| R64 | 46 |  Benjamin BeckerClay | 514 |  Carlos MoyaClay | 6-0 6-2 | 3 | 63 | 3 | 0 | 56.5% | 80.8% | 60.0% | 5/5 |
| R64 | 61 |  Leonardo MayerClay | 37 |  Julien BenneteauClay | 6-7(9) 7-5 6-4 | 3 | 162 | 8 | 3 | 65.5% | 75.0% | 57.9% | 5/6 |
| R64 | 23 |  Stan WawrinkaClay | 87 | Marcel GranollersClay | 6-4 6-4 | 3 | 92 | 3 | 2 | 51.4% | 55.6% | 44.1% | 6/10 |
| R64 | 13 |  Mikhail YouzhnyClay | 72 |  Lukas LackoClay | 2-6 6-3 6-1 | 3 | 97 | 2 | 2 | 65.2% | 68.9% | 54.2% | 1/4 |
| R64 | 34 |  Ernests GulbisClay | 33 | Albert MontanesClay | 7-5 6-1 | 3 | 97 | 6 | 1 | 65.5% | 71.1% | 65.0% | 4/5 |
| R64 | 32 | Feliciano LopezClay | 53 |  Lukasz KubotClay | 6-3 6-3 | 3 | 72 | 6 | 3 | 52.8% | 82.1% | 40.0% | 2/4 |
| R64 | 51 | Juan Ignacio ChelaClay | 50 |  Pablo CuevasClay | 2-0 RET | 3 | 5 | 1 | 0 | 100.0% | 100.0% | NaN% | 0/0 |
| R64 | 38 |  Victor HanescuClay | 45 | Igor AndreevClay | 3-6 6-5 RET | 3 | 96 | 4 | 2 | 71.6% | 66.7% | 42.1% | 1/4 |
| R64 | 315 | Daniel Munoz de la NavaClay | 22 |  Sam QuerreyClay | 6-7(3) 6-3 7-5 | 3 | 132 | 5 | 0 | 52.0% | 75.0% | 62.5% | 5/6 |
| R64 | 12 | David FerrerClay | 44 | Jeremy ChardyClay | 6-3 7-6(2) | 3 | 111 | 0 | 2 | 72.3% | 63.8% | 55.6% | 4/7 |
| R64 | 28 |  Marcos BaghdatisClay | 66 | Marco ChiudinelliClay | 6-3 6-4 | 3 | 85 | 12 | 4 | 64.5% | 80.0% | 59.1% | 2/2 |
| R64 | 52 | Eduardo SchwankClay | 56 | Paul-Henri MathieuClay | 6-3 6-3 | 3 | 78 | 6 | 1 | 64.8% | 71.4% | 63.2% | 0/1 |
| R64 | 36 |  Ivo KarlovicClay | 73 |  Evgeny KorolevClay | 6-4 7-6(5) | 3 | 95 | 19 | 0 | 67.1% | 83.0% | 65.2% | 2/2 |
| R64 | 30 |  Jurgen MelzerClay | 97 |  Kevin AndersonClay | 6-2 2-6 6-4 | 3 | 116 | 6 | 0 | 77.1% | 65.6% | 36.8% | 6/9 |
| R64 | 98 | Mardy FishClay | 85 | Michael RussellClay | 6-2 7-6(1) | 3 | 105 | 14 | 2 | 61.3% | 73.5% | 48.4% | 5/7 |
| R64 | 26 |  Thomaz BellucciClay | 93 | Pere RibaClay | 7-6(5) 6-1 | 3 | 88 | 4 | 2 | 56.7% | 71.1% | 58.6% | 2/4 |
| R64 | 27 | Juan MonacoClay | 60 | Simon GreulClay | 6-1 6-1 | 3 | 59 | 4 | 3 | 67.4% | 65.5% | 64.3% | 1/2 |
| R64 | 35 | Nicolas AlmagroClay | 40 |  Viktor TroickiClay | 6-1 7-6(3) | 3 | 99 | 2 | 1 | 63.7% | 66.7% | 48.3% | 7/9 |
| R64 | 39 | Guillermo Garcia-LopezClay | 96 | Daniel Gimeno-TraverClay | 6-3 6-4 | 3 | 71 | 2 | 1 | 63.5% | 84.8% | 57.9% | 1/2 |
| R64 | 42 | Philipp PetzschnerClay | 78 |  Fabio FogniniClay | 6-1 4-6 7-5 | 3 | 121 | 5 | 3 | 53.6% | 67.3% | 46.7% | 8/12 |
| R64 | 18 | Gael MonfilsClay | 64 | Stephane RobertClay | 6-2 7-5 | 3 | 84 | 7 | 3 | 61.3% | 63.2% | 54.2% | 2/4 |
| R64 | 19 | John IsnerClay | 140 |  Christophe RochusClay | 5-7 6-2 6-2 | 3 | 102 | 21 | 2 | 65.8% | 84.6% | 55.6% | 3/4 |
| R64 | 59 |  Santiago GiraldoClay | 29 | Philipp KohlschreiberClay | 1-6 6-2 6-3 | 3 | 99 | 1 | 0 | 69.4% | 76.0% | 45.5% | 2/4 |
| R64 | 62 |  Alexandr DolgopolovClay | 55 | Andreas SeppiClay | 6-3 6-4 | 3 | 66 | 4 | 0 | 55.2% | 81.3% | 61.5% | 3/3 |
| R32 | 1 | Roger FedererClay | 46 | Benjamin BeckerClay | 6-2 7-6(4) | 3 | 82 | 8 | 1 | 68.4% | 82.1% | 66.7% | 0/0 |
| R32 | 23 | Stan WawrinkaClay | 61 | Leonardo MayerClay | 6-4 4-2 RET | 3 | 66 | 3 | 1 | 66.7% | 82.1% | 50.0% | 1/2 |
| R32 | 34 | Ernests GulbisClay | 13 | Mikhail YouzhnyClay | 7-6(2) 6-4 | 3 | 104 | 5 | 0 | 60.3% | 91.4% | 73.9% | 1/1 |
| R32 | 32 | Feliciano LopezClay | 103 | Oscar HernandezClay | 6-1 6-2 | 3 | 64 | 4 | 3 | 52.4% | 95.5% | 50.0% | 1/1 |
| R32 | 4 |  Andy MurrayClay | 51 | Juan Ignacio ChelaClay | 6-3 6-3 | 3 | 73 | 5 | 1 | 44.2% | 89.5% | 58.3% | 0/2 |
| R32 | 38 | Victor HanescuClay | 315 | Daniel Munoz de la NavaClay | 6-0 4-6 6-3 | 3 | 102 | 7 | 1 | 77.6% | 74.6% | 52.9% | 4/6 |
| R32 | 12 | David FerrerClay | 28 | Marcos BaghdatisClay | 1-6 6-3 7-5 | 3 | 158 | 2 | 1 | 67.7% | 61.2% | 53.1% | 13/17 |
| R32 | 11 | Marin CilicClay | 52 | Eduardo SchwankClay | 6-3 6-0 | 3 | 66 | 5 | 0 | 49.1% | 80.8% | 51.9% | 3/4 |
| R32 | 9 | Fernando VerdascoClay | 36 | Ivo KarlovicClay | 7-6(5) 6-3 | 3 | 99 | 7 | 2 | 83.6% | 82.1% | 54.5% | 2/2 |
| R32 | 30 | Jurgen MelzerClay | 98 | Mardy FishClay | 3-6 6-1 6-4 | 3 | 99 | 4 | 2 | 55.6% | 75.0% | 59.4% | 0/1 |
| R32 | 27 | Juan MonacoClay | 26 | Thomaz BellucciClay | 6-2 6-2 | 3 | 71 | 0 | 0 | 74.0% | 64.9% | 76.9% | 3/4 |
| R32 | 35 | Nicolas AlmagroClay | 7 |  Robin SoderlingClay | 6-4 7-5 | 3 | 102 | 8 | 0 | 56.3% | 67.5% | 58.1% | 4/6 |
| R32 | 39 | Guillermo Garcia-LopezClay | 10 | Jo-Wilfried TsongaClay | 6-2 RET | 3 | 40 | 1 | 0 | 66.7% | 56.3% | 75.0% | 5/6 |
| R32 | 18 | Gael MonfilsClay | 42 | Philipp PetzschnerClay | 1-1 RET | 3 | 11 | 0 | 2 | 50.0% | 50.0% | 25.0% | 0/1 |
| R32 | 19 | John IsnerClay | 59 | Santiago GiraldoClay | 1-6 7-6(6) 6-2 | 3 | 115 | 22 | 3 | 70.0% | 62.3% | 48.5% | 11/14 |
| R32 | 3 | Rafael NadalClay | 62 | Alexandr DolgopolovClay | 6-4 6-3 | 3 | 87 | 0 | 2 | 76.5% | 71.2% | 56.3% | 1/1 |
| R16 | 1 | Roger FedererClay | 23 | Stan WawrinkaClay | 6-3 6-1 | 3 | 69 | 6 | 1 | 63.4% | 84.6% | 53.3% | 0/1 |
| R16 | 34 | Ernests GulbisClay | 32 | Feliciano LopezClay | 6-2 7-6(0) | 3 | 94 | 9 | 2 | 72.9% | 81.4% | 62.5% | 3/3 |
| R16 | 4 | Andy MurrayClay | 38 | Victor HanescuClay | 6-2 6-1 | 3 | 70 | 4 | 0 | 57.8% | 84.6% | 63.2% | 2/2 |
| R16 | 12 | David FerrerClay | 11 | Marin CilicClay | 6-3 6-2 | 3 | 71 | 3 | 0 | 72.3% | 88.2% | 53.8% | 3/3 |
| R16 | 30 | Jurgen MelzerClay | 9 | Fernando VerdascoClay | 7-5 6-3 | 3 | 116 | 4 | 4 | 59.5% | 70.2% | 40.6% | 9/12 |
| R16 | 35 | Nicolas AlmagroClay | 27 | Juan MonacoClay | 6-4 6-1 | 3 | 68 | 7 | 0 | 60.4% | 82.8% | 57.9% | 1/1 |
| R16 | 18 | Gael MonfilsClay | 39 | Guillermo Garcia-LopezClay | 7-6(5) 6-4 | 3 | 130 | 3 | 1 | 69.8% | 73.3% | 57.7% | 6/6 |
| R16 | 3 | Rafael NadalClay | 19 | John IsnerClay | 7-5 6-4 | 3 | 87 | 1 | 0 | 65.4% | 85.3% | 83.3% | 0/0 |
| QF | 1 | Roger FedererClay | 34 | Ernests GulbisClay | 3-6 6-1 6-4 | 3 | 113 | 6 | 2 | 70.0% | 69.6% | 54.2% | 4/6 |
| QF | 12 | David FerrerClay | 4 | Andy MurrayClay | 7-5 6-3 | 3 | 131 | 0 | 1 | 86.3% | 65.2% | 45.5% | 6/8 |
| QF | 35 | Nicolas AlmagroClay | 30 | Jurgen MelzerClay | 6-3 6-1 | 3 | 58 | 6 | 2 | 64.3% | 85.2% | 66.7% | 0/0 |
| QF | 3 | Rafael NadalClay | 18 | Gael MonfilsClay | 6-1 6-3 | 3 | 78 | 1 | 1 | 73.2% | 90.0% | 54.5% | 2/2 |
| SF | 1 | Roger FedererClay | 12 | David FerrerClay | 7-5 3-6 6-3 | 3 | 126 | 8 | 2 | 60.5% | 85.7% | 59.4% | 3/4 |
| SF | 3 | Rafael NadalClay | 35 | Nicolas AlmagroClay | 4-6 6-2 6-2 | 3 | 136 | 1 | 1 | 64.3% | 77.8% | 36.0% | 3/6 |
| F | 3 | Rafael NadalClay | 1 | Roger FedererClay | 6-4 7-6(5) | 3 | 131 | 2 | 2 | 72.8% | 54.2% | 63.6% | 8/11 |
