| R32 | 57 |  Luciano DarderiClay | 121 |  Tristan BoyerClay | 6-4 6-4 | 3 | 99 | 2 | 4 | 56.2% | 73.2% | 59.4% | 4/4 |
| R32 | 106 |  Vit KoprivaClay | 414 |  Borna GojoClay | 2-6 6-2 6-4 | 3 | 118 | 3 | 3 | 63.1% | 64.2% | 51.6% | 5/9 |
| R32 | 122 |  Kamil MajchrzakClay | 55 |  Jaume MunarClay | 6-4 6-3 | 3 | 89 | 4 | 1 | 63.6% | 77.1% | 65.0% | 2/3 |
| R32 | 71 | Mattia BellucciClay | 107 |  Pavel KotovClay | 6-4 6-4 | 3 | 103 | 9 | 3 | 57.1% | 81.3% | 62.5% | 1/2 |
| R32 | 110 | Pablo Carreno BustaClay | 1193 | MARYounes Lalami LaaroussiClay | 6-1 6-3 | 3 | 77 | 2 | 1 | 59.1% | 84.6% | 72.2% | 1/1 |
| R32 | 98 |  Jesper de JongClay | 608 | MARElliot BenchetritClay | 7-5 6-1 | 3 | 92 | 3 | 1 | 55.6% | 92.0% | 85.0% | 0/0 |
| R32 | 84 |  Hugo GastonClay | 128 |  Juan Manuel CerundoloClay | 5-7 6-3 6-4 | 3 | 138 | 5 | 4 | 51.6% | 69.4% | 45.7% | 3/8 |
| R32 | 169 | Pierre-Hugues HerbertClay | 126 | Federico CoriaClay | 4-6 6-3 6-2 | 3 | 129 | 7 | 12 | 58.6% | 76.5% | 36.1% | 4/8 |
| R32 | 135 |  Otto VirtanenClay | 83 |  Daniel AltmaierClay | 6-2 4-6 7-6(3) | 3 | 149 | 5 | 6 | 59.6% | 71.4% | 60.5% | 1/3 |
| R32 | 51 | Roberto Carballes BaenaClay | 703 | MARTaha BaadiClay | 7-6(3) 6-3 | 3 | 121 | 1 | 7 | 60.8% | 72.9% | 45.2% | 3/5 |
| R32 | 92 |  Raphael CollignonClay | 99 | Fabio FogniniClay | 6-3 6-3 | 3 | 82 | 2 | 4 | 72.7% | 75.0% | 46.7% | 3/4 |
| R32 | 102 |  Hugo DellienClay | 76 |  Aleksandar VukicClay | 7-5 4-6 7-5 | 3 | 152 | 5 | 0 | 77.3% | 67.1% | 68.0% | 3/5 |
| R16 | 37 | Tallon GriekspoorClay | 110 | Pablo Carreno BustaClay | 7-6(1) 3-6 6-3 | 3 | 143 | 13 | 5 | 65.7% | 77.5% | 45.9% | 4/6 |
| R16 | 106 | Vit KoprivaClay | 38 | Lorenzo SonegoClay | 6-2 5-7 6-4 | 3 | 162 | 2 | 5 | 64.4% | 62.7% | 48.6% | 6/10 |
| R16 | 57 | Luciano DarderiClay | 84 | Hugo GastonClay | 2-6 6-2 6-3 | 3 | 111 | 1 | 1 | 59.7% | 69.8% | 48.3% | 0/3 |
| R16 | 71 | Mattia BellucciClay | 169 | Pierre-Hugues HerbertClay | 6-2 7-5 | 3 | 84 | 4 | 0 | 56.0% | 75.0% | 72.7% | 0/1 |
| R16 | 41 | Alexandre MullerClay | 102 | Hugo DellienClay | 6-7(5) 6-1 6-4 | 3 | 145 | 9 | 1 | 67.0% | 68.3% | 71.0% | 1/3 |
| R16 | 43 |  Nuno BorgesClay | 92 | Raphael CollignonClay | 6-2 3-6 7-6(0) | 3 | 119 | 12 | 0 | 71.9% | 81.3% | 40.0% | 4/5 |
| R16 | 51 | Roberto Carballes BaenaClay | 135 | Otto VirtanenClay | 6-4 6-4 | 3 | 80 | 1 | 0 | 77.6% | 66.7% | 61.5% | 2/4 |
| R16 | 122 | Kamil MajchrzakClay | 98 | Jesper de JongClay | 7-6(3) 6-1 | 3 | 88 | 3 | 1 | 62.3% | 78.8% | 75.0% | 0/1 |
| QF | 37 | Tallon GriekspoorClay | 71 | Mattia BellucciClay | 6-3 6-4 | 3 | 84 | 5 | 1 | 56.5% | 77.1% | 66.7% | 4/4 |
| QF | 122 | Kamil MajchrzakClay | 41 | Alexandre MullerClay | 7-5 6-4 | 3 | 96 | 4 | 0 | 70.6% | 72.9% | 50.0% | 8/10 |
| QF | 51 | Roberto Carballes BaenaClay | 43 | Nuno BorgesClay | 6-4 6-4 | 3 | 106 | 1 | 3 | 66.7% | 63.3% | 43.3% | 15/17 |
| QF | 57 | Luciano DarderiClay | 106 | Vit KoprivaClay | 7-5 6-2 | 3 | 116 | 5 | 2 | 56.6% | 67.4% | 57.6% | 5/6 |
| SF | 37 | Tallon GriekspoorClay | 122 | Kamil MajchrzakClay | 7-5 7-6(3) | 3 | 107 | 10 | 1 | 60.0% | 84.4% | 53.3% | 4/5 |
| SF | 57 | Luciano DarderiClay | 51 | Roberto Carballes BaenaClay | 6-3 6-2 | 3 | 92 | 5 | 1 | 50.0% | 79.3% | 55.2% | 2/3 |
| F | 57 | Luciano DarderiClay | 37 | Tallon GriekspoorClay | 7-6(3) 7-6(4) | 3 | 123 | 3 | 3 | 61.4% | 72.5% | 65.6% | 3/4 |
