| R32 | 278 |  Juan BalcellsClay | 15 | Carlos MoyaClay | 4-6 6-3 6-3 | 3 | 106 | 10 | 3 | 71.1% | 60.9% | 53.6% | 4/8 |
| R32 | 131 | Julian AlonsoClay | 143 |  Oliver GrossClay | 6-2 6-7(5) 7-6(6) | 3 | 148 | 5 | 2 | 57.5% | 67.2% | 73.3% | 2/3 |
| R32 | 71 |  Juan Antonio MarinClay | 182 | Roberto CarreteroClay | 7-6(4) 6-0 | 3 | 84 | 3 | 4 | 56.9% | 84.8% | 52.0% | 1/2 |
| R32 | 46 | Rainer SchuettlerClay | 89 | Alberto BerasateguiClay | 7-6(6) 7-5 | 3 | 93 | 1 | 1 | 72.3% | 68.1% | 50.0% | 0/3 |
| R32 | 111 |  Orlin StanoytchevClay | 22 | Albert CostaClay | 6-3 6-7(3) 6-3 | 3 | 129 | 6 | 5 | 50.5% | 80.4% | 71.1% | 1/1 |
| R32 | 68 | Juan Carlos FerreroClay | 242 | Tommy RobredoClay | 6-4 6-3 | 3 | 75 | 1 | 0 | 67.3% | 67.6% | 66.7% | 6/7 |
| R32 | 81 | Jens KnippschildClay | 75 | Galo BlancoClay | 6-3 5-7 6-2 | 3 | 128 | 12 | 9 | 46.3% | 88.6% | 45.1% | 8/11 |
| R32 | 29 | Francisco ClavetClay | 66 | Albert PortasClay | 3-6 7-6(3) 6-4 | 3 | 129 | 6 | 2 | 58.8% | 75.4% | 37.5% | 6/11 |
| R32 | 158 | Juan Albert Viloca-PuigClay | 41 | Fernando VicenteClay | 6-3 5-7 6-4 | 3 | 134 | 9 | 5 | 64.8% | 70.6% | 43.2% | 8/12 |
| R32 | 73 |  Markus HipflClay | 72 |  Gaston GaudioClay | 7-5 6-1 | 3 | 90 | 3 | 0 | 68.1% | 71.9% | 53.3% | 1/3 |
| R32 | 65 | Mariano PuertaClay | 360 | Carlos CostaClay | 6-4 6-1 | 3 | 66 | 0 | 2 | 69.2% | 77.8% | 43.8% | 2/3 |
| R32 | 25 |  Dominik HrbatyClay | 117 | German PuentesClay | 5-7 7-5 6-1 | 3 | 139 | 7 | 5 | 47.7% | 69.2% | 47.4% | 10/16 |
| R32 | 47 | Franco SquillariClay | 88 |  Marcelo FilippiniClay | 6-3 7-5 | 3 | 89 | 1 | 2 | 50.0% | 75.8% | 60.6% | 2/3 |
| R32 | 91 | Hernan GumyClay | 173 | Alex CalatravaClay | 7-6(15) 4-6 7-5 | 3 | 214 | 3 | 4 | 65.6% | 61.9% | 56.8% | 13/17 |
| R32 | 54 | Alberto MartinClay | 97 | Martin RodriguezClay | 7-6(4) 6-2 | 3 | 95 | 1 | 2 | 63.0% | 64.7% | 56.7% | 4/5 |
| R32 | 11 | Alex CorretjaClay | 52 | David PrinosilClay | 6-4 6-1 | 3 | 81 | 5 | 2 | 44.1% | 73.3% | 71.1% | 3/3 |
| R16 | 131 | Julian AlonsoClay | 278 | Juan BalcellsClay | 7-6(6) 6-4 | 3 | 82 | 3 | 6 | 62.3% | 88.4% | 53.8% | 3/3 |
| R16 | 71 | Juan Antonio MarinClay | 46 | Rainer SchuettlerClay | 6-3 6-1 | 3 | 68 | 2 | 4 | 55.6% | 70.0% | 45.8% | 6/8 |
| R16 | 68 | Juan Carlos FerreroClay | 111 | Orlin StanoytchevClay | 6-3 7-6(4) | 3 | 105 | 2 | 2 | 75.3% | 69.1% | 55.6% | 2/4 |
| R16 | 29 | Francisco ClavetClay | 81 | Jens KnippschildClay | 6-7(3) 6-4 6-4 | 3 | 154 | 1 | 4 | 60.8% | 60.3% | 63.8% | 12/14 |
| R16 | 73 | Markus HipflClay | 158 | Juan Albert Viloca-PuigClay | 6-4 6-0 | 3 | 77 | 2 | 4 | 61.9% | 88.5% | 56.3% | 0/0 |
| R16 | 25 | Dominik HrbatyClay | 65 | Mariano PuertaClay | 7-6(5) 6-3 | 3 | 81 | 5 | 4 | 43.3% | 80.8% | 64.7% | 1/2 |
| R16 | 91 | Hernan GumyClay | 47 | Franco SquillariClay | 7-6(4) 6-3 | 3 | 116 | 2 | 3 | 64.8% | 73.7% | 48.4% | 5/6 |
| R16 | 11 | Alex CorretjaClay | 54 | Alberto MartinClay | 6-1 6-2 | 3 | 70 | 5 | 3 | 35.4% | 82.4% | 67.7% | 3/3 |
| QF | 131 | Julian AlonsoClay | 71 | Juan Antonio MarinClay | 7-6(5) 7-5 | 3 | 110 | 3 | 3 | 50.0% | 57.5% | 62.5% | 2/6 |
| QF | 68 | Juan Carlos FerreroClay | 29 | Francisco ClavetClay | 6-3 6-3 | 3 | 62 | 3 | 0 | 60.5% | 73.9% | 86.7% | 3/3 |
| QF | 25 | Dominik HrbatyClay | 73 | Markus HipflClay | 4-6 7-5 6-3 | 3 | 125 | 8 | 3 | 52.7% | 77.1% | 53.5% | 5/8 |
| QF | 11 | Alex CorretjaClay | 91 | Hernan GumyClay | 6-3 6-2 | 3 | 94 | 3 | 4 | 42.9% | 81.5% | 47.2% | 2/3 |
| SF | 68 | Juan Carlos FerreroClay | 131 | Julian AlonsoClay | 6-2 7-6(11) | 3 | 98 | 0 | 3 | 75.0% | 72.9% | 50.0% | 2/4 |
| SF | 11 | Alex CorretjaClay | 25 | Dominik HrbatyClay | 6-4 6-4 | 3 | 83 | 7 | 0 | 55.4% | 83.3% | 41.4% | 5/6 |
| F | 68 | Juan Carlos FerreroClay | 11 | Alex CorretjaClay | 2-6 7-5 6-3 | 3 | 164 | 3 | 3 | 72.3% | 60.3% | 50.0% | 6/10 |
