| R64 | 24 |  Marcos BaghdatisClay | 123 |  Alejandro FallaClay | 6-3 3-6 7-6(5) | 3 | 155 | 11 | 3 | 49.5% | 77.6% | 52.0% | 3/5 |
| R64 | 19 |  Marin CilicClay | 41 |  Potito StaraceClay | 7-6(5) 6-4 | 3 | 94 | 11 | 1 | 56.2% | 75.6% | 53.1% | 4/6 |
| R64 | 32 |  Juan Martin del PotroClay | 13 |  Mikhail YouzhnyClay | 6-1 3-6 6-3 | 3 | 127 | 8 | 3 | 72.2% | 73.7% | 59.1% | 4/5 |
| R64 | 160 | Flavio CipollaClay | 12 |  Andy RoddickClay | 6-4 6-7(7) 6-3 | 3 | 183 | 3 | 3 | 68.4% | 65.4% | 63.9% | 8/10 |
| R64 | 27 |  Michael LlodraClay | 18 | Sam QuerreyClay | 6-2 6-3 | 3 | 63 | 2 | 6 | 66.1% | 75.7% | 52.6% | 3/4 |
| R64 | 61 |  Daniel Gimeno-TraverClay | 16 | Richard GasquetClay | 3-6 6-4 6-3 | 3 | 135 | 3 | 1 | 64.8% | 70.2% | 41.9% | 8/12 |
| R64 | 39 | Feliciano LopezClay | 25 |  Milos RaonicClay | 4-6 7-6(2) 6-4 | 3 | 124 | 12 | 0 | 64.9% | 81.0% | 55.9% | 1/2 |
| R64 | 49 |  Xavier MalisseClay | 71 |  Victor HanescuClay | 3-6 6-4 7-5 | 3 | 128 | 12 | 0 | 65.0% | 73.1% | 55.6% | 5/6 |
| R64 | 55 |  Yen-Hsun LuClay | 17 | Fernando VerdascoClay | 7-6(7) 7-5 | 3 | 124 | 4 | 4 | 69.8% | 73.3% | 46.2% | 5/6 |
| R64 | 22 | Jo-Wilfried TsongaClay | 9 | Nicolas AlmagroClay | 6-1 6-3 | 3 | 67 | 8 | 3 | 65.2% | 86.7% | 56.3% | 2/2 |
| R64 | 76 | Pere RibaClay | 46 |  Kei NishikoriClay | 6-2 6-4 | 3 | 79 | 7 | 4 | 63.6% | 71.4% | 35.0% | 5/8 |
| R64 | 60 | Santiago GiraldoClay | 21 |  Alexandr DolgopolovClay | 6-1 7-5 | 3 | 67 | 2 | 0 | 69.2% | 73.3% | 50.0% | 5/6 |
| R64 | 50 | Marcel GranollersClay | 28 | Nikolay DavydenkoClay | 7-5 6-2 | 3 | 95 | 1 | 0 | 67.3% | 75.7% | 66.7% | 0/0 |
| R64 | 43 | Juan MonacoClay | 44 |  Andrey GolubevClay | 2-6 6-2 6-2 | 3 | 98 | 0 | 0 | 72.7% | 67.5% | 66.7% | 0/3 |
| R64 | 10 | Gael MonfilsClay | 133 | Ivo KarlovicClay | 6-3 7-6(6) | 3 | 82 | 3 | 3 | 82.0% | 80.0% | 45.5% | 0/0 |
| R64 | 30 |  Florian MayerClay | 15 |  Viktor TroickiClay | 4-6 7-5 6-4 | 3 | 143 | 1 | 5 | 64.4% | 73.1% | 32.4% | 8/12 |
| R64 | 36 |  Thomaz BellucciClay | 48 | Pablo AndujarClay | 6-4 6-2 | 3 | 91 | 4 | 1 | 62.5% | 68.6% | 61.9% | 2/3 |
| R64 | 20 | Gilles SimonClay | 37 | Ivan LjubicicClay | 7-5 7-6(8) | 3 | 116 | 5 | 1 | 56.3% | 80.0% | 74.2% | 0/0 |
| R64 | 59 | Adrian MannarinoClay | 42 | Juan Ignacio ChelaClay | 4-6 6-4 6-4 | 3 | 144 | 13 | 1 | 62.7% | 65.6% | 42.1% | 5/10 |
| R64 | 38 | Sergiy StakhovskyClay | 26 | Albert MontanesClay | 7-6(6) 3-6 7-6(5) | 3 | 144 | 7 | 1 | 61.1% | 72.5% | 54.5% | 2/4 |
| R64 | 33 | John IsnerClay | 11 | Mardy FishClay | 7-6(5) 4-6 7-6(3) | 3 | 174 | 13 | 1 | 70.3% | 71.8% | 69.7% | 3/4 |
| R64 | 29 | Guillermo Garcia-LopezClay | 14 |  Stan WawrinkaClay | 6-4 5-7 6-4 | 3 | 165 | 3 | 2 | 51.4% | 73.7% | 53.7% | 5/7 |
| R64 | 83 |  Thiemo de BakkerClay | 73 | Juan Carlos FerreroClay | 2-6 7-5 6-4 | 3 | 123 | 10 | 3 | 55.3% | 78.7% | 57.9% | 4/6 |
| R64 | 35 |  Kevin AndersonClay | 74 | Olivier RochusClay | 6-2 6-4 | 3 | 73 | 12 | 4 | 63.0% | 82.4% | 45.0% | 3/4 |
| R32 | 1 | Rafael NadalClay | 24 | Marcos BaghdatisClay | 6-1 6-3 | 3 | 82 | 1 | 0 | 56.1% | 82.6% | 77.8% | 0/0 |
| R32 | 32 | Juan Martin del PotroClay | 19 | Marin CilicClay | 6-3 6-0 | 3 | 64 | 2 | 1 | 65.7% | 91.3% | 58.3% | 0/0 |
| R32 | 27 | Michael LlodraClay | 160 | Flavio CipollaClay | 6-4 6-2 | 3 | 77 | 3 | 0 | 65.3% | 75.0% | 64.7% | 0/1 |
| R32 | 61 | Daniel Gimeno-TraverClay | 8 |  Jurgen MelzerClay | 7-6(8) 6-3 | 3 | 95 | 5 | 1 | 66.1% | 61.0% | 47.6% | 3/7 |
| R32 | 3 | Roger FedererClay | 39 | Feliciano LopezClay | 7-6(13) 6-7(1) 7-6(7) | 3 | 176 | 25 | 3 | 68.4% | 80.6% | 65.1% | 4/5 |
| R32 | 49 | Xavier MalisseClay | 55 | Yen-Hsun LuClay | 6-2 6-2 | 3 | 57 | 7 | 1 | 70.0% | 82.1% | 75.0% | 0/0 |
| R32 | 22 | Jo-Wilfried TsongaClay | 76 | Pere RibaClay | 6-4 6-2 | 3 | 200 | 6 | 2 | 73.5% | 77.8% | 53.8% | 2/3 |
| R32 | 5 |  Robin SoderlingClay | 60 | Santiago GiraldoClay | 6-3 6-3 | 3 | 80 | 9 | 2 | 57.7% | 83.3% | 45.5% | 2/3 |
| R32 | 7 |  Tomas BerdychClay | 50 | Marcel GranollersClay | 6-4 6-0 | 3 | 76 | 1 | 0 | 65.9% | 70.4% | 64.3% | 2/4 |
| R32 | 43 | Juan MonacoClay | 10 | Gael MonfilsClay | 6-2 3-0 RET | 3 | 64 | 0 | 0 | 77.4% | 66.7% | 85.7% | 3/3 |
| R32 | 36 | Thomaz BellucciClay | 30 | Florian MayerClay | 6-7(5) 6-3 3-0 RET | 3 | 102 | 11 | 1 | 71.0% | 73.5% | 65.0% | 0/2 |
| R32 | 4 |  Andy MurrayClay | 20 | Gilles SimonClay | 6-4 3-6 6-0 | 3 | 143 | 8 | 3 | 62.1% | 66.1% | 50.0% | 8/10 |
| R32 | 6 | David FerrerClay | 59 | Adrian MannarinoClay | 7-5 0-6 6-0 | 3 | 115 | 4 | 5 | 62.0% | 66.1% | 39.5% | 8/12 |
| R32 | 38 | Sergiy StakhovskyClay | 33 | John IsnerClay | 7-5 4-6 7-6(3) | 3 | 136 | 5 | 1 | 68.0% | 75.7% | 63.6% | 3/4 |
| R32 | 29 | Guillermo Garcia-LopezClay | 83 | Thiemo de BakkerClay | 6-2 6-3 | 3 | 73 | 1 | 1 | 42.0% | 95.2% | 62.1% | 1/1 |
| R32 | 2 | Novak DjokovicClay | 35 | Kevin AndersonClay | 6-3 6-4 | 3 | 101 | 2 | 2 | 70.9% | 82.1% | 56.3% | 2/2 |
| R16 | 1 | Rafael NadalClay | 32 | Juan Martin del PotroClay | W/O | 3 | - | 2 | 2 | 70.9% | 82.1% | 56.3% | 2/2 |
| R16 | 27 | Michael LlodraClay | 61 | Daniel Gimeno-TraverClay | 1-6 6-4 7-6(4) | 3 | 138 | 7 | 2 | 66.7% | 71.3% | 42.5% | 13/16 |
| R16 | 3 | Roger FedererClay | 49 | Xavier MalisseClay | 6-4 6-3 | 3 | 71 | 5 | 0 | 61.5% | 75.0% | 70.0% | 1/2 |
| R16 | 5 | Robin SoderlingClay | 22 | Jo-Wilfried TsongaClay | 7-6(8) 7-5 | 3 | 133 | 5 | 2 | 63.6% | 81.6% | 60.7% | 3/3 |
| R16 | 7 | Tomas BerdychClay | 43 | Juan MonacoClay | 7-5 6-3 | 3 | 109 | 4 | 2 | 54.3% | 81.6% | 46.9% | 4/5 |
| R16 | 36 | Thomaz BellucciClay | 4 | Andy MurrayClay | 6-4 6-2 | 3 | 91 | 4 | 1 | 63.2% | 80.6% | 52.4% | 3/3 |
| R16 | 6 | David FerrerClay | 38 | Sergiy StakhovskyClay | 6-3 7-6(3) | 3 | 89 | 2 | 2 | 69.6% | 87.2% | 76.5% | 3/4 |
| R16 | 2 | Novak DjokovicClay | 29 | Guillermo Garcia-LopezClay | 6-1 6-2 | 3 | 51 | 5 | 1 | 61.8% | 100.0% | 84.6% | 0/0 |
| QF | 1 | Rafael NadalClay | 27 | Michael LlodraClay | 6-2 6-2 | 3 | 75 | 1 | 0 | 73.2% | 83.3% | 72.7% | 0/0 |
| QF | 3 | Roger FedererClay | 5 | Robin SoderlingClay | 7-6(2) 6-4 | 3 | 103 | 8 | 2 | 60.3% | 77.3% | 65.5% | 2/2 |
| QF | 36 | Thomaz BellucciClay | 7 | Tomas BerdychClay | 7-6(2) 6-3 | 3 | 94 | 5 | 1 | 65.0% | 84.6% | 76.2% | 0/0 |
| QF | 2 | Novak DjokovicClay | 6 | David FerrerClay | 6-4 4-6 6-3 | 3 | 148 | 6 | 1 | 65.9% | 76.8% | 41.4% | 3/6 |
| SF | 1 | Rafael NadalClay | 3 | Roger FedererClay | 5-7 6-1 6-3 | 3 | 156 | 1 | 0 | 81.2% | 67.1% | 52.6% | 9/11 |
| SF | 2 | Novak DjokovicClay | 36 | Thomaz BellucciClay | 4-6 6-4 6-1 | 3 | 130 | 6 | 1 | 63.7% | 68.6% | 62.1% | 1/3 |
| F | 2 | Novak DjokovicClay | 1 | Rafael NadalClay | 7-5 6-4 | 3 | 138 | 3 | 1 | 56.9% | 69.7% | 52.0% | 3/6 |
