| R64 | 51 | Florent SerraClay | 31 | Rainer SchuettlerClay | 6-2 6-4 | 3 | 64 | 2 | 2 | 71.9% | 78.0% | 50.0% | 3/3 |
| R64 | 11 | Nikolay DavydenkoClay | 41 | Viktor TroickiClay | 6-2 6-2 | 3 | 79 | 2 | 2 | 78.7% | 66.7% | 46.2% | 4/5 |
| R64 | 16 | James BlakeClay | 33 | Victor HanescuClay | 6-2 6-4 | 3 | 68 | 3 | 1 | 54.7% | 79.3% | 50.0% | 1/2 |
| R64 | 25 | Ivo KarlovicClay | 45 | Julien BenneteauClay | 3-6 7-6(5) 6-4 | 3 | 132 | 21 | 1 | 62.5% | 78.3% | 55.6% | 3/4 |
| R64 | 23 | Robin SoderlingClay | 84 | Ivan NavarroClay | 6-4 6-2 | 3 | 71 | 6 | 2 | 52.7% | 75.9% | 57.7% | 2/3 |
| R32 | 1 | Rafael NadalClay | 27 | Jurgen MelzerClay | 6-3 6-1 | 3 | 62 | 1 | 0 | 58.5% | 87.5% | 64.7% | 0/0 |
| R32 | 35 | Philipp KohlschreiberClay | 14 | Marin CilicClay | 6-1 6-7(5) 7-6(2) | 3 | 175 | 4 | 2 | 69.7% | 67.1% | 59.5% | 7/8 |
| R32 | 47 | Juan MonacoClay | 13 | David FerrerClay | 6-4 6-4 | 3 | 90 | 1 | 2 | 80.0% | 68.2% | 63.6% | 3/5 |
| R32 | 8 | Fernando VerdascoClay | 115 | Juan Carlos FerreroClay | 6-3 6-2 | 3 | 96 | 4 | 1 | 77.6% | 61.5% | 46.7% | 5/7 |
| R32 | 4 | Novak DjokovicClay | 65 | Oscar HernandezClay | 6-3 6-3 | 3 | 99 | 3 | 3 | 67.9% | 81.6% | 44.4% | 0/0 |
| R32 | 36 | Andreas SeppiClay | 60 | Sam QuerreyClay | 6-3 4-6 6-4 | 3 | 117 | 6 | 1 | 61.2% | 70.0% | 52.6% | 8/10 |
| R32 | 54 | Ivan LjubicicClay | 9 | Jo-Wilfried TsongaClay | 6-4 7-5 | 3 | 100 | 6 | 3 | 55.8% | 86.0% | 47.1% | 5/6 |
| R32 | 7 | Gilles SimonClay | 72 | Fabio FogniniClay | 6-3 6-2 | 3 | 71 | 2 | 0 | 62.7% | 67.6% | 59.1% | 2/4 |
| R32 | 5 | Juan Martin del PotroClay | 22 | Tomas BerdychClay | 6-2 4-1 RET | 3 | 69 | 3 | 0 | 70.0% | 76.2% | 88.9% | 0/0 |
| R32 | 18 | Stan WawrinkaClay | 40 | Jeremy ChardyClay | 6-4 7-5 | 3 | 98 | 12 | 0 | 61.9% | 74.4% | 70.8% | 2/3 |
| R32 | 17 | Tommy RobredoClay | 26 | Mardy FishClay | 3-6 7-6(5) 6-2 | 3 | 134 | 2 | 0 | 72.8% | 71.6% | 56.0% | 2/4 |
| R32 | 3 | Andy MurrayClay | 61 | Simone BolelliClay | 7-6(9) 6-4 | 3 | 128 | 4 | 2 | 49.4% | 76.3% | 64.1% | 4/4 |
| R32 | 6 | Andy RoddickClay | 75 | Tommy HaasClay | 1-6 7-6(9) 6-4 | 3 | 143 | 9 | 2 | 72.2% | 72.9% | 55.6% | 0/2 |
| R32 | 11 | Nikolay DavydenkoClay | 51 | Florent SerraClay | 7-5 6-3 | 3 | 87 | 7 | 2 | 72.7% | 66.7% | 50.0% | 4/6 |
| R32 | 16 | James BlakeClay | 25 | Ivo KarlovicClay | 6-7(4) 6-4 7-6(4) | 3 | 124 | 4 | 4 | 64.8% | 82.9% | 65.8% | 1/1 |
| R32 | 2 | Roger FedererClay | 23 | Robin SoderlingClay | 6-1 7-5 | 3 | 70 | 11 | 1 | 50.0% | 85.2% | 63.0% | 0/1 |
| R16 | 1 | Rafael NadalClay | 35 | Philipp KohlschreiberClay | W/O | 3 | - | 11 | 1 | 50.0% | 85.2% | 63.0% | 0/1 |
| R16 | 8 | Fernando VerdascoClay | 47 | Juan MonacoClay | 7-5 6-2 | 3 | 108 | 2 | 1 | 71.8% | 60.8% | 55.0% | 2/4 |
| R16 | 4 | Novak DjokovicClay | 36 | Andreas SeppiClay | 6-4 6-4 | 3 | 98 | 3 | 2 | 64.9% | 78.4% | 55.0% | 1/2 |
| R16 | 54 | Ivan LjubicicClay | 7 | Gilles SimonClay | 3-6 6-4 6-3 | 3 | 130 | 5 | 3 | 57.4% | 67.2% | 53.5% | 10/12 |
| R16 | 5 | Juan Martin del PotroClay | 18 | Stan WawrinkaClay | 4-6 6-4 6-4 | 3 | 176 | 5 | 3 | 50.0% | 72.7% | 47.3% | 9/13 |
| R16 | 3 | Andy MurrayClay | 17 | Tommy RobredoClay | 7-5 6-1 | 3 | 104 | 0 | 2 | 65.0% | 74.4% | 61.9% | 2/2 |
| R16 | 6 | Andy RoddickClay | 11 | Nikolay DavydenkoClay | W/O | 3 | - | 0 | 2 | 65.0% | 74.4% | 61.9% | 2/2 |
| R16 | 2 | Roger FedererClay | 16 | James BlakeClay | 6-2 6-4 | 3 | 62 | 5 | 0 | 57.4% | 87.1% | 56.5% | 1/1 |
| QF | 1 | Rafael NadalClay | 8 | Fernando VerdascoClay | 6-4 7-5 | 3 | 119 | 1 | 1 | 77.6% | 62.7% | 58.8% | 3/5 |
| QF | 4 | Novak DjokovicClay | 54 | Ivan LjubicicClay | 6-4 6-4 | 3 | 105 | 5 | 1 | 63.9% | 76.9% | 63.6% | 2/2 |
| QF | 5 | Juan Martin del PotroClay | 3 | Andy MurrayClay | 7-6(4) 6-3 | 3 | 112 | 5 | 2 | 55.3% | 71.4% | 67.6% | 4/5 |
| QF | 2 | Roger FedererClay | 6 | Andy RoddickClay | 7-5 6-7(5) 6-1 | 3 | 131 | 15 | 2 | 57.7% | 87.5% | 48.8% | 2/3 |
| SF | 1 | Rafael NadalClay | 4 | Novak DjokovicClay | 3-6 7-6(5) 7-6(9) | 3 | 243 | 4 | 4 | 75.9% | 71.3% | 50.0% | 6/8 |
| SF | 2 | Roger FedererClay | 5 | Juan Martin del PotroClay | 6-3 6-4 | 3 | 81 | 8 | 1 | 65.0% | 82.1% | 52.4% | 4/4 |
| F | 2 | Roger FedererClay | 1 | Rafael NadalClay | 6-4 6-4 | 3 | 86 | 6 | 3 | 62.7% | 69.0% | 68.0% | 4/4 |
| R64 | 27 | Jurgen MelzerClay | 28 | Albert MontanesClay | 4-6 7-5 6-3 | 3 | 120 | 10 | 4 | 56.1% | 82.6% | 55.6% | 1/3 |
| R64 | 35 | Philipp KohlschreiberClay | 34 | Nicolas AlmagroClay | 6-3 6-4 | 3 | 92 | 2 | 1 | 69.8% | 75.0% | 63.2% | 3/3 |
| R64 | 14 | Marin CilicClay | 90 | Marcel GranollersClay | 6-2 6-7(4) 6-1 | 3 | 149 | 3 | 3 | 52.8% | 66.7% | 60.8% | 8/9 |
| R64 | 13 | David FerrerClay | 108 | Guillermo CanasClay | 6-2 6-2 | 3 | 84 | 0 | 1 | 56.1% | 78.3% | 72.2% | 1/2 |
| R64 | 47 | Juan MonacoClay | 32 | Feliciano LopezClay | 6-4 7-5 | 3 | 130 | 0 | 1 | 70.3% | 67.3% | 68.2% | 6/6 |
| R64 | 115 | Juan Carlos FerreroClay | 39 | Igor KunitsynClay | 6-3 4-6 6-4 | 3 | 131 | 1 | 3 | 64.3% | 58.7% | 60.0% | 4/8 |
| R64 | 65 | Oscar HernandezClay | 49 | Martin Vassallo ArguelloClay | 6-3 6-3 | 3 | 91 | 2 | 1 | 74.5% | 78.9% | 61.5% | 1/1 |
| R64 | 36 | Andreas SeppiClay | 68 | Eduardo SchwankClay | 7-5 6-4 | 3 | 107 | 2 | 0 | 67.5% | 61.1% | 61.5% | 9/11 |
| R64 | 60 | Sam QuerreyClay | 19 | Radek StepanekClay | 7-6(2) 5-2 RET | 3 | 78 | 10 | 0 | 58.9% | 87.9% | 56.5% | 1/1 |
| R64 | 9 | Jo-Wilfried TsongaClay | 20 | Marat SafinClay | 6-4 7-5 | 3 | 90 | 2 | 2 | 60.0% | 83.3% | 62.5% | 1/1 |
| R64 | 54 | Ivan LjubicicClay | 78 | Teymuraz GabashviliClay | 6-3 6-2 | 3 | 68 | 5 | 0 | 52.3% | 95.7% | 57.1% | 0/1 |
| R64 | 72 | Fabio FogniniClay | 37 | Paul-Henri MathieuClay | 6-7(5) 6-4 3-0 RET | 3 | 119 | 7 | 2 | 64.6% | 62.3% | 62.1% | 4/7 |
| R64 | 22 | Tomas BerdychClay | 77 | Guillermo Garcia-LopezClay | 6-0 7-6(5) | 3 | 109 | 4 | 3 | 56.2% | 68.3% | 53.1% | 8/10 |
| R64 | 40 | Jeremy ChardyClay | 44 | Jose AcasusoClay | 6-3 6-2 | 3 | 65 | 6 | 2 | 51.8% | 75.9% | 63.0% | 0/0 |
| R64 | 18 | Stan WawrinkaClay | 188 | Marco CrugnolaClay | 6-2 6-0 | 3 | 59 | 2 | 2 | 65.8% | 72.0% | 69.2% | 4/5 |
| R64 | 17 | Tommy RobredoClay | 29 | Nicolas KieferClay | 3-6 6-2 6-2 | 3 | 119 | 5 | 2 | 63.6% | 67.3% | 60.7% | 5/7 |
| R64 | 26 | Mardy FishClay | 62 | Janko TipsarevicClay | 7-6(3) 6-4 | 3 | 125 | 10 | 1 | 58.2% | 74.4% | 67.9% | 1/2 |
| R64 | 61 | Simone BolelliClay | 197 | Juan Ignacio ChelaClay | 7-5 7-6(3) | 3 | 117 | 4 | 1 | 56.6% | 76.7% | 69.7% | 3/3 |
| R64 | 75 | Tommy HaasClay | 42 | Ernests GulbisClay | 6-2 5-7 7-5 | 3 | 138 | 7 | 6 | 56.5% | 71.2% | 47.5% | 1/5 |