| R32 | 89 |  Victor HanescuClay | 513 | MARHicham KhaddariClay | 7-6(3) 6-3 | 3 | 102 | 3 | 6 | 58.9% | 81.8% | 39.1% | 1/4 |
| R32 | 38 |  Joao SousaClay | 55 |  Igor SijslingClay | 6-2 6-4 | 3 | 58 | 2 | 0 | 58.7% | 81.5% | 57.9% | 1/2 |
| R32 | 273 |  Roberto Carballes BaenaClay | 106 |  David GoffinClay | 6-2 7-5 | 3 | 108 | 3 | 1 | 49.4% | 69.2% | 55.0% | 5/6 |
| R32 | 67 |  Jiri VeselyClay | 87 |  Leonardo MayerClay | 6-4 6-3 | 3 | 85 | 1 | 3 | 48.3% | 85.7% | 56.7% | 1/2 |
| R32 | 266 |  Filip PeliwoClay | 80 |  Filippo VolandriClay | 7-6(6) 6-3 | 3 | 89 | 1 | 1 | 40.6% | 69.2% | 63.2% | 5/7 |
| R32 | 43 | Federico DelbonisClay | 27 |  Gilles SimonClay | 6-4 6-4 | 3 | 84 | 1 | 2 | 60.3% | 76.3% | 60.0% | 2/2 |
| R32 | 104 | Albert Ramos-VinolasClay | 248 | MARLamine OuahabClay | 6-3 2-6 6-1 | 3 | 100 | 2 | 1 | 62.9% | 61.5% | 47.8% | 2/7 |
| R32 | 64 | Pablo Carreno BustaClay | 92 |  Tobias KamkeClay | 6-1 6-2 | 3 | 52 | 7 | 0 | 53.2% | 80.0% | 63.6% | 0/0 |
| R32 | 77 |  Aleksandr NedovyesovClay | 47 | Robin HaaseClay | 7-6(6) 6-4 | 3 | 92 | 4 | 1 | 61.6% | 66.7% | 42.9% | 4/8 |
| R32 | 53 | Guillermo Garcia-LopezClay | 56 | Mikhail KukushkinClay | 7-6(5) 7-6(6) | 3 | 136 | 3 | 7 | 50.5% | 69.6% | 44.4% | 1/5 |
| R32 | 61 | Carlos BerlocqClay | 58 |  Teymuraz GabashviliClay | 6-4 6-1 | 3 | 76 | 3 | 2 | 69.2% | 69.4% | 68.8% | 2/3 |
| R32 | 57 | Albert MontanesClay | 62 | Kenny De SchepperClay | 6-2 6-3 | 3 | 70 | 4 | 3 | 60.4% | 93.1% | 42.1% | 4/4 |
| R16 | 89 | Victor HanescuClay | 19 |  Kevin AndersonClay | 6-4 6-4 | 3 | 86 | 0 | 5 | 67.6% | 75.0% | 52.2% | 5/5 |
| R16 | 43 | Federico DelbonisClay | 266 | Filip PeliwoClay | 6-2 6-7(5) 6-4 | 3 | 130 | 5 | 3 | 57.0% | 75.5% | 55.0% | 1/3 |
| R16 | 36 | Marcel GranollersClay | 104 | Albert Ramos-VinolasClay | 6-3 7-6(3) | 3 | 100 | 8 | 0 | 62.3% | 86.8% | 65.2% | 0/0 |
| R16 | 64 | Pablo Carreno BustaClay | 77 | Aleksandr NedovyesovClay | 3-6 6-1 7-6(3) | 3 | 111 | 4 | 3 | 47.7% | 71.4% | 65.2% | 4/6 |
| R16 | 53 | Guillermo Garcia-LopezClay | 61 | Carlos BerlocqClay | 6-2 7-5 | 3 | 113 | 0 | 1 | 53.2% | 63.6% | 58.6% | 0/2 |
| R16 | 33 | Benoit PaireClay | 57 | Albert MontanesClay | 6-4 5-7 6-4 | 3 | 98 | 13 | 3 | 57.0% | 75.5% | 60.0% | 3/5 |
| R16 | 273 | Roberto Carballes BaenaClay | 38 | Joao SousaClay | 6-7(7) 7-6(5) 6-2 | 3 | 193 | 2 | 9 | 53.8% | 62.0% | 45.9% | 3/10 |
| R16 | 142 |  Andrey KuznetsovClay | 67 | Jiri VeselyClay | 6-2 3-1 RET | 3 | 44 | 1 | 0 | 63.9% | 78.3% | 46.2% | 0/1 |
| QF | 43 | Federico DelbonisClay | 89 | Victor HanescuClay | 7-6(5) 6-3 | 3 | 100 | 1 | 1 | 63.6% | 71.4% | 42.9% | 7/9 |
| QF | 36 | Marcel GranollersClay | 64 | Pablo Carreno BustaClay | 6-7(4) 6-3 6-0 | 3 | 142 | 9 | 6 | 52.1% | 83.7% | 46.7% | 2/3 |
| QF | 53 | Guillermo Garcia-LopezClay | 33 | Benoit PaireClay | 7-5 7-6(4) | 3 | 97 | 0 | 5 | 62.3% | 70.8% | 44.8% | 3/7 |
| QF | 273 | Roberto Carballes BaenaClay | 142 | Andrey KuznetsovClay | 6-4 6-2 | 3 | 88 | 2 | 2 | 63.7% | 60.3% | 57.6% | 14/15 |
| SF | 36 | Marcel GranollersClay | 43 | Federico DelbonisClay | 6-1 6-4 | 3 | 75 | 1 | 0 | 52.2% | 70.8% | 63.6% | 0/1 |
| SF | 53 | Guillermo Garcia-LopezClay | 273 | Roberto Carballes BaenaClay | 6-2 6-7(6) 6-4 | 3 | 167 | 1 | 5 | 70.1% | 64.0% | 43.8% | 3/7 |
| F | 53 | Guillermo Garcia-LopezClay | 36 | Marcel GranollersClay | 5-7 6-4 6-3 | 3 | 159 | 1 | 6 | 62.9% | 76.8% | 48.5% | 3/7 |
