| R32 | 84 |  Albert MontanesClay | 93 |  Alexander PeyaClay | 6-3 6-2 | 3 | 74 | 0 | 0 | 63.2% | 72.2% | 66.7% | 4/4 |
| R32 | 319 |  Dusan VemicClay | 60 | Ruben Ramirez HidalgoClay | 6-3 6-0 | 3 | 68 | 8 | 1 | 63.8% | 70.0% | 70.6% | 4/4 |
| R32 | 68 |  Michael RussellClay | 95 | Paul GoldsteinClay | 6-2 6-0 | 3 | 70 | 1 | 0 | 68.4% | 80.8% | 75.0% | 2/2 |
| R32 | 77 | Vincent SpadeaClay | 46 | Robby GinepriClay | 6-3 3-6 6-3 | 3 | 108 | 3 | 4 | 61.1% | 72.7% | 40.0% | 8/12 |
| R32 | 10 |  Tommy HaasClay | 67 | Sam QuerreyClay | 3-6 6-3 7-5 | 3 | 99 | 5 | 6 | 48.7% | 84.2% | 45.0% | 1/5 |
| R32 | 105 |  Nicolas DevilderClay | 117 | Justin GimelstobClay | 6-2 6-3 | 3 | 78 | 4 | 3 | 51.1% | 83.3% | 65.2% | 1/1 |
| R32 | 81 |  Diego HartfieldClay | 58 | Sebastien GrosjeanClay | 6-4 6-4 | 3 | 89 | 4 | 2 | 65.7% | 71.7% | 50.0% | 8/10 |
| R32 | 108 |  Ivo KarlovicClay | 44 | Benjamin BeckerClay | 7-5 7-6(3) | 3 | 116 | 16 | 2 | 62.5% | 72.7% | 60.6% | 9/10 |
| R32 | 28 | Jurgen MelzerClay | 134 | Rainer SchuettlerClay | 6-2 3-6 6-1 | 3 | 111 | 5 | 4 | 58.7% | 68.5% | 55.3% | 5/6 |
| R32 | 661 |  Victor HanescuClay | 1039 |  Martin VerkerkClay | 6-4 6-4 | 3 | 68 | 3 | 1 | 70.0% | 83.3% | 55.6% | 2/2 |
| R32 | 156 | Mariano ZabaletaClay | 297 | Ryan SweetingClay | 6-0 7-6(8) | 3 | 82 | 8 | 1 | 67.7% | 73.8% | 70.0% | 3/3 |
| R32 | 24 | Mardy FishClay | 62 | Martin Vassallo ArguelloClay | 5-7 6-2 7-5 | 3 | 152 | 5 | 6 | 49.5% | 75.6% | 43.5% | 7/12 |
| R32 | 52 | Juan MonacoClay | 671 | Jan-Michael GambillClay | 7-5 6-4 | 3 | 70 | 2 | 1 | 63.2% | 83.3% | 71.4% | 3/4 |
| R32 | 70 |  Amer DelicClay | 80 | Robert KendrickClay | 6-3 1-6 7-5 | 3 | 91 | 8 | 2 | 68.9% | 72.5% | 52.2% | 3/6 |
| R32 | 165 | Alex KuznetsovClay | 263 | Lars BurgsmullerClay | 7-5 7-5 | 3 | 102 | 5 | 1 | 67.6% | 78.3% | 45.5% | 2/4 |
| R32 | 9 | James BlakeClay | 107 |  Davide SanguinettiClay | 6-3 6-0 | 3 | 59 | 2 | 1 | 53.0% | 68.6% | 61.3% | 5/5 |
| R16 | 84 | Albert MontanesClay | 319 | Dusan VemicClay | 6-4 4-6 6-4 | 3 | 125 | 5 | 2 | 62.4% | 73.0% | 57.9% | 9/10 |
| R16 | 77 | Vincent SpadeaClay | 68 | Michael RussellClay | 7-6(3) 2-6 6-1 | 3 | 135 | 6 | 3 | 64.4% | 60.0% | 41.7% | 5/11 |
| R16 | 10 | Tommy HaasClay | 105 | Nicolas DevilderClay | 6-3 6-4 | 3 | 77 | 7 | 3 | 59.7% | 81.1% | 60.0% | 5/5 |
| R16 | 108 | Ivo KarlovicClay | 81 | Diego HartfieldClay | W/O | 3 | - | 7 | 3 | 59.7% | 81.1% | 60.0% | 5/5 |
| R16 | 28 | Jurgen MelzerClay | 661 | Victor HanescuClay | 6-4 6-2 | 3 | 81 | 5 | 2 | 59.3% | 71.4% | 62.5% | 3/3 |
| R16 | 156 | Mariano ZabaletaClay | 24 | Mardy FishClay | 7-5 6-4 | 3 | 100 | 0 | 0 | 51.4% | 78.4% | 51.4% | 5/7 |
| R16 | 52 | Juan MonacoClay | 70 | Amer DelicClay | 6-2 6-3 | 3 | 66 | 0 | 0 | 64.9% | 79.2% | 76.9% | 0/1 |
| R16 | 9 | James BlakeClay | 165 | Alex KuznetsovClay | 7-6(4) 6-1 | 3 | 77 | 5 | 4 | 57.6% | 71.1% | 57.1% | 2/4 |
| QF | 84 | Albert MontanesClay | 77 | Vincent SpadeaClay | 6-4 6-4 | 3 | 80 | 4 | 0 | 82.8% | 71.7% | 45.5% | 1/2 |
| QF | 108 | Ivo KarlovicClay | 10 | Tommy HaasClay | 7-6(7) 6-4 | 3 | 98 | 12 | 2 | 56.0% | 85.7% | 48.5% | 2/2 |
| QF | 156 | Mariano ZabaletaClay | 28 | Jurgen MelzerClay | 6-1 6-2 | 3 | 69 | 3 | 3 | 52.8% | 60.7% | 72.0% | 5/5 |
| QF | 9 | James BlakeClay | 52 | Juan MonacoClay | 7-6(5) 1-6 7-6(0) | 3 | 132 | 6 | 3 | 61.7% | 63.6% | 63.4% | 4/8 |
| SF | 108 | Ivo KarlovicClay | 84 | Albert MontanesClay | 7-6(5) 6-2 | 3 | 72 | 15 | 0 | 71.4% | 84.4% | 66.7% | 3/3 |
| SF | 156 | Mariano ZabaletaClay | 9 | James BlakeClay | 7-5 7-6(7) | 3 | 104 | 3 | 4 | 64.6% | 82.4% | 53.6% | 4/5 |
| F | 108 | Ivo KarlovicClay | 156 | Mariano ZabaletaClay | 6-4 6-1 | 3 | 79 | 10 | 1 | 68.3% | 78.0% | 42.1% | 5/5 |
