| R16 | 81 |  Daniel KoellererClay | 79 |  Diego JunqueiraClay | 6-1 6-2 | 3 | 63 | 2 | 0 | 62.5% | 92.0% | 66.7% | 1/1 |
| R32 | 79 | Diego JunqueiraClay | 76 |  Paul CapdevilleClay | 6-3 6-2 | 3 | 51 | 7 | 3 | 52.8% | 85.7% | 48.0% | 1/2 |
| R32 | 81 | Daniel KoellererClay | 120 |  Thomaz BellucciClay | 6-4 6-4 | 3 | 107 | 1 | 1 | 74.0% | 63.0% | 47.4% | 2/4 |
| R32 | 122 | Nicolas MassuClay | 378 |  Robin VikClay | 6-4 6-2 | 3 | 108 | 2 | 3 | 57.1% | 66.7% | 50.0% | 8/9 |
| R32 | 45 |  Julien BenneteauClay | 55 |  Dudi SelaClay | 7-5 6-1 | 3 | 81 | 5 | 2 | 61.0% | 77.8% | 56.5% | 3/4 |
| R32 | 64 |  Oscar HernandezClay | 42 | Fabrice SantoroClay | 6-2 6-3 | 3 | 59 | 1 | 1 | 79.5% | 83.9% | 75.0% | 0/0 |
| R32 | 61 |  Andreas BeckClay | 73 | Jan HernychClay | 5-7 6-3 7-5 | 3 | 137 | 3 | 5 | 47.8% | 72.7% | 58.3% | 3/5 |
| R32 | 131 | Ruben Ramirez HidalgoClay | 38 |  Mario AncicClay | 6-4 6-3 | 3 | 89 | 2 | 3 | 58.8% | 86.7% | 61.9% | 4/4 |
| R32 | 205 | Juan Ignacio ChelaClay | 44 | Marc GicquelClay | 5-7 6-3 6-0 | 3 | 133 | 4 | 2 | 63.7% | 63.8% | 48.5% | 6/11 |
| R32 | 51 | Martin Vassallo ArguelloClay | 65 |  Christophe RochusClay | 6-2 6-4 | 3 | 80 | 5 | 1 | 61.8% | 67.6% | 61.9% | 2/3 |
| R32 | 74 | Guillermo Garcia-LopezClay | 71 | Bjorn PhauClay | 6-3 6-2 | 3 | 80 | 2 | 1 | 74.4% | 82.8% | 60.0% | 2/3 |
| R32 | 95 | Marcel GranollersClay | 70 |  Teymuraz GabashviliClay | 7-6(11) 6-3 | 3 | 134 | 3 | 4 | 51.7% | 73.3% | 50.0% | 7/9 |
| R32 | 32 |  Victor HanescuClay | 108 |  Nicolas LapenttiClay | 6-7(6) 6-3 7-5 | 3 | 166 | 5 | 2 | 70.0% | 77.8% | 70.4% | 2/3 |
| R32 | 46 |  Mikhail YouzhnyClay | 98 | Daniel Gimeno-TraverClay | 6-2 7-6(7) | 3 | 94 | 5 | 1 | 71.4% | 72.0% | 75.0% | 5/5 |
| R32 | 213 | Stefan KoubekClay | 68 | Philipp PetzschnerClay | 7-6(8) 6-4 | 3 | 92 | 3 | 5 | 44.1% | 76.7% | 65.8% | 0/1 |
| R32 | 89 | Agustin CalleriClay | 66 |  Yen-Hsun LuClay | 3-6 7-5 0-1 RET | 3 | 98 | 5 | 7 | 53.2% | 69.0% | 51.4% | 7/10 |
| R32 | 26 | Jurgen MelzerClay | 67 |  Fred GilClay | 6-3 6-0 | 3 | 54 | 5 | 2 | 54.1% | 80.0% | 76.5% | 1/2 |
| R16 | 45 | Julien BenneteauClay | 122 | Nicolas MassuClay | 6-1 6-7(4) 7-6(7) | 3 | 187 | 13 | 8 | 67.8% | 68.8% | 42.1% | 5/9 |
| R16 | 64 | Oscar HernandezClay | 61 | Andreas BeckClay | 7-5 6-4 | 3 | 128 | 6 | 5 | 61.0% | 74.5% | 53.3% | 7/8 |
| R16 | 205 | Juan Ignacio ChelaClay | 131 | Ruben Ramirez HidalgoClay | 6-3 6-2 | 3 | 102 | 2 | 4 | 63.8% | 96.7% | 41.2% | 0/0 |
| R16 | 74 | Guillermo Garcia-LopezClay | 51 | Martin Vassallo ArguelloClay | 4-6 6-4 6-3 | 3 | 186 | 0 | 2 | 55.6% | 78.0% | 62.5% | 5/6 |
| R16 | 32 | Victor HanescuClay | 95 | Marcel GranollersClay | 6-1 7-6(2) | 3 | 84 | 5 | 0 | 64.5% | 70.0% | 81.8% | 2/2 |
| R16 | 46 | Mikhail YouzhnyClay | 213 | Stefan KoubekClay | 6-2 6-4 | 3 | 89 | 4 | 2 | 46.9% | 78.3% | 61.5% | 4/5 |
| R16 | 26 | Jurgen MelzerClay | 89 | Agustin CalleriClay | 6-4 7-5 | 3 | 87 | 5 | 5 | 60.0% | 79.5% | 50.0% | 3/4 |
| QF | 45 | Julien BenneteauClay | 81 | Daniel KoellererClay | 6-2 6-7(5) 6-0 | 3 | 151 | 9 | 4 | 68.1% | 79.0% | 41.4% | 4/4 |
| QF | 64 | Oscar HernandezClay | 205 | Juan Ignacio ChelaClay | 6-4 6-4 | 3 | 95 | 2 | 0 | 77.2% | 72.7% | 69.2% | 1/1 |
| QF | 74 | Guillermo Garcia-LopezClay | 32 | Victor HanescuClay | 6-2 6-2 | 3 | 81 | 0 | 3 | 58.2% | 75.0% | 52.2% | 5/6 |
| QF | 46 | Mikhail YouzhnyClay | 26 | Jurgen MelzerClay | 6-4 6-4 | 3 | 88 | 5 | 2 | 60.3% | 81.6% | 44.0% | 0/1 |
| SF | 45 | Julien BenneteauClay | 64 | Oscar HernandezClay | 6-3 6-4 | 3 | 89 | 4 | 6 | 60.6% | 75.0% | 53.8% | 4/5 |
| SF | 74 | Guillermo Garcia-LopezClay | 46 | Mikhail YouzhnyClay | 6-3 1-6 7-6(5) | 3 | 143 | 1 | 7 | 68.4% | 70.8% | 56.7% | 2/4 |
| F | 74 | Guillermo Garcia-LopezClay | 45 | Julien BenneteauClay | 3-6 7-6(1) 6-3 | 3 | 190 | 0 | 8 | 70.9% | 63.0% | 43.3% | 4/8 |
