| R64 | 97 |  Carlos CostaClay | 85 | Emilio Benfele AlvarezClay | 6-4 6-2 | 3 | 84 | 4 | 1 | 49.0% | 87.5% | 68.0% | 2/2 |
| R64 | 146 |  Thierry ChampionClay | 121 |  Marcelo CharpentierClay | 4-6 7-5 6-3 | 3 | 126 | 6 | 0 | 51.9% | 75.9% | 42.0% | 8/12 |
| R64 | 117 |  Alexander VolkovClay | 152 |  Omar CamporeseClay | 6-3 7-5 | 3 | 80 | 4 | 2 | 36.0% | 77.8% | 54.2% | 5/7 |
| R64 | 321 |  Gerald MandlClay | 84 | Gilbert SchallerClay | 5-2 RET | 3 | 31 | 4 | 0 | 46.2% | 66.7% | 71.4% | 3/3 |
| R64 | 75 | Hernan GumyClay | 296 | Wolfgang SchranzClay | 6-4 6-4 | 3 | 92 | 3 | 1 | 63.2% | 72.1% | 64.0% | 0/0 |
| R64 | 277 | Joaquin Munoz-HernandezClay | 877 | Thomas SchiesslingClay | W/O | 3 | 99 | 0 | 2 | 52.5% | 59.5% | 73.7% | 5/6 |
| R64 | 122 |  Bernd KarbacherClay | 127 |  Jaime OncinsClay | 7-6(3) 6-2 | 3 | 102 | 6 | 4 | 43.6% | 64.7% | 47.7% | 7/10 |
| R64 | 92 | Julian AlonsoClay | 320 | Markus HipflClay | 7-5 4-6 6-1 | 3 | 84 | 6 | 6 | 57.7% | 71.1% | 54.5% | 2/6 |
| R64 | 171 | Stefan KoubekClay | 215 |  David RiklClay | 2-6 6-1 7-5 | 3 | 86 | 3 | 2 | 53.7% | 66.7% | 58.1% | 1/5 |
| R64 | 96 |  Nicolas LapenttiClay | 345 | Emilio SanchezClay | 2-6 6-1 6-1 | 3 | 90 | 2 | 4 | 58.1% | 86.1% | 42.3% | 3/5 |
| R64 | 113 | Franco SquillariClay | 206 | Andrei OlhovskiyClay | 6-1 6-3 | 3 | 53 | 1 | 2 | 68.5% | 75.7% | 58.8% | 3/3 |
| R64 | 145 | Lucas Arnold KerClay | 416 | Daniel OrsanicClay | 6-1 6-4 | 3 | 77 | 4 | 4 | 58.8% | 80.0% | 61.9% | 4/5 |
| R64 | 116 |  Oleg OgorodovClay | 95 |  Richard FrombergClay | 6-7(6) 6-4 6-3 | 3 | 136 | 7 | 5 | 52.3% | 77.6% | 54.7% | 6/7 |
| R64 | 106 | Martin SinnerClay | 454 | Werner EschauerClay | 6-4 6-4 | 3 | 72 | 2 | 8 | 41.7% | 84.0% | 51.4% | 2/4 |
| R64 | 224 | Marcos Aurelio GorrizClay | 240 | Sebastian PrietoClay | 6-3 6-1 | 3 | 71 | 3 | 0 | 50.9% | 74.1% | 61.5% | 1/1 |
| R64 | 79 | Fernando MeligeniClay | 172 | Frederic FontangClay | 6-4 6-7(5) 7-6(6) | 3 | 160 | 5 | 5 | 54.0% | 57.3% | 59.4% | 11/15 |
| R32 | 5 | Thomas MusterClay | 97 | Carlos CostaClay | 6-3 6-1 | 3 | 81 | 0 | 1 | 60.4% | 68.8% | 52.4% | 2/3 |
| R32 | 74 | Slava DosedelClay | 146 | Thierry ChampionClay | 6-3 6-2 | 3 | 72 | 2 | 0 | 58.2% | 71.9% | 60.9% | 1/2 |
| R32 | 51 |  Marcelo FilippiniClay | 117 | Alexander VolkovClay | 6-3 6-2 | 3 | 62 | 1 | 2 | 70.0% | 80.0% | 60.0% | 3/3 |
| R32 | 41 | MARHicham AraziClay | 321 | Gerald MandlClay | 6-4 7-6(5) | 3 | 78 | 4 | 5 | 44.8% | 90.0% | 56.8% | 0/1 |
| R32 | 75 | Hernan GumyClay | 12 | Gustavo KuertenClay | 6-1 6-3 | 3 | 67 | 2 | 3 | 50.0% | 66.7% | 66.7% | 3/4 |
| R32 | 76 | Hendrik DreekmannClay | 277 | Joaquin Munoz-HernandezClay | 6-0 6-1 | 3 | 41 | 4 | 3 | 52.9% | 83.3% | 56.3% | 0/0 |
| R32 | 122 | Bernd KarbacherClay | 64 | Jiri NovakClay | 6-3 6-4 | 3 | 75 | 2 | 0 | 47.0% | 67.7% | 65.7% | 3/4 |
| R32 | 92 | Julian AlonsoClay | 31 | Bohdan UlihrachClay | 6-2 6-3 | 3 | 52 | 1 | 1 | 45.1% | 69.6% | 75.0% | 4/5 |
| R32 | 171 | Stefan KoubekClay | 22 | Alberto BerasateguiClay | 6-2 6-3 | 3 | 59 | 2 | 3 | 61.5% | 62.5% | 52.0% | 5/7 |
| R32 | 96 | Nicolas LapenttiClay | 71 |  Jeff TarangoClay | 6-3 3-6 6-1 | 3 | 115 | 9 | 2 | 63.9% | 61.3% | 54.3% | 14/17 |
| R32 | 70 | Galo BlancoClay | 113 | Franco SquillariClay | 6-3 6-2 | 3 | 72 | 2 | 4 | 48.4% | 66.7% | 62.5% | 9/10 |
| R32 | 4 | Alex CorretjaClay | 145 | Lucas Arnold KerClay | 6-2 6-7(8) 6-4 | 3 | 140 | 4 | 3 | 49.4% | 77.3% | 68.9% | 2/3 |
| R32 | 48 | Juan Albert Viloca-PuigClay | 116 | Oleg OgorodovClay | 6-2 6-0 | 3 | 48 | 2 | 1 | 57.1% | 75.0% | 86.7% | 0/0 |
| R32 | 56 |  Filip DewulfClay | 106 | Martin SinnerClay | 6-1 6-0 | 3 | 53 | 1 | 4 | 43.2% | 68.4% | 72.0% | 3/3 |
| R32 | 88 | Renzo FurlanClay | 224 | Marcos Aurelio GorrizClay | 6-2 6-4 | 3 | 75 | 4 | 4 | 47.1% | 91.7% | 63.0% | 1/1 |
| R32 | 6 | Yevgeny KafelnikovClay | 79 | Fernando MeligeniClay | 6-1 6-3 | 3 | 70 | 5 | 3 | 46.2% | 80.0% | 51.4% | 1/1 |
| R16 | 74 | Slava DosedelClay | 5 | Thomas MusterClay | 2-6 6-3 6-4 | 3 | 95 | 2 | 5 | 53.2% | 81.0% | 54.1% | 0/2 |
| R16 | 51 | Marcelo FilippiniClay | 41 | MARHicham AraziClay | 6-3 6-1 | 3 | 63 | 0 | 1 | 71.7% | 74.4% | 47.1% | 3/3 |
| R16 | 75 | Hernan GumyClay | 76 | Hendrik DreekmannClay | 6-3 6-0 | 3 | 68 | 3 | 4 | 43.9% | 88.9% | 52.2% | 0/1 |
| R16 | 92 | Julian AlonsoClay | 122 | Bernd KarbacherClay | 6-3 6-2 | 3 | 55 | 1 | 2 | 61.7% | 79.3% | 72.2% | 0/0 |
| R16 | 171 | Stefan KoubekClay | 96 | Nicolas LapenttiClay | 7-5 6-3 | 3 | 89 | 3 | 3 | 70.8% | 58.8% | 52.4% | 3/6 |
| R16 | 70 | Galo BlancoClay | 4 | Alex CorretjaClay | 7-6(4) 7-5 | 3 | 117 | 1 | 5 | 51.2% | 64.3% | 62.5% | 4/7 |
| R16 | 56 | Filip DewulfClay | 48 | Juan Albert Viloca-PuigClay | 6-4 6-2 | 3 | 63 | 3 | 3 | 58.1% | 72.2% | 61.5% | 5/5 |
| R16 | 6 | Yevgeny KafelnikovClay | 88 | Renzo FurlanClay | 7-6(5) 6-7(2) 6-1 | 3 | 122 | 5 | 6 | 48.1% | 70.0% | 53.7% | 4/8 |
| QF | 74 | Slava DosedelClay | 51 | Marcelo FilippiniClay | 7-5 6-4 | 3 | 88 | 3 | 2 | 62.1% | 70.7% | 56.0% | 4/6 |
| QF | 92 | Julian AlonsoClay | 75 | Hernan GumyClay | 4-6 6-3 7-6(5) | 3 | 133 | 3 | 2 | 67.7% | 69.8% | 60.0% | 3/6 |
| QF | 70 | Galo BlancoClay | 171 | Stefan KoubekClay | 6-7(6) 6-2 6-4 | 3 | 138 | 5 | 4 | 52.8% | 70.2% | 56.9% | 4/6 |
| QF | 56 | Filip DewulfClay | 6 | Yevgeny KafelnikovClay | 7-5 7-5 | 3 | 94 | 0 | 8 | 46.7% | 65.7% | 47.5% | 4/8 |
| SF | 92 | Julian AlonsoClay | 74 | Slava DosedelClay | 6-3 6-4 | 3 | 61 | 2 | 2 | 57.9% | 72.7% | 58.3% | 4/6 |
| SF | 56 | Filip DewulfClay | 70 | Galo BlancoClay | 6-3 6-2 | 3 | 51 | 8 | 4 | 46.8% | 95.5% | 64.0% | 2/2 |
| F | 56 | Filip DewulfClay | 92 | Julian AlonsoClay | 7-6(2) 6-4 6-1 | 5 | 92 | 10 | 7 | 50.5% | 83.3% | 59.6% | 3/4 |
