| R64 | 167 | Dick NormanClay | 128 | Alessio Di MauroClay | 3-6 6-2 6-4 | 3 | 117 | 8 | 5 | 62.5% | 66.7% | 41.7% | 5/10 |
| R64 | 185 | Andreas SeppiClay | 146 | Michal TabaraClay | 7-6(4) 6-3 | 3 | 76 | 5 | 6 | 47.1% | 81.3% | 47.2% | 3/6 |
| R64 | 256 | Frantisek CermakClay | 126 | Ivo HeubergerClay | 7-6(0) 6-4 | 3 | 97 | 8 | 3 | 63.5% | 85.0% | 56.5% | 0/1 |
| R64 | 103 | Juan MonacoClay | 159 | Juan-Pablo GuzmanClay | 7-5 6-4 | 3 | 91 | 4 | 5 | 59.0% | 71.7% | 46.9% | 4/6 |
| R64 | 156 | Peter LuczakClay | 122 | Alexander PeyaClay | 6-2 7-6(4) | 3 | 107 | 2 | 4 | 60.5% | 63.5% | 61.8% | 7/7 |
| R64 | 214 | Yuri SchukinClay | 295 | Johannes AgerClay | 6-1 3-6 6-3 | 3 | 93 | 3 | 0 | 71.0% | 59.2% | 50.0% | 4/9 |
| R64 | 121 | Potito StaraceClay | 129 | Marc LopezClay | 7-6(1) 6-2 | 3 | 82 | 2 | 2 | 78.3% | 74.5% | 46.2% | 0/2 |
| R64 | 71 | Radek StepanekClay | 269 | Daniel Gimeno-TraverClay | 6-7(2) 7-5 7-6(3) | 3 | 141 | 6 | 4 | 63.6% | 82.4% | 56.4% | 0/1 |
| R64 | 88 | Oscar HernandezClay | 132 | Albert PortasClay | 6-1 6-4 | 3 | 49 | 3 | 1 | 61.9% | 96.2% | 68.8% | 0/0 |
| R64 | 161 | Franco SquillariClay | 96 | Paul-Henri MathieuClay | 6-4 6-2 | 3 | 90 | 4 | 1 | 58.8% | 76.7% | 66.7% | 0/0 |
| R64 | 141 | Martin Vassallo ArguelloClay | 200 | Nicolas ThomannClay | 6-4 6-7(3) 6-1 | 3 | 113 | 15 | 8 | 60.7% | 77.8% | 62.9% | 6/7 |
| R64 | 134 | Santiago VenturaClay | 157 | Stefano PescosolidoClay | 7-6(4) 6-4 | 3 | 107 | 7 | 5 | 47.3% | 74.4% | 39.6% | 10/14 |
| R64 | 94 | Stefan KoubekClay | 124 | Marc RossetClay | 6-3 6-0 | 3 | 52 | 4 | 1 | 38.6% | 82.4% | 70.4% | 3/3 |
| R64 | 114 | Alejandro FallaClay | 116 | Adrian GarciaClay | 6-0 6-3 | 3 | 40 | 2 | 0 | 58.3% | 85.7% | 73.3% | 0/0 |
| R64 | 221 | Werner EschauerClay | 652 | Thomas SchiesslingClay | 6-3 6-2 | 3 | 78 | 2 | 1 | 48.6% | 76.5% | 50.0% | 6/7 |
| R64 | 181 | Ivo MinarClay | 110 | Galo BlancoClay | 7-6(2) 7-6(11) | 3 | 117 | 8 | 3 | 50.0% | 75.0% | 59.1% | 3/6 |
| R32 | 8 | Rainer SchuettlerClay | 185 | Andreas SeppiClay | 3-6 7-6(13) 6-0 | 3 | 135 | 3 | 2 | 48.1% | 56.0% | 68.5% | 6/9 |
| R32 | 60 | David SanchezClay | 256 | Frantisek CermakClay | 6-4 5-7 6-4 | 3 | 129 | 2 | 2 | 64.9% | 77.8% | 41.2% | 10/13 |
| R32 | 103 | Juan MonacoClay | 40 | David FerrerClay | 6-3 6-4 | 3 | 77 | 1 | 2 | 67.6% | 63.0% | 40.9% | 5/8 |
| R32 | 37 | Florian MayerClay | 156 | Peter LuczakClay | 6-2 6-4 | 3 | 78 | 3 | 4 | 50.0% | 77.4% | 51.6% | 4/5 |
| R32 | 13 | Nicolas MassuClay | 214 | Yuri SchukinClay | 6-2 6-3 | 3 | 78 | 8 | 4 | 46.8% | 86.4% | 60.0% | 0/0 |
| R32 | 74 | Tomas BerdychClay | 121 | Potito StaraceClay | 6-2 7-5 | 3 | 81 | 3 | 3 | 44.9% | 74.2% | 63.2% | 2/2 |
| R32 | 71 | Radek StepanekClay | 43 | Irakli LabadzeClay | 6-2 7-6(1) | 3 | 79 | 6 | 5 | 58.2% | 74.4% | 53.6% | 1/3 |
| R32 | 31 | Mariano ZabaletaClay | 88 | Oscar HernandezClay | 7-6(5) 6-2 | 3 | 87 | 4 | 0 | 69.0% | 75.0% | 66.7% | 1/2 |
| R32 | 41 | Fernando VerdascoClay | 161 | Franco SquillariClay | 7-6(3) 6-2 | 3 | 88 | 2 | 0 | 68.4% | 76.9% | 77.8% | 2/2 |
| R32 | 141 | Martin Vassallo ArguelloClay | 62 | Jurgen MelzerClay | 6-4 6-2 | 3 | 74 | 3 | 4 | 57.9% | 78.8% | 58.3% | 3/3 |
| R32 | 134 | Santiago VenturaClay | 83 | Albert MontanesClay | 6-2 6-1 | 3 | 47 | 7 | 2 | 72.1% | 83.9% | 58.3% | 2/2 |
| R32 | 25 | Feliciano LopezClay | 94 | Stefan KoubekClay | 3-6 6-3 6-4 | 3 | 103 | 5 | 7 | 47.7% | 87.8% | 46.7% | 5/7 |
| R32 | 47 | Luis HornaClay | 114 | Alejandro FallaClay | 7-6(3) 7-6(2) | 3 | 96 | 1 | 0 | 68.0% | 74.5% | 79.2% | 3/3 |
| R32 | 50 | Albert CostaClay | 221 | Werner EschauerClay | 6-3 6-7(2) 6-3 | 3 | 161 | 5 | 1 | 57.8% | 68.3% | 54.3% | 10/13 |
| R32 | 51 | Nikolay DavydenkoClay | 167 | Dick NormanClay | 6-2 6-2 | 3 | 64 | 0 | 1 | 80.0% | 84.4% | 75.0% | 1/1 |
| R32 | 11 | Gaston GaudioClay | 181 | Ivo MinarClay | 6-4 6-1 | 3 | 74 | 2 | 1 | 57.8% | 75.7% | 48.1% | 4/5 |
| R16 | 8 | Rainer SchuettlerClay | 60 | David SanchezClay | 6-0 RET | 3 | 28 | 0 | 0 | 61.1% | 81.8% | 71.4% | 0/0 |
| R16 | 37 | Florian MayerClay | 103 | Juan MonacoClay | 6-4 6-4 | 3 | 74 | 5 | 2 | 63.1% | 75.6% | 33.3% | 2/5 |
| R16 | 13 | Nicolas MassuClay | 74 | Tomas BerdychClay | 7-6(3) 3-6 6-4 | 3 | 150 | 4 | 8 | 47.7% | 75.0% | 59.6% | 7/10 |
| R16 | 31 | Mariano ZabaletaClay | 71 | Radek StepanekClay | 6-3 7-5 | 3 | 87 | 4 | 3 | 61.0% | 77.8% | 56.5% | 1/2 |
| R16 | 41 | Fernando VerdascoClay | 141 | Martin Vassallo ArguelloClay | 7-6(7) 6-3 | 3 | 97 | 3 | 3 | 64.5% | 73.5% | 66.7% | 0/0 |
| R16 | 25 | Feliciano LopezClay | 134 | Santiago VenturaClay | 6-3 6-0 | 3 | 52 | 3 | 6 | 42.9% | 70.8% | 65.6% | 5/5 |
| R16 | 47 | Luis HornaClay | 50 | Albert CostaClay | 4-6 7-6(4) 6-4 | 3 | 141 | 9 | 3 | 68.9% | 77.4% | 64.3% | 0/1 |
| R16 | 11 | Gaston GaudioClay | 51 | Nikolay DavydenkoClay | 6-3 6-3 | 3 | 68 | 0 | 3 | 55.8% | 75.9% | 47.8% | 2/4 |
| QF | 8 | Rainer SchuettlerClay | 37 | Florian MayerClay | 7-6(6) 6-2 | 3 | 87 | 5 | 4 | 57.6% | 63.2% | 50.0% | 2/5 |
| QF | 13 | Nicolas MassuClay | 31 | Mariano ZabaletaClay | 7-6(4) 7-6(6) | 3 | 172 | 1 | 1 | 58.0% | 69.0% | 61.9% | 9/11 |
| QF | 41 | Fernando VerdascoClay | 25 | Feliciano LopezClay | 6-2 6-3 | 3 | 61 | 3 | 1 | 78.8% | 63.4% | 63.6% | 0/1 |
| QF | 11 | Gaston GaudioClay | 47 | Luis HornaClay | 7-6(5) 7-6(1) | 3 | 126 | 3 | 3 | 72.9% | 80.6% | 34.8% | 4/6 |
| SF | 13 | Nicolas MassuClay | 8 | Rainer SchuettlerClay | 6-3 6-3 | 3 | 87 | 3 | 3 | 64.4% | 73.7% | 52.4% | 4/5 |
| SF | 11 | Gaston GaudioClay | 41 | Fernando VerdascoClay | 6-0 6-2 | 3 | 64 | 3 | 1 | 57.8% | 76.9% | 68.4% | 2/2 |
| F | 13 | Nicolas MassuClay | 11 | Gaston GaudioClay | 7-6(3) 6-4 | 3 | 132 | 3 | 3 | 54.1% | 73.9% | 53.8% | 9/11 |