| R32 | 24 |  Dominik HrbatyClay | 93 |  Alexander PeyaClay | 7-6(7) 6-4 | 3 | 90 | 5 | 0 | 64.1% | 78.0% | 65.2% | 2/3 |
| R32 | 524 |  Slimane SaoudiClay | 460 | MARRabie ChakiClay | 6-2 6-1 | 3 | 59 | 1 | 2 | 67.4% | 82.8% | 64.3% | 1/1 |
| R32 | 77 |  Albert MontanesClay | 96 |  Danai UdomchokeClay | 1-6 6-3 7-5 | 3 | 101 | 3 | 3 | 56.5% | 70.8% | 54.1% | 3/6 |
| R32 | 52 |  Nicolas MassuClay | 79 |  Sergio RoitmanClay | 6-2 6-3 | 3 | 74 | 2 | 3 | 56.5% | 73.1% | 55.0% | 1/2 |
| R32 | 59 | Ruben Ramirez HidalgoClay | 54 |  Gilles SimonClay | 6-4 6-4 | 3 | 78 | 2 | 6 | 58.1% | 77.8% | 53.8% | 1/2 |
| R32 | 198 | Thierry AscioneClay | 134 | MARYounes El AynaouiClay | 6-4 6-3 | 3 | 77 | 4 | 3 | 66.1% | 74.4% | 50.0% | 5/7 |
| R32 | 63 | Sebastien GrosjeanClay | 592 |  Victor HanescuClay | 7-6(4) 6-4 | 3 | 97 | 4 | 1 | 52.1% | 78.9% | 60.0% | 7/8 |
| R32 | 50 | Arnaud ClementClay | 87 |  Ernests GulbisClay | 7-6(1) 6-3 | 3 | 88 | 2 | 2 | 53.1% | 76.5% | 70.0% | 3/3 |
| R32 | 44 | Marc GicquelClay | 116 |  Alessio Di MauroClay | 6-4 6-2 | 3 | 66 | 6 | 0 | 61.7% | 69.0% | 77.8% | 0/1 |
| R32 | 106 | Nicolas MahutClay | 74 | Florent SerraClay | 6-2 6-4 | 3 | 78 | 2 | 1 | 54.2% | 75.0% | 59.3% | 3/4 |
| R32 | 67 |  Michael RussellClay | 81 | Diego HartfieldClay | 6-1 6-4 | 3 | 78 | 2 | 3 | 66.7% | 87.5% | 37.5% | 0/1 |
| R32 | 39 | Julien BenneteauClay | 139 |  Fred GilClay | 7-6(2) 3-6 7-6(5) | 3 | 170 | 6 | 5 | 66.9% | 67.9% | 52.5% | 16/20 |
| R32 | 57 | Paul-Henri MathieuClay | 83 |  Kristian PlessClay | 6-3 6-1 | 3 | 132 | 4 | 0 | 62.2% | 85.7% | 64.7% | 3/3 |
| R32 | 163 | Edouard Roger-VasselinClay | 58 | Martin Vassallo ArguelloClay | 6-2 6-2 | 3 | 102 | 2 | 3 | 69.5% | 68.3% | 44.4% | 4/5 |
| R32 | 91 |  Janko TipsarevicClay | 85 | Michael LlodraClay | 6-2 7-6(6) | 3 | 95 | 7 | 0 | 47.6% | 80.0% | 60.6% | 0/1 |
| R32 | 37 | Jose AcasusoClay | 92 | Nicolas DevilderClay | 6-4 6-4 | 3 | 76 | 2 | 0 | 57.9% | 78.8% | 54.2% | 0/1 |
| R16 | 24 | Dominik HrbatyClay | 524 | Slimane SaoudiClay | 7-5 7-6(2) | 3 | 99 | 3 | 4 | 57.1% | 65.9% | 48.5% | 3/7 |
| R16 | 77 | Albert MontanesClay | 52 | Nicolas MassuClay | 6-1 2-1 RET | 3 | 56 | 2 | 1 | 56.7% | 82.4% | 46.2% | 2/3 |
| R16 | 59 | Ruben Ramirez HidalgoClay | 198 | Thierry AscioneClay | 6-4 7-6(4) | 3 | 90 | 5 | 1 | 47.6% | 83.3% | 63.6% | 4/5 |
| R16 | 63 | Sebastien GrosjeanClay | 50 | Arnaud ClementClay | 4-6 7-5 6-1 | 3 | 147 | 8 | 1 | 42.9% | 76.9% | 59.6% | 4/6 |
| R16 | 44 | Marc GicquelClay | 106 | Nicolas MahutClay | 6-2 6-4 | 3 | 76 | 10 | 0 | 53.2% | 72.7% | 62.1% | 2/2 |
| R16 | 39 | Julien BenneteauClay | 67 | Michael RussellClay | 6-3 6-3 | 3 | 84 | 8 | 1 | 75.5% | 73.0% | 75.0% | 2/3 |
| R16 | 57 | Paul-Henri MathieuClay | 163 | Edouard Roger-VasselinClay | 4-6 6-3 6-4 | 3 | 138 | 3 | 1 | 58.5% | 69.1% | 74.4% | 3/4 |
| R16 | 37 | Jose AcasusoClay | 91 | Janko TipsarevicClay | 6-4 6-4 | 3 | 74 | 6 | 1 | 51.8% | 69.0% | 55.6% | 0/2 |
| QF | 77 | Albert MontanesClay | 24 | Dominik HrbatyClay | 7-6(5) 6-3 | 3 | 88 | 8 | 2 | 59.2% | 83.3% | 48.3% | 2/3 |
| QF | 59 | Ruben Ramirez HidalgoClay | 63 | Sebastien GrosjeanClay | 1-6 7-5 7-6(3) | 3 | 155 | 3 | 4 | 57.8% | 66.7% | 43.5% | 8/13 |
| QF | 44 | Marc GicquelClay | 39 | Julien BenneteauClay | 3-6 6-1 6-1 | 3 | 95 | 6 | 0 | 67.7% | 69.0% | 65.0% | 2/4 |
| QF | 57 | Paul-Henri MathieuClay | 37 | Jose AcasusoClay | 7-6(5) 6-4 | 3 | 106 | 3 | 0 | 56.9% | 73.0% | 60.7% | 3/6 |
| SF | 77 | Albert MontanesClay | 59 | Ruben Ramirez HidalgoClay | 1-6 7-5 6-3 | 3 | 132 | 1 | 4 | 63.4% | 67.8% | 41.2% | 3/7 |
| SF | 57 | Paul-Henri MathieuClay | 44 | Marc GicquelClay | 6-3 7-5 | 3 | 95 | 7 | 0 | 59.0% | 77.8% | 68.0% | 1/2 |
| F | 57 | Paul-Henri MathieuClay | 77 | Albert MontanesClay | 6-1 6-1 | 3 | 63 | 5 | 0 | 50.0% | 94.4% | 66.7% | 1/1 |
