| R32 | 95 |  Sumit NagalClay | 99 |  Corentin MoutetClay | 4-6 6-3 6-2 | 3 | 130 | 6 | 0 | 74.2% | 66.7% | 69.6% | 6/7 |
| R32 | 67 |  Aleksandar VukicClay | 86 | Alexandre MullerClay | 6-3 7-6(5) | 3 | 101 | 9 | 2 | 66.3% | 78.2% | 50.0% | 9/10 |
| R32 | 82 |  Stan WawrinkaClay | 103 |  Albert Ramos-VinolasClay | 6-1 6-4 | 3 | 75 | 8 | 1 | 57.9% | 87.9% | 33.3% | 4/5 |
| R32 | 60 |  Mariano NavoneClay | 235 |  Aziz DougazClay | 6-3 6-2 | 3 | 76 | 0 | 1 | 74.0% | 75.7% | 76.9% | 0/0 |
| R32 | 73 | Jaume MunarClay | 94 | Luca Van AsscheClay | 7-6(3) 6-2 | 3 | 109 | 8 | 0 | 61.8% | 61.9% | 65.4% | 2/4 |
| R32 | 135 |  Matteo BerrettiniClay | 56 |  Alexander ShevchenkoClay | 6-2 6-1 | 3 | 74 | 3 | 2 | 55.6% | 84.0% | 50.0% | 2/2 |
| R32 | 157 |  Nicolas Moreno De AlboranClay | 55 | Facundo Diaz AcostaClay | 6-4 3-6 6-3 | 3 | 138 | 4 | 2 | 63.6% | 78.6% | 50.0% | 2/3 |
| R32 | 102 |  David GoffinClay | 81 | Arthur RinderknechClay | 6-4 6-4 | 3 | 98 | 5 | 1 | 52.4% | 66.7% | 60.0% | 0/2 |
| R32 | 64 | Roberto Carballes BaenaClay | 145 | Matteo GiganteClay | 6-2 2-0 RET | 3 | 49 | 2 | 0 | 56.0% | 85.7% | 72.7% | 0/0 |
| R32 | 63 | Flavio CobolliClay | 230 |  Abdullah ShelbayhClay | 6-1 6-4 | 3 | 71 | 3 | 2 | 65.1% | 96.4% | 60.0% | 0/0 |
| R32 | 68 |  Pavel KotovClay | 661 | MARElliot BenchetritClay | 7-5 6-3 | 3 | 110 | 1 | 3 | 67.2% | 65.9% | 65.0% | 3/5 |
| R32 | 100 | Fabio FogniniClay | 89 | Hugo GastonClay | 6-7(4) 6-1 6-4 | 3 | 154 | 4 | 8 | 59.0% | 62.9% | 46.5% | 11/16 |
| R16 | 67 | Aleksandar VukicClay | 47 |  Sebastian OfnerClay | 7-6(11) 2-6 7-6(7) | 3 | 168 | 8 | 2 | 61.7% | 71.8% | 59.1% | 5/9 |
| R16 | 60 | Mariano NavoneClay | 82 | Stan WawrinkaClay | 3-6 7-5 6-2 | 3 | 138 | 1 | 5 | 68.8% | 74.5% | 56.0% | 4/6 |
| R16 | 61 | Lorenzo SonegoClay | 95 | Sumit NagalClay | 1-6 6-3 6-4 | 3 | 139 | 4 | 2 | 58.1% | 79.1% | 58.1% | 2/4 |
| R16 | 135 | Matteo BerrettiniClay | 73 | Jaume MunarClay | 6-4 4-6 6-3 | 3 | 140 | 8 | 0 | 68.2% | 74.1% | 44.4% | 4/6 |
| R16 | 157 | Nicolas Moreno De AlboranClay | 102 | David GoffinClay | 6-3 6-4 | 3 | 93 | 5 | 0 | 67.2% | 80.5% | 55.0% | 3/3 |
| R16 | 64 | Roberto Carballes BaenaClay | 42 |  Daniel EvansClay | 6-4 7-6(3) | 3 | 139 | 1 | 1 | 68.7% | 71.9% | 53.8% | 6/7 |
| R16 | 68 | Pavel KotovClay | 63 | Flavio CobolliClay | 6-1 7-6(5) | 3 | 118 | 1 | 1 | 65.5% | 70.2% | 53.3% | 7/7 |
| R16 | 100 | Fabio FogniniClay | 34 |  Laslo DjereClay | 7-6(1) 2-6 6-4 | 3 | 147 | 3 | 0 | 64.4% | 70.7% | 53.1% | 0/3 |
| QF | 60 | Mariano NavoneClay | 67 | Aleksandar VukicClay | 6-2 6-4 | 3 | 81 | 1 | 2 | 74.5% | 88.6% | 50.0% | 0/0 |
| QF | 135 | Matteo BerrettiniClay | 61 | Lorenzo SonegoClay | 6-3 7-6(5) | 3 | 100 | 5 | 4 | 80.9% | 83.6% | 46.2% | 1/1 |
| QF | 64 | Roberto Carballes BaenaClay | 157 | Nicolas Moreno De AlboranClay | 6-4 4-6 6-4 | 3 | 151 | 1 | 2 | 72.8% | 76.3% | 63.6% | 0/1 |
| QF | 68 | Pavel KotovClay | 100 | Fabio FogniniClay | 6-1 6-2 | 3 | 77 | 4 | 1 | 74.0% | 86.5% | 30.8% | 3/3 |
| SF | 135 | Matteo BerrettiniClay | 60 | Mariano NavoneClay | 6-7(4) 6-3 6-2 | 3 | 162 | 6 | 2 | 75.6% | 76.9% | 52.4% | 1/2 |
| SF | 64 | Roberto Carballes BaenaClay | 68 | Pavel KotovClay | 6-4 6-2 | 3 | 99 | 2 | 0 | 72.9% | 65.1% | 68.8% | 6/7 |
| F | 135 | Matteo BerrettiniClay | 64 | Roberto Carballes BaenaClay | 7-5 6-2 | 3 | 106 | 5 | 1 | 71.2% | 74.5% | 47.4% | 7/8 |
