| R32 | 75 |  Filippo VolandriClay | 78 |  Julien BenneteauClay | 7-5 6-3 | 3 | 99 | 0 | 1 | 70.1% | 72.3% | 45.0% | 4/6 |
| R32 | 90 | SLOBlaz KavcicClay | 204 | MARReda El AmraniClay | 3-4 RET | 3 | 32 | 0 | 3 | 76.9% | 60.0% | 33.3% | 1/3 |
| R32 | 52 | Fabio FogniniClay | 331 |  Gerard GranollersClay | 6-2 4-6 6-3 | 3 | 136 | 5 | 10 | 48.0% | 64.6% | 48.1% | 8/13 |
| R32 | 84 | Pere RibaClay | 115 |  Jesse Huta GalungClay | 6-3 6-3 | 3 | 64 | 2 | 1 | 62.5% | 76.7% | 72.2% | 0/0 |
| R32 | 69 | Pablo AndujarClay | 79 | Florent SerraClay | 6-1 3-6 6-2 | 3 | 90 | 3 | 1 | 60.6% | 70.0% | 65.4% | 1/3 |
| R32 | 51 | Jeremy ChardyClay | 112 |  Bjorn PhauClay | 6-2 7-5 | 3 | 99 | 6 | 4 | 56.6% | 69.8% | 51.5% | 3/4 |
| R32 | 47 | Potito StaraceClay | 85 | Daniel BrandsClay | 7-5 6-2 | 3 | 76 | 1 | 0 | 81.1% | 81.4% | 80.0% | 1/1 |
| R32 | 103 | Ruben Ramirez HidalgoClay | 99 |  Rui MachadoClay | 7-5 6-1 | 3 | 93 | 2 | 0 | 54.4% | 64.5% | 73.1% | 1/2 |
| R32 | 83 | Fred GilClay | 114 | Simone BolelliClay | 6-3 6-1 | 3 | 71 | 2 | 0 | 54.8% | 82.6% | 68.4% | 0/0 |
| R32 | 58 |  Victor HanescuClay | 60 | Daniel Gimeno-TraverClay | 4-6 6-4 6-4 | 3 | 150 | 0 | 6 | 52.3% | 70.7% | 47.2% | 13/17 |
| R32 | 81 | Michael BerrerClay | 377 | Nicolas DevilderClay | 6-3 6-3 | 3 | 84 | 4 | 2 | 50.0% | 69.2% | 50.0% | 5/8 |
| R32 | 244 |  Andrey KuznetsovClay | 320 | Sergio Gutierrez-FerrolClay | 6-1 7-6(5) | 3 | 77 | 3 | 0 | 63.2% | 61.1% | 66.7% | 2/4 |
| R16 | 24 | Albert MontanesClay | 75 | Filippo VolandriClay | 6-1 6-4 | 3 | 78 | 8 | 0 | 49.0% | 84.0% | 38.5% | 4/7 |
| R16 | 52 | Fabio FogniniClay | 90 | SLOBlaz KavcicClay | 1-6 7-5 7-5 | 3 | 154 | 3 | 8 | 58.5% | 48.4% | 47.7% | 14/22 |
| R16 | 84 | Pere RibaClay | 40 |  Andrey GolubevClay | 0-6 6-1 7-5 | 3 | 96 | 3 | 4 | 45.7% | 68.8% | 55.3% | 7/12 |
| R16 | 69 | Pablo AndujarClay | 51 | Jeremy ChardyClay | 7-6(6) 6-1 | 3 | 90 | 1 | 0 | 70.5% | 74.4% | 55.6% | 0/2 |
| R16 | 47 | Potito StaraceClay | 103 | Ruben Ramirez HidalgoClay | 6-4 6-3 | 3 | 91 | 0 | 2 | 64.6% | 74.2% | 70.6% | 2/3 |
| R16 | 23 | Gilles SimonClay | 83 | Fred GilClay | 6-3 6-4 | 3 | 84 | 4 | 3 | 54.8% | 82.4% | 53.6% | 1/1 |
| R16 | 58 | Victor HanescuClay | 81 | Michael BerrerClay | 6-4 7-6(4) | 3 | 101 | 6 | 3 | 60.6% | 77.5% | 61.5% | 3/4 |
| R16 | 244 | Andrey KuznetsovClay | 26 |  Marcos BaghdatisClay | 6-4 4-6 6-4 | 3 | 124 | 1 | 3 | 48.9% | 65.9% | 60.9% | 5/9 |
| QF | 24 | Albert MontanesClay | 52 | Fabio FogniniClay | 7-6(1) 6-1 | 3 | 101 | 3 | 5 | 44.3% | 77.4% | 56.4% | 0/1 |
| QF | 69 | Pablo AndujarClay | 84 | Pere RibaClay | 6-2 6-2 | 3 | 74 | 3 | 1 | 79.5% | 82.9% | 22.2% | 0/1 |
| QF | 47 | Potito StaraceClay | 23 | Gilles SimonClay | 6-4 3-6 6-4 | 3 | 140 | 2 | 3 | 64.6% | 66.1% | 47.1% | 7/11 |
| QF | 58 | Victor HanescuClay | 244 | Andrey KuznetsovClay | 6-7(1) 7-5 6-2 | 3 | 133 | 5 | 2 | 65.3% | 69.7% | 54.3% | 5/8 |
| SF | 69 | Pablo AndujarClay | 24 | Albert MontanesClay | 6-4 6-4 | 3 | 114 | 2 | 2 | 77.4% | 58.5% | 42.1% | 13/16 |
| SF | 47 | Potito StaraceClay | 58 | Victor HanescuClay | 6-1 6-7(3) 7-6(2) | 3 | 150 | 2 | 0 | 75.0% | 66.7% | 53.8% | 1/4 |
| F | 69 | Pablo AndujarClay | 47 | Potito StaraceClay | 6-1 6-2 | 3 | 75 | 0 | 2 | 57.4% | 80.6% | 52.2% | 2/2 |
