| R32 | 316 |  Miljan ZekicClay | 66 |  Andrey KuznetsovClay | 7-6(4) 7-6(6) | 3 | 109 | 8 | 1 | 70.7% | 76.9% | 59.3% | 5/6 |
| R32 | 80 |  Thomaz BellucciClay | 70 |  Alexandr DolgopolovClay | 6-2 5-7 6-4 | 3 | 116 | 9 | 2 | 58.3% | 77.6% | 57.1% | 5/7 |
| R32 | 53 |  Jan-Lennard StruffClay | 248 | Tommy HaasClay | 6-3 7-6(4) | 3 | 92 | 12 | 4 | 46.7% | 77.1% | 70.0% | 3/3 |
| R32 | 71 | Dusan LajovicClay | 120 | Maximilian MartererClay | 7-5 7-6(4) | 3 | 117 | 0 | 2 | 72.0% | 63.9% | 60.7% | 7/8 |
| R32 | 47 | Philipp KohlschreiberClay | 108 |  Facundo BagnisClay | 7-5 3-6 6-3 | 3 | 131 | 10 | 7 | 52.1% | 81.6% | 51.1% | 4/6 |
| R32 | 48 |  Jiri VeselyClay | 125 | Yannick HanfmannClay | 6-4 6-4 | 3 | 83 | 3 | 5 | 49.2% | 79.3% | 60.0% | 2/3 |
| R32 | 122 |  Santiago GiraldoClay | 52 |  Robin HaaseClay | 7-6(6) 4-6 6-4 | 3 | 133 | 7 | 2 | 62.0% | 77.4% | 55.3% | 3/6 |
| R32 | 150 |  Gerald MelzerClay | 97 | Carlos BerlocqClay | 6-4 5-7 6-3 | 3 | 136 | 4 | 1 | 59.3% | 70.4% | 51.4% | 5/8 |
| R32 | 62 |  Joao SousaClay | 99 | Mikhail YouzhnyClay | 6-7(4) 7-5 6-3 | 3 | 133 | 9 | 3 | 47.7% | 84.3% | 55.4% | 6/7 |
| R32 | 57 | Horacio ZeballosClay | 64 | Rogerio Dutra SilvaClay | 2-6 7-6(11) 7-6(4) | 3 | 173 | 10 | 2 | 64.2% | 70.0% | 69.2% | 3/6 |
| R32 | 118 | Renzo OlivoClay | 110 | Thiago MonteiroClay | 7-5 6-2 | 3 | 74 | 5 | 2 | 57.1% | 92.9% | 57.1% | 0/1 |
| R32 | 157 | Sebastian OfnerClay | 63 |  Nikoloz BasilashviliClay | 7-5 3-0 RET | 3 | 60 | 4 | 2 | 64.6% | 67.7% | 52.9% | 3/5 |
| R16 | 25 |  Fabio FogniniClay | 316 | Miljan ZekicClay | 6-4 6-4 | 3 | 80 | 2 | 5 | 70.5% | 72.1% | 55.6% | 3/4 |
| R16 | 80 | Thomaz BellucciClay | 53 | Jan-Lennard StruffClay | 6-4 7-6(3) | 3 | 99 | 4 | 6 | 52.7% | 87.2% | 57.1% | 2/2 |
| R16 | 71 | Dusan LajovicClay | 37 |  Gilles SimonClay | 6-4 6-4 | 3 | 93 | 5 | 1 | 72.7% | 72.9% | 50.0% | 4/5 |
| R16 | 47 | Philipp KohlschreiberClay | 48 | Jiri VeselyClay | 6-3 6-3 | 3 | 66 | 7 | 0 | 62.7% | 90.6% | 52.6% | 3/3 |
| R16 | 150 | Gerald MelzerClay | 122 | Santiago GiraldoClay | 6-3 7-6(1) | 3 | 80 | 2 | 2 | 57.6% | 79.4% | 60.0% | 4/6 |
| R16 | 62 | Joao SousaClay | 36 | Paolo LorenziClay | 6-7(5) 6-4 6-1 | 3 | 144 | 9 | 3 | 42.3% | 82.9% | 58.9% | 5/6 |
| R16 | 118 | Renzo OlivoClay | 57 | Horacio ZeballosClay | 7-6(4) 6-2 | 3 | 84 | 5 | 3 | 58.3% | 88.6% | 56.0% | 3/4 |
| R16 | 157 | Sebastian OfnerClay | 27 |  Pablo CuevasClay | 6-3 2-6 7-6(3) | 3 | 120 | 8 | 2 | 45.3% | 82.1% | 61.7% | 1/3 |
| QF | 25 | Fabio FogniniClay | 80 | Thomaz BellucciClay | 6-3 6-1 | 3 | 65 | 3 | 3 | 61.0% | 68.0% | 37.5% | 1/4 |
| QF | 47 | Philipp KohlschreiberClay | 71 | Dusan LajovicClay | 4-6 6-4 7-6(5) | 3 | 152 | 3 | 2 | 60.7% | 63.2% | 65.9% | 6/9 |
| QF | 62 | Joao SousaClay | 150 | Gerald MelzerClay | 2-6 6-1 6-3 | 3 | 113 | 11 | 1 | 49.4% | 77.3% | 40.0% | 9/12 |
| QF | 157 | Sebastian OfnerClay | 118 | Renzo OlivoClay | 6-3 1-6 6-3 | 3 | 107 | 5 | 6 | 58.3% | 66.1% | 47.5% | 7/10 |
| SF | 47 | Philipp KohlschreiberClay | 25 | Fabio FogniniClay | 7-5 6-3 | 3 | 89 | 4 | 1 | 53.6% | 80.0% | 57.7% | 0/1 |
| SF | 62 | Joao SousaClay | 157 | Sebastian OfnerClay | 7-6(4) 7-6(4) | 3 | 118 | 3 | 3 | 46.3% | 84.2% | 54.5% | 6/7 |
| F | 47 | Philipp KohlschreiberClay | 62 | Joao SousaClay | 6-3 6-4 | 3 | 82 | 4 | 0 | 70.8% | 63.0% | 57.9% | 5/7 |
