| R64 | 103 | Juan-Pablo GuzmanClay | 97 | Peter LuczakClay | 6-3 6-4 | 3 | 71 | 6 | 1 | 71.7% | 76.3% | 86.7% | 3/3 |
| R64 | 113 | Olivier PatienceClay | 192 | Jan HajekClay | 6-3 6-2 | 3 | 71 | 5 | 3 | 38.6% | 90.9% | 60.0% | 0/0 |
| R64 | 123 | Paul CapdevilleClay | 179 | Hugo ArmandoClay | 6-0 6-3 | 3 | 60 | 4 | 3 | 65.0% | 76.9% | 50.0% | 0/1 |
| R64 | 82 | Mariano ZabaletaClay | 111 | Federico LuzziClay | 7-6(5) 6-2 | 3 | 83 | 8 | 2 | 61.1% | 72.7% | 50.0% | 1/3 |
| R64 | 169 | Daniel KoellererClay | 66 | Stefan KoubekClay | 6-4 6-0 | 3 | 60 | 2 | 3 | 51.1% | 78.3% | 63.6% | 0/1 |
| R64 | 78 | Sergio RoitmanClay | 81 | Guillermo Garcia-LopezClay | 2-6 6-1 6-1 | 3 | 76 | 0 | 1 | 73.8% | 66.7% | 43.8% | 2/5 |
| R64 | 91 | Luis HornaClay | 255 | Jeremy ChardyClay | 7-5 6-3 | 3 | 74 | 3 | 0 | 60.0% | 91.7% | 50.0% | 2/3 |
| R64 | 94 | Ivan NavarroClay | 145 | Konstantinos EconomidisClay | 6-4 6-2 | 3 | 74 | 4 | 1 | 68.1% | 75.0% | 80.0% | 3/4 |
| R64 | 85 | Martin Vassallo ArguelloClay | 838 | Jonathan EyssericClay | 6-2 6-3 | 3 | 91 | 2 | 1 | 66.7% | 71.9% | 75.0% | 0/0 |
| R64 | 173 | Christophe RochusClay | 92 | Chris GuccioneClay | 7-6(6) 7-6(10) | 3 | 125 | 5 | 1 | 68.0% | 72.1% | 62.5% | 9/10 |
| R64 | 155 | Fabio FogniniClay | 110 | Juan Pablo BrzezickiClay | 6-4 6-3 | 3 | 77 | 1 | 2 | 43.5% | 85.2% | 45.7% | 5/7 |
| R64 | 86 | Andreas SeppiClay | 63 | Feliciano LopezClay | 5-7 6-0 7-6(3) | 3 | 118 | 8 | 6 | 64.0% | 71.9% | 56.3% | 2/5 |
| R64 | 406 | Rainer EitzingerClay | 89 | Max MirnyiClay | 6-4 3-6 7-6(3) | 3 | 123 | 0 | 4 | 75.9% | 65.9% | 57.7% | 5/7 |
| R64 | 88 | Diego HartfieldClay | 283 | Martin FischerClay | 5-7 6-4 6-2 | 3 | 137 | 7 | 4 | 65.3% | 71.2% | 48.6% | 7/10 |
| R64 | 240 | Laurent RecoudercClay | 87 | Ernests GulbisClay | 5-7 6-3 6-4 | 3 | 103 | 3 | 0 | 64.6% | 69.8% | 72.4% | 4/7 |
| R64 | 137 | Alexander PeyaClay | 124 | Oliver MarachClay | 6-3 7-6(5) | 3 | 99 | 12 | 1 | 58.5% | 86.8% | 55.6% | 2/3 |
| R32 | 7 | Tommy RobredoClay | 103 | Juan-Pablo GuzmanClay | 6-1 6-4 | 3 | 72 | 4 | 2 | 72.3% | 72.3% | 61.1% | 10/10 |
| R32 | 49 | Igor AndreevClay | 113 | Olivier PatienceClay | 7-6(5) 6-2 | 3 | 91 | 5 | 0 | 75.0% | 64.4% | 66.7% | 3/5 |
| R32 | 36 | Philipp KohlschreiberClay | 123 | Paul CapdevilleClay | 6-4 6-1 | 3 | 74 | 0 | 0 | 64.7% | 60.6% | 77.8% | 6/7 |
| R32 | 32 | Juan MonacoClay | 82 | Mariano ZabaletaClay | 6-1 2-6 6-3 | 3 | 100 | 3 | 1 | 57.5% | 60.9% | 55.9% | 7/11 |
| R32 | 18 | Juan Ignacio ChelaClay | 169 | Daniel KoellererClay | 3-6 6-3 6-2 | 3 | 168 | 4 | 6 | 47.2% | 72.5% | 42.1% | 14/18 |
| R32 | 78 | Sergio RoitmanClay | 65 | Nicolas MassuClay | 7-5 6-2 | 3 | 106 | 2 | 1 | 54.4% | 59.5% | 58.1% | 2/4 |
| R32 | 41 | Fernando VerdascoClay | 91 | Luis HornaClay | 6-1 6-4 | 3 | 72 | 0 | 2 | 81.8% | 80.6% | 25.0% | 0/1 |
| R32 | 34 | Nicolas AlmagroClay | 94 | Ivan NavarroClay | 7-5 6-3 | 3 | 89 | 11 | 3 | 50.7% | 81.1% | 58.3% | 6/6 |
| R32 | 37 | Florian MayerClay | 85 | Martin Vassallo ArguelloClay | 6-1 6-3 | 3 | 59 | 5 | 0 | 68.3% | 82.1% | 69.2% | 0/0 |
| R32 | 46 | Potito StaraceClay | 173 | Christophe RochusClay | 6-2 6-2 | 3 | 68 | 4 | 2 | 69.2% | 72.2% | 56.3% | 4/5 |
| R32 | 155 | Fabio FogniniClay | 53 | Werner EschauerClay | 4-6 6-4 7-5 | 3 | 136 | 6 | 3 | 55.1% | 70.4% | 47.7% | 3/7 |
| R32 | 86 | Andreas SeppiClay | 17 | Juan Carlos FerreroClay | 7-6(3) 4-6 6-2 | 3 | 128 | 5 | 7 | 56.0% | 74.5% | 55.0% | 3/6 |
| R32 | 29 | Agustin CalleriClay | 406 | Rainer EitzingerClay | 6-3 7-6(4) | 3 | 84 | 6 | 6 | 49.2% | 93.3% | 45.2% | 3/4 |
| R32 | 88 | Diego HartfieldClay | 51 | Oscar HernandezClay | 5-7 6-0 6-3 | 3 | 124 | 5 | 4 | 63.1% | 77.4% | 45.2% | 3/6 |
| R32 | 68 | Nicolas LapenttiClay | 240 | Laurent RecoudercClay | 7-6(5) 6-2 | 3 | 103 | 7 | 6 | 54.0% | 72.3% | 47.5% | 11/13 |
| R32 | 137 | Alexander PeyaClay | 13 | Mikhail YouzhnyClay | 7-5 6-0 | 3 | 86 | 3 | 5 | 56.6% | 76.7% | 56.5% | 4/5 |
| R16 | 7 | Tommy RobredoClay | 49 | Igor AndreevClay | 4-6 6-1 7-6(5) | 3 | 124 | 2 | 2 | 73.4% | 75.4% | 48.0% | 1/3 |
| R16 | 32 | Juan MonacoClay | 36 | Philipp KohlschreiberClay | 6-3 6-3 | 3 | 66 | 1 | 1 | 61.2% | 76.7% | 78.9% | 1/1 |
| R16 | 78 | Sergio RoitmanClay | 18 | Juan Ignacio ChelaClay | 5-7 6-3 6-4 | 3 | 140 | 2 | 2 | 51.1% | 61.7% | 55.6% | 8/14 |
| R16 | 41 | Fernando VerdascoClay | 34 | Nicolas AlmagroClay | 6-2 7-6(6) | 3 | 93 | 0 | 2 | 69.0% | 63.3% | 68.2% | 3/4 |
| R16 | 46 | Potito StaraceClay | 37 | Florian MayerClay | 4-6 7-6(0) 6-2 | 3 | 128 | 1 | 3 | 61.9% | 60.0% | 56.8% | 4/8 |
| R16 | 86 | Andreas SeppiClay | 155 | Fabio FogniniClay | 7-6(3) 7-5 | 3 | 110 | 6 | 2 | 63.9% | 63.0% | 65.4% | 3/7 |
| R16 | 29 | Agustin CalleriClay | 88 | Diego HartfieldClay | 7-5 6-2 | 3 | 81 | 8 | 4 | 45.5% | 84.0% | 63.3% | 0/1 |
| R16 | 68 | Nicolas LapenttiClay | 137 | Alexander PeyaClay | 6-4 6-4 | 3 | 95 | 2 | 1 | 61.8% | 66.7% | 57.7% | 1/2 |
| QF | 32 | Juan MonacoClay | 7 | Tommy RobredoClay | 6-2 2-6 6-2 | 3 | 104 | 6 | 3 | 59.7% | 62.8% | 44.8% | 2/7 |
| QF | 41 | Fernando VerdascoClay | 78 | Sergio RoitmanClay | 7-6(6) 3-6 6-3 | 3 | 136 | 5 | 3 | 87.1% | 71.6% | 27.3% | 4/8 |
| QF | 46 | Potito StaraceClay | 86 | Andreas SeppiClay | 1-6 7-5 7-6(7) | 3 | 142 | 3 | 1 | 67.4% | 54.7% | 58.1% | 7/14 |
| QF | 29 | Agustin CalleriClay | 68 | Nicolas LapenttiClay | 7-6(5) 6-1 | 3 | 84 | 4 | 2 | 58.5% | 80.6% | 63.6% | 1/2 |
| SF | 32 | Juan MonacoClay | 41 | Fernando VerdascoClay | 7-5 7-5 | 3 | 87 | 2 | 0 | 71.0% | 81.8% | 72.2% | 1/1 |
| SF | 46 | Potito StaraceClay | 29 | Agustin CalleriClay | 6-4 7-5 | 3 | 84 | 0 | 0 | 74.6% | 74.5% | 62.5% | 5/6 |
| F | 32 | Juan MonacoClay | 46 | Potito StaraceClay | 5-7 6-3 6-4 | 3 | 150 | 4 | 2 | 69.8% | 63.0% | 57.1% | 7/10 |