClay | 57 | Fabio FogniniClay | 6-3 6-3 | 3 | 74 | 7 | 2 | 65.0% | 79.5% | 47.6% | 1/1 |
| R64 | 85 | Andrey GolubevClay | 43 | Jeremy ChardyClay | 6-2 7-6(2) | 3 | 89 | 2 | 4 | 52.3% | 76.5% | 38.7% | 1/4 |
| R64 | 17 | David FerrerClay | 76 | Peter LuczakClay | 6-2 6-4 | 3 | 97 | 1 | 1 | 68.1% | 61.7% | 68.2% | 3/4 |
| R64 | 27 | Jurgen MelzerClay | 48 | Paul-Henri MathieuClay | 6-3 6-2 | 3 | 89 | 3 | 2 | 46.9% | 82.6% | 53.8% | 2/4 |
| R64 | 49 | Philipp PetzschnerClay | 42 | Guillermo Garcia-LopezClay | 6-3 2-6 6-2 | 3 | 138 | 6 | 1 | 49.4% | 75.0% | 51.2% | 3/5 |
| R64 | 33 | Philipp KohlschreiberClay | 31 | Thomaz BellucciClay | 2-6 6-3 7-6(3) | 3 | 144 | 3 | 2 | 59.8% | 63.6% | 43.2% | 4/10 |
| R64 | 34 | Nicolas AlmagroClay | 58 | Simon GreulClay | 3-6 7-5 6-2 | 3 | 118 | 2 | 2 | 45.9% | 68.9% | 50.9% | 7/11 |
| R64 | 40 | Benjamin BeckerClay | 295 | Bernard TomicClay | 6-4 6-2 | 3 | 76 | 11 | 0 | 63.2% | 72.2% | 61.9% | 2/3 |
| R64 | 16 | Juan Carlos FerreroClay | 89 | Marcel GranollersClay | 6-0 6-3 | 3 | 69 | 0 | 1 | 73.8% | 74.2% | 63.6% | 0/1 |
| R64 | 24 | Juan MonacoClay | 68 | Jarkko NieminenClay | 7-5 7-5 | 3 | 116 | 5 | 1 | 67.6% | 58.3% | 60.9% | 4/8 |
| R64 | 51 | Michael BerrerClay | 71 | Evgeny KorolevClay | 6-1 6-4 | 3 | 64 | 3 | 3 | 71.7% | 68.4% | 53.3% | 5/7 |
| R64 | 77 | Thiemo de BakkerClay | 61 | Eduardo SchwankClay | 6-3 7-5 | 3 | 94 | 10 | 1 | 61.5% | 72.5% | 60.0% | 3/4 |
| R32 | 2 | Novak DjokovicClay | 67 | Florent SerraClay | 6-2 6-3 | 3 | 83 | 2 | 4 | 61.8% | 59.5% | 57.7% | 7/9 |
| R32 | 20 | Stan WawrinkaClay | 44 | Ernests GulbisClay | 6-1 6-4 | 3 | 71 | 5 | 1 | 67.2% | 74.4% | 57.1% | 3/3 |
| R32 | 23 | Tommy RobredoClay | 37 | Viktor TroickiClay | 6-4 6-3 | 3 | 75 | 0 | 0 | 74.1% | 72.5% | 57.1% | 2/3 |
| R32 | 151 | David NalbandianClay | 13 | Mikhail YouzhnyClay | 4-6 6-3 7-6(5) | 3 | 175 | 2 | 5 | 64.4% | 69.2% | 44.4% | 7/11 |
| R32 | 9 | Marin CilicClay | 50 | Igor AndreevClay | 6-7(4) 6-1 6-4 | 3 | 171 | 5 | 1 | 49.5% | 63.6% | 53.6% | 14/18 |
| R32 | 32 | Albert MontanesClay | 46 | Andreas SeppiClay | 7-6(1) 3-6 6-0 | 3 | 125 | 4 | 3 | 66.2% | 64.7% | 42.3% | 3/8 |
| R32 | 15 | Tomas BerdychClay | 75 | Richard GasquetClay | 6-2 6-0 | 3 | 57 | 4 | 1 | 62.8% | 85.2% | 50.0% | 3/3 |
| R32 | 12 | Fernando VerdascoClay | 36 | Julien BenneteauClay | 6-2 6-1 | 3 | 75 | 1 | 1 | 56.8% | 80.0% | 57.9% | 1/1 |
| R32 | 14 | Ivan LjubicicClay | 66 | Michael LlodraClay | 6-3 7-6(3) | 3 | 99 | 8 | 0 | 59.2% | 78.6% | 48.3% | 3/5 |
| R32 | 17 | David FerrerClay | 85 | Andrey GolubevClay | 6-3 6-2 | 3 | 70 | 1 | 2 | 57.8% | 80.8% | 63.2% | 1/2 |
| R32 | 49 | Philipp PetzschnerClay | 27 | Jurgen MelzerClay | 7-6(4) 6-2 | 3 | 93 | 5 | 1 | 45.9% | 66.7% | 54.3% | 3/5 |
| R32 | 33 | Philipp KohlschreiberClay | 4 | Andy MurrayClay | 6-2 6-1 | 3 | 64 | 2 | 1 | 73.0% | 85.2% | 60.0% | 0/0 |
| R32 | 10 | Jo-Wilfried TsongaClay | 34 | Nicolas AlmagroClay | 7-6(5) 7-5 | 3 | 125 | 2 | 3 | 52.1% | 67.3% | 60.0% | 10/11 |
| R32 | 16 | Juan Carlos FerreroClay | 40 | Benjamin BeckerClay | 6-3 6-4 | 3 | 80 | 2 | 0 | 70.6% | 75.0% | 93.3% | 0/0 |
| R32 | 51 | Michael BerrerClay | 24 | Juan MonacoClay | 6-4 6-4 | 3 | 101 | 2 | 1 | 72.1% | 70.5% | 52.9% | 2/3 |
| R32 | 3 | Rafael NadalClay | 77 | Thiemo de BakkerClay | 6-1 6-0 | 3 | 60 | 2 | 1 | 57.1% | 75.0% | 66.7% | 3/3 |
| R16 | 2 | Novak DjokovicClay | 20 | Stan WawrinkaClay | 6-4 6-4 | 3 | 101 | 2 | 1 | 70.5% | 65.1% | 55.6% | 3/5 |
| R16 | 151 | David NalbandianClay | 23 | Tommy RobredoClay | 6-3 6-4 | 3 | 89 | 0 | 2 | 65.2% | 77.8% | 45.8% | 6/7 |
| R16 | 32 | Albert MontanesClay | 9 | Marin CilicClay | 6-4 6-4 | 3 | 96 | 1 | 2 | 59.3% | 77.1% | 50.0% | 7/9 |
| R16 | 12 | Fernando VerdascoClay | 15 | Tomas BerdychClay | 5-7 6-3 6-2 | 3 | 153 | 7 | 4 | 61.9% | 63.3% | 59.5% | 2/5 |
| R16 | 17 | David FerrerClay | 14 | Ivan LjubicicClay | 6-0 7-6(4) | 3 | 91 | 3 | 0 | 75.0% | 71.4% | 71.4% | 1/2 |
| R16 | 33 | Philipp KohlschreiberClay | 49 | Philipp PetzschnerClay | 6-3 6-4 | 3 | 93 | 2 | 1 | 70.5% | 74.4% | 55.6% | 2/2 |
| R16 | 16 | Juan Carlos FerreroClay | 10 | Jo-Wilfried TsongaClay | 6-1 3-6 7-5 | 3 | 135 | 0 | 1 | 72.2% | 64.9% | 72.7% | 0/2 |
| R16 | 3 | Rafael NadalClay | 51 | Michael BerrerClay | 6-0 6-1 | 3 | 54 | 2 | 1 | 71.1% | 77.8% | 72.7% | 0/0 |
| QF | 2 | Novak DjokovicClay | 151 | David NalbandianClay | 6-2 6-3 | 3 | 80 | 2 | 0 | 58.0% | 69.0% | 61.9% | 2/3 |
| QF | 12 | Fernando VerdascoClay | 32 | Albert MontanesClay | 6-3 6-7(4) 6-0 | 3 | 126 | 5 | 3 | 70.2% | 72.9% | 36.0% | 1/4 |
| QF | 17 | David FerrerClay | 33 | Philipp KohlschreiberClay | 7-5 7-6(1) | 3 | 121 | 1 | 2 | 47.7% | 67.7% | 58.8% | 3/7 |
| QF | 3 | Rafael NadalClay | 16 | Juan Carlos FerreroClay | 6-4 6-2 | 3 | 95 | 2 | 0 | 66.7% | 78.1% | 56.3% | 0/1 |
| SF | 12 | Fernando VerdascoClay | 2 | Novak DjokovicClay | 6-2 6-2 | 3 | 92 | 4 | 1 | 77.8% | 71.4% | 50.0% | 2/3 |
| SF | 3 | Rafael NadalClay | 17 | David FerrerClay | 6-2 6-3 | 3 | 75 | 2 | 2 | 70.0% | 65.7% | 53.3% | 2/4 |
| F | 3 | Rafael NadalClay | 12 | Fernando VerdascoClay | 6-0 6-1 | 3 | 86 | 2 | 1 | 68.9% | 64.5% | 64.3% | 5/5 |