| R32 | 22 |  Igor AndreevClay | 482 | MARRabie ChakiClay | 3-6 6-3 7-5 | 3 | 122 | 4 | 3 | 69.5% | 73.7% | 52.0% | 5/8 |
| R32 | 60 |  Nicolas DevilderClay | 103 |  Daniel KoellererClay | 6-3 6-4 | 3 | 71 | 6 | 1 | 64.3% | 69.4% | 70.0% | 0/1 |
| R32 | 75 |  Mischa ZverevClay | 120 |  Flavio CipollaClay | 6-2 3-6 6-3 | 3 | 97 | 5 | 4 | 69.7% | 69.8% | 52.2% | 6/9 |
| R32 | 50 | Marc GicquelClay | 92 |  Kristof VliegenClay | 7-5 6-3 | 3 | 68 | 1 | 1 | 46.7% | 85.7% | 66.7% | 1/3 |
| R32 | 39 |  Victor HanescuClay | 97 | Steve DarcisClay | 6-4 7-5 | 3 | 96 | 1 | 2 | 64.4% | 59.6% | 69.2% | 6/8 |
| R32 | 101 |  Ivan NavarroClay | 118 |  Sergiy StakhovskyClay | 7-5 4-2 RET | 3 | 99 | 4 | 1 | 62.0% | 71.0% | 47.4% | 2/4 |
| R32 | 90 | Potito StaraceClay | 64 | Oscar HernandezClay | 4-6 6-3 6-3 | 3 | 107 | 2 | 1 | 69.6% | 75.0% | 71.4% | 1/3 |
| R32 | 115 | Juan Carlos FerreroClay | 61 | Christophe RochusClay | 6-2 6-3 | 3 | 61 | 9 | 1 | 74.4% | 71.9% | 63.6% | 1/2 |
| R32 | 68 |  Ivan LjubicicClay | 57 | Arnaud ClementClay | 7-6(6) 5-7 6-4 | 3 | 178 | 16 | 1 | 57.7% | 78.1% | 53.2% | 3/5 |
| R32 | 70 |  Fred GilClay | 80 | Alberto MartinClay | 6-3 3-6 7-6(4) | 3 | 142 | 3 | 4 | 51.5% | 67.3% | 44.9% | 4/9 |
| R32 | 117 | Santiago VenturaClay | 464 | Oliver MarachClay | 6-1 6-1 | 3 | 42 | 5 | 1 | 75.0% | 86.7% | 40.0% | 1/1 |
| R32 | 35 | Albert MontanesClay | 585 | MARReda El AmraniClay | 6-2 7-5 | 3 | 85 | 2 | 1 | 61.1% | 81.8% | 66.7% | 2/2 |
| R32 | 47 | Florent SerraClay | 63 |  Thomaz BellucciClay | 6-3 6-3 | 3 | 77 | 5 | 1 | 61.4% | 71.4% | 54.5% | 3/4 |
| R32 | 125 | Olivier RochusClay | 747 | MARMehdi ZiadiClay | 4-6 6-2 6-1 | 3 | 115 | 1 | 0 | 67.9% | 73.6% | 52.0% | 8/10 |
| R32 | 69 |  Teymuraz GabashviliClay | 107 | Fabio FogniniClay | 6-2 6-1 | 3 | 45 | 5 | 2 | 52.3% | 78.3% | 66.7% | 1/1 |
| R32 | 119 | Ruben Ramirez HidalgoClay | 29 | Rainer SchuettlerClay | 6-4 7-6(5) | 3 | 135 | 2 | 1 | 54.1% | 76.1% | 51.3% | 3/4 |
| R16 | 22 | Igor AndreevClay | 60 | Nicolas DevilderClay | 6-7(11) 7-6(5) 6-4 | 3 | 197 | 3 | 1 | 61.2% | 68.9% | 66.0% | 4/5 |
| R16 | 50 | Marc GicquelClay | 75 | Mischa ZverevClay | 6-4 7-5 | 3 | 98 | 1 | 0 | 58.2% | 69.6% | 45.5% | 7/9 |
| R16 | 39 | Victor HanescuClay | 101 | Ivan NavarroClay | 6-1 6-0 | 3 | 48 | 6 | 1 | 62.9% | 86.4% | 69.2% | 0/0 |
| R16 | 115 | Juan Carlos FerreroClay | 90 | Potito StaraceClay | 6-4 7-6(1) | 3 | 110 | 3 | 1 | 74.7% | 66.1% | 50.0% | 7/10 |
| R16 | 70 | Fred GilClay | 68 | Ivan LjubicicClay | 6-7(2) 7-5 6-4 | 3 | 175 | 5 | 4 | 53.4% | 79.0% | 50.0% | 5/6 |
| R16 | 35 | Albert MontanesClay | 117 | Santiago VenturaClay | 5-7 6-3 7-5 | 3 | 135 | 0 | 7 | 59.1% | 66.2% | 42.6% | 8/14 |
| R16 | 47 | Florent SerraClay | 125 | Olivier RochusClay | 6-3 6-3 | 3 | 86 | 3 | 1 | 55.2% | 68.8% | 53.8% | 3/5 |
| R16 | 69 | Teymuraz GabashviliClay | 119 | Ruben Ramirez HidalgoClay | 6-4 6-4 | 3 | 107 | 4 | 6 | 56.3% | 75.5% | 47.4% | 7/7 |
| QF | 22 | Igor AndreevClay | 50 | Marc GicquelClay | 6-1 6-3 | 3 | 53 | 5 | 1 | 73.0% | 88.9% | 80.0% | 0/0 |
| QF | 115 | Juan Carlos FerreroClay | 39 | Victor HanescuClay | 6-3 7-5 | 3 | 93 | 3 | 0 | 82.4% | 73.8% | 77.8% | 0/1 |
| QF | 35 | Albert MontanesClay | 70 | Fred GilClay | 7-6(5) 6-4 | 3 | 102 | 6 | 6 | 51.5% | 73.5% | 56.3% | 0/2 |
| QF | 47 | Florent SerraClay | 69 | Teymuraz GabashviliClay | 6-0 6-4 | 3 | 64 | 2 | 1 | 51.1% | 73.9% | 59.1% | 0/1 |
| SF | 115 | Juan Carlos FerreroClay | 22 | Igor AndreevClay | 7-6(9) 6-3 | 3 | 125 | 0 | 1 | 66.3% | 71.7% | 51.9% | 1/3 |
| SF | 47 | Florent SerraClay | 35 | Albert MontanesClay | 6-4 6-4 | 3 | 89 | 4 | 2 | 54.9% | 66.7% | 62.5% | 3/4 |
| F | 115 | Juan Carlos FerreroClay | 47 | Florent SerraClay | 6-4 7-5 | 3 | 97 | 5 | 3 | 71.2% | 69.0% | 29.4% | 3/7 |
