| R32 | 23 |  Alberto BerasateguiClay | 120 | Albert PortasClay | 6-3 6-3 | 3 | 62 | 1 | 1 | 85.2% | 71.2% | 33.3% | 4/5 |
| R32 | 109 |  Marcos OndruskaClay | 63 | Jordi BurilloClay | 3-6 6-3 6-2 | 3 | 100 | 4 | 5 | 51.3% | 72.5% | 52.6% | 7/10 |
| R32 | 69 |  Sjeng SchalkenClay | 93 | Carlos MoyaClay | 6-2 6-2 | 3 | 51 | 3 | 3 | 51.1% | 87.0% | 45.5% | 5/6 |
| R32 | 41 |  Bohdan UlihrachClay | 177 | Emilio Benfele AlvarezClay | 6-3 6-3 | 3 | 80 | 1 | 1 | 45.9% | 71.4% | 66.7% | 5/5 |
| R32 | 25 | Albert CostaClay | 124 |  Gaston EtlisClay | 6-3 6-3 | 3 | 64 | 2 | 1 | 64.4% | 76.3% | 42.9% | 1/2 |
| R32 | 100 |  Magnus GustafssonClay | 85 |  Carl-Uwe SteebClay | 6-2 6-0 | 3 | 54 | 2 | 3 | 45.7% | 71.4% | 72.0% | 2/2 |
| R32 | 136 | Felix MantillaClay | 107 | Oscar MartinezClay | 6-1 6-3 | 3 | 67 | 0 | 1 | 56.5% | 76.9% | 55.0% | 2/3 |
| R32 | 118 |  Kris GoossensClay | 31 | Carlos CostaClay | 7-6(6) 6-0 | 3 | 97 | 2 | 4 | 50.8% | 66.7% | 40.6% | 5/9 |
| R32 | 27 | Francisco ClavetClay | 340 | Libor NemecekClay | 6-1 6-1 | 3 | 46 | 3 | 0 | 62.9% | 86.4% | 76.9% | 0/0 |
| R32 | 83 | Hernan GumyClay | 221 | Alex CalatravaClay | 6-3 6-4 | 3 | 79 | 3 | 8 | 41.7% | 85.0% | 57.1% | 1/3 |
| R32 | 92 |  Richard FrombergClay | 91 | Karel NovacekClay | 6-4 6-4 | 3 | 72 | 10 | 0 | 58.7% | 92.6% | 84.2% | 1/1 |
| R32 | 35 | Alex CorretjaClay | 175 | Juan Albert Viloca-PuigClay | 7-6(4) 6-1 | 3 | 98 | 2 | 1 | 62.3% | 76.3% | 69.6% | 2/3 |
| R32 | 80 | Tomas CarbonellClay | 50 | Jordi ArreseClay | 4-6 6-3 6-3 | 3 | 118 | 3 | 5 | 42.5% | 70.3% | 48.0% | 5/10 |
| R32 | 102 | Alex Lopez MoronClay | 134 | Carsten ArriensClay | 3-0 RET | 3 | 7 | 1 | 0 | 60.0% | 83.3% | 75.0% | 0/0 |
| R32 | 116 | Emilio SanchezClay | 47 | Javier SanchezClay | 6-0 6-7(2) 6-2 | 3 | 108 | 6 | 0 | 70.8% | 68.3% | 42.3% | 5/8 |
| R32 | 21 |  Gilbert SchallerClay | 86 |  Frederik FetterleinClay | 6-4 6-1 | 3 | 85 | 2 | 0 | 56.9% | 69.0% | 54.5% | 3/5 |
| R16 | 23 | Alberto BerasateguiClay | 109 | Marcos OndruskaClay | 6-4 7-6(3) | 3 | 106 | 1 | 1 | 87.5% | 58.6% | 60.0% | 6/9 |
| R16 | 69 | Sjeng SchalkenClay | 41 | Bohdan UlihrachClay | 4-6 6-4 6-2 | 3 | 114 | 5 | 7 | 56.0% | 62.7% | 47.5% | 8/13 |
| R16 | 100 | Magnus GustafssonClay | 25 | Albert CostaClay | 6-2 6-4 | 3 | 73 | 3 | 1 | 55.6% | 70.0% | 62.5% | 4/5 |
| R16 | 136 | Felix MantillaClay | 118 | Kris GoossensClay | 6-2 6-3 | 3 | 87 | 0 | 0 | 64.5% | 62.5% | 77.3% | 3/3 |
| R16 | 83 | Hernan GumyClay | 27 | Francisco ClavetClay | 6-4 6-2 | 3 | 77 | 3 | 5 | 60.4% | 68.8% | 47.6% | 3/6 |
| R16 | 92 | Richard FrombergClay | 35 | Alex CorretjaClay | W/O | 3 | - | 3 | 5 | 60.4% | 68.8% | 47.6% | 3/6 |
| R16 | 80 | Tomas CarbonellClay | 102 | Alex Lopez MoronClay | 2-6 7-6(2) 6-4 | 3 | 127 | 5 | 2 | 58.4% | 71.2% | 40.5% | 2/7 |
| R16 | 21 | Gilbert SchallerClay | 116 | Emilio SanchezClay | 7-6(2) 5-7 7-6(5) | 3 | 192 | 1 | 0 | 83.2% | 63.5% | 61.9% | 6/10 |
| QF | 69 | Sjeng SchalkenClay | 23 | Alberto BerasateguiClay | 3-6 6-4 7-6(3) | 3 | 111 | 6 | 9 | 52.6% | 76.5% | 47.8% | 6/11 |
| QF | 136 | Felix MantillaClay | 100 | Magnus GustafssonClay | 4-6 7-6(6) 6-1 | 3 | 135 | 0 | 2 | 68.2% | 56.0% | 57.1% | 7/12 |
| QF | 83 | Hernan GumyClay | 92 | Richard FrombergClay | 6-1 6-3 | 3 | 81 | 2 | 1 | 62.0% | 71.0% | 63.2% | 1/1 |
| QF | 21 | Gilbert SchallerClay | 80 | Tomas CarbonellClay | 7-5 6-2 | 3 | 80 | 0 | 0 | 77.6% | 64.4% | 69.2% | 1/3 |
| SF | 69 | Sjeng SchalkenClay | 136 | Felix MantillaClay | 6-4 4-6 6-2 | 3 | 111 | 7 | 4 | 61.1% | 67.3% | 51.4% | 2/5 |
| SF | 21 | Gilbert SchallerClay | 83 | Hernan GumyClay | 5-7 6-0 6-4 | 3 | 148 | 0 | 0 | 77.5% | 63.8% | 45.0% | 6/11 |
| F | 69 | Sjeng SchalkenClay | 21 | Gilbert SchallerClay | 6-4 6-2 | 3 | 74 | 2 | 2 | 51.6% | 84.4% | 46.7% | 3/3 |
