| R32 | 2 |  Gustavo KuertenClay | 83 |  Nikolay DavydenkoClay | 6-2 6-3 | 3 | 75 | 5 | 0 | 49.0% | 75.0% | 52.0% | 3/5 |
| R32 | 158 |  Magnus NormanClay | 340 |  Mariano Albert-FerrandoClay | 6-3 6-4 | 3 | 98 | 3 | 0 | 61.8% | 76.6% | 51.7% | 6/6 |
| R32 | 94 |  Cedric PiolineClay | 107 |  Jose AcasusoClay | 6-3 6-7(4) 6-4 | 3 | 150 | 12 | 9 | 58.6% | 70.6% | 43.8% | 1/4 |
| R32 | 37 | Gaston GaudioClay | 73 | Fernando VicenteClay | 0-6 6-3 6-2 | 3 | 84 | 1 | 2 | 64.1% | 58.5% | 56.5% | 9/13 |
| R32 | 70 |  Olivier RochusClay | 33 |  Sjeng SchalkenClay | 6-2 3-6 7-5 | 3 | 125 | 3 | 2 | 66.7% | 56.5% | 51.6% | 5/11 |
| R32 | 762 | Rafael NadalClay | 81 |  Ramon DelgadoClay | 6-4 6-4 | 3 | 83 | 1 | 1 | 89.4% | 61.0% | 42.9% | 6/9 |
| R32 | 105 | Juan BalcellsClay | 67 | Antony DupuisClay | 7-5 6-4 | 3 | 86 | 8 | 2 | 67.1% | 73.6% | 42.3% | 3/4 |
| R32 | 61 | Agustin CalleriClay | 84 |  Markus HipflClay | 6-0 6-2 | 3 | 55 | 4 | 0 | 57.6% | 89.5% | 78.6% | 0/0 |
| R32 | 63 |  Dominik HrbatyClay | 154 | Guillermo CoriaClay | 6-0 1-0 RET | 3 | 33 | 0 | 1 | 65.0% | 92.3% | 42.9% | 0/0 |
| R32 | 82 | Christophe RochusClay | 66 |  Kristian PlessClay | 7-6(7) 2-6 6-2 | 3 | 117 | 3 | 4 | 60.0% | 65.0% | 47.5% | 4/9 |
| R32 | 95 | Galo BlancoClay | 91 |  Hyung-Taik LeeClay | 6-3 6-3 | 3 | 75 | 4 | 2 | 42.0% | 76.2% | 51.7% | 1/3 |
| R32 | 54 |  Jarkko NieminenClay | 85 | Andre SaClay | 6-1 6-2 | 3 | 60 | 1 | 1 | 75.9% | 63.6% | 78.6% | 8/8 |
| R32 | 62 | Albert MontanesClay | 98 |  Michael RussellClay | 6-7(5) 7-6(5) 6-4 | 3 | 180 | 7 | 3 | 63.4% | 61.1% | 57.7% | 13/16 |
| R32 | 74 | David SanchezClay | 69 |  Paradorn SrichaphanClay | 6-2 6-4 | 3 | 76 | 0 | 3 | 68.3% | 69.8% | 70.0% | 3/3 |
| R32 | 197 | Jean-Francois BachelotClay | 191 |  Mario RadicClay | 6-4 6-2 | 3 | 71 | 5 | 2 | 38.6% | 81.8% | 60.0% | 1/2 |
| R32 | 68 | Mariano ZabaletaClay | 30 | Albert PortasClay | 6-1 6-4 | 3 | 65 | 3 | 0 | 54.7% | 89.7% | 45.8% | 1/2 |
| R16 | 2 | Gustavo KuertenClay | 158 | Magnus NormanClay | 6-1 5-7 6-3 | 3 | 139 | 6 | 3 | 50.0% | 75.0% | 45.5% | 5/8 |
| R16 | 37 | Gaston GaudioClay | 94 | Cedric PiolineClay | 6-1 6-3 | 3 | 61 | 7 | 0 | 77.8% | 77.1% | 50.0% | 2/3 |
| R16 | 70 | Olivier RochusClay | 762 | Rafael NadalClay | 6-2 6-2 | 3 | 62 | 1 | 0 | 70.8% | 67.6% | 85.7% | 0/0 |
| R16 | 61 | Agustin CalleriClay | 105 | Juan BalcellsClay | 6-3 6-1 | 3 | 59 | 6 | 1 | 53.1% | 73.1% | 69.6% | 1/1 |
| R16 | 63 | Dominik HrbatyClay | 82 | Christophe RochusClay | 6-4 6-4 | 3 | 70 | 6 | 4 | 69.1% | 74.5% | 28.6% | 2/4 |
| R16 | 54 | Jarkko NieminenClay | 95 | Galo BlancoClay | 6-0 6-3 | 3 | 65 | 2 | 0 | 60.9% | 82.1% | 55.6% | 2/2 |
| R16 | 74 | David SanchezClay | 62 | Albert MontanesClay | 7-6(5) 6-4 | 3 | 104 | 4 | 1 | 72.5% | 68.0% | 78.9% | 3/4 |
| R16 | 68 | Mariano ZabaletaClay | 197 | Jean-Francois BachelotClay | 4-6 7-5 6-0 | 3 | 125 | 5 | 1 | 66.3% | 66.7% | 65.5% | 3/5 |
| QF | 37 | Gaston GaudioClay | 2 | Gustavo KuertenClay | 7-5 6-0 | 3 | 61 | 5 | 1 | 72.9% | 82.9% | 69.2% | 2/2 |
| QF | 61 | Agustin CalleriClay | 70 | Olivier RochusClay | 6-3 0-6 6-1 | 3 | 76 | 3 | 1 | 63.2% | 60.5% | 56.0% | 3/6 |
| QF | 54 | Jarkko NieminenClay | 63 | Dominik HrbatyClay | 6-4 7-6(2) | 3 | 94 | 2 | 3 | 70.0% | 58.7% | 40.7% | 13/19 |
| QF | 68 | Mariano ZabaletaClay | 74 | David SanchezClay | 7-5 6-3 | 3 | 95 | 2 | 0 | 57.9% | 81.8% | 54.2% | 0/2 |
| SF | 37 | Gaston GaudioClay | 61 | Agustin CalleriClay | 4-6 6-3 6-2 | 3 | 100 | 1 | 1 | 61.3% | 75.5% | 58.1% | 4/6 |
| SF | 54 | Jarkko NieminenClay | 68 | Mariano ZabaletaClay | 6-1 6-3 | 3 | 72 | 3 | 0 | 68.2% | 73.3% | 78.6% | 0/0 |
| F | 37 | Gaston GaudioClay | 54 | Jarkko NieminenClay | 6-2 6-3 | 3 | 60 | 5 | 0 | 68.9% | 71.0% | 78.6% | 2/3 |
