| R32 | 32 |  Dominik HrbatyClay | 149 |  Philipp KohlschreiberClay | 6-2 6-2 | 3 | 65 | 4 | 1 | 57.1% | 84.4% | 45.8% | 6/6 |
| R32 | 150 |  Alex CalatravaClay | 101 |  Gilles ElseneerClay | 6-3 4-6 6-4 | 3 | 108 | 4 | 4 | 71.1% | 55.9% | 50.0% | 6/11 |
| R32 | 136 |  Juan-Pablo GuzmanClay | 165 |  Eric TainoClay | 6-2 6-1 | 3 | 59 | 0 | 2 | 52.0% | 76.9% | 54.2% | 3/3 |
| R32 | 90 | Oscar HernandezClay | 451 | MARMounir El AarejClay | 6-4 6-4 | 3 | 94 | 0 | 4 | 65.0% | 69.2% | 61.9% | 3/4 |
| R32 | 109 |  Julien BenneteauClay | 80 | Ruben Ramirez HidalgoClay | 6-4 6-2 | 3 | 100 | 1 | 5 | 58.9% | 67.4% | 53.3% | 6/7 |
| R32 | 574 | Julien BoutterClay | - | MARMehdi ZiadiClay | 6-1 3-6 6-1 | 3 | 86 | 2 | 8 | 49.3% | 75.8% | 64.7% | 2/3 |
| R32 | 181 | Federico BrowneClay | 422 |  Zeljko KrajanClay | 6-3 7-5 | 3 | 86 | 2 | 8 | 49.3% | 75.8% | 64.7% | 2/3 |
| R32 | 91 | Thierry AscioneClay | 663 | MARMehdi TahiriClay | 6-3 6-4 | 3 | 71 | 0 | 0 | 69.2% | 72.2% | 62.5% | 4/6 |
| R32 | 79 | Cyril SaulnierClay | 129 |  Stefano PescosolidoClay | 6-3 6-2 | 3 | 55 | 5 | 2 | 54.2% | 84.6% | 68.2% | 1/1 |
| R32 | 133 | Christophe RochusClay | 146 | Fernando VicenteClay | 7-5 6-1 | 3 | 78 | 1 | 6 | 53.5% | 73.7% | 30.3% | 5/9 |
| R32 | 107 | Albert PortasClay | 121 | Olivier MutisClay | 6-2 7-5 | 3 | 71 | 5 | 2 | 51.6% | 75.0% | 53.3% | 4/5 |
| R32 | 82 | Antony DupuisClay | 432 | Arnaud Di PasqualeClay | 7-6(7) 6-4 | 3 | 123 | 3 | 3 | 48.9% | 72.7% | 47.8% | 7/9 |
| R32 | 141 |  Ivo HeubergerClay | - |  Dennis Van ScheppingenClay | 6-4 6-2 | 3 | 77 | 2 | 7 | 35.1% | 80.0% | 45.9% | 5/7 |
| R32 | 407 | Simone VagnozziClay | 125 |  Jean-Rene LisnardClay | 7-6(7) 6-1 | 3 | 77 | 2 | 7 | 35.1% | 80.0% | 45.9% | 5/7 |
| R32 | 316 | Santiago VenturaClay | 155 |  Razvan SabauClay | 6-2 6-3 | 3 | 77 | 2 | 7 | 35.1% | 80.0% | 45.9% | 5/7 |
| R32 | 111 | Nicolas MahutClay | 196 |  Bjorn RehnquistClay | 6-1 6-2 | 3 | 77 | 2 | 7 | 35.1% | 80.0% | 45.9% | 5/7 |
| R16 | 32 | Dominik HrbatyClay | 150 | Alex CalatravaClay | 5-7 6-4 6-4 | 3 | 147 | 6 | 3 | 56.7% | 72.7% | 45.2% | 7/11 |
| R16 | 90 | Oscar HernandezClay | 136 | Juan-Pablo GuzmanClay | 6-4 1-6 7-6(3) | 3 | 138 | 3 | 0 | 65.1% | 66.1% | 46.7% | 8/13 |
| R16 | 109 | Julien BenneteauClay | 574 | Julien BoutterClay | 2-6 6-3 6-4 | 3 | 117 | 4 | 3 | 62.7% | 55.8% | 54.8% | 4/9 |
| R16 | 91 | Thierry AscioneClay | 181 | Federico BrowneClay | 6-2 3-1 RET | 3 | 45 | 1 | 2 | 59.0% | 78.3% | 56.3% | 2/2 |
| R16 | 133 | Christophe RochusClay | 79 | Cyril SaulnierClay | 6-0 6-3 | 3 | 57 | 1 | 1 | 64.3% | 63.0% | 73.3% | 1/2 |
| R16 | 82 | Antony DupuisClay | 107 | Albert PortasClay | 7-6(4) 7-6(2) | 3 | 109 | 13 | 1 | 57.1% | 84.1% | 60.6% | 2/3 |
| R16 | 141 | Ivo HeubergerClay | 407 | Simone VagnozziClay | 6-3 6-4 | 3 | 103 | 7 | 3 | 45.3% | 73.5% | 48.8% | 7/9 |
| R16 | 316 | Santiago VenturaClay | 111 | Nicolas MahutClay | 7-6(5) 6-4 | 3 | 94 | 4 | 3 | 55.6% | 67.5% | 59.4% | 2/4 |
| QF | 32 | Dominik HrbatyClay | 90 | Oscar HernandezClay | 6-3 6-0 | 3 | 56 | 0 | 2 | 54.7% | 86.2% | 50.0% | 3/3 |
| QF | 109 | Julien BenneteauClay | 91 | Thierry AscioneClay | 6-3 6-4 | 3 | 75 | 2 | 0 | 66.1% | 71.8% | 65.0% | 5/5 |
| QF | 133 | Christophe RochusClay | 82 | Antony DupuisClay | 6-3 6-1 | 3 | 58 | 3 | 1 | 60.9% | 82.1% | 61.1% | 2/2 |
| QF | 316 | Santiago VenturaClay | 141 | Ivo HeubergerClay | 6-2 6-4 | 3 | 86 | 2 | 3 | 40.3% | 68.0% | 62.2% | 4/5 |
| SF | 32 | Dominik HrbatyClay | 109 | Julien BenneteauClay | 6-2 6-2 | 3 | 61 | 7 | 2 | 63.0% | 79.4% | 45.0% | 4/4 |
| SF | 316 | Santiago VenturaClay | 133 | Christophe RochusClay | 6-1 1-6 6-2 | 3 | 96 | 2 | 2 | 53.2% | 65.9% | 50.0% | 6/9 |
| F | 316 | Santiago VenturaClay | 32 | Dominik HrbatyClay | 6-3 1-6 6-4 | 3 | 116 | 6 | 7 | 44.6% | 75.7% | 52.2% | 6/8 |
