| R32 | 7 |  Andrey RublevClay | 54 |  Bernabe Zapata MirallesClay | 5-7 6-1 7-6(7) | 3 | 172 | 5 | 2 | 69.0% | 66.3% | 55.6% | 9/12 |
| R32 | 61 |  Daniel AltmaierClay | 48 |  Richard GasquetClay | 7-5 6-4 | 3 | 114 | 6 | 2 | 51.7% | 71.0% | 48.3% | 2/6 |
| R32 | 79 |  Zhizhen ZhangClay | 151 |  Jan ChoinskiClay | 6-4 7-5 | 3 | 113 | 4 | 2 | 56.3% | 70.0% | 61.3% | 4/5 |
| R32 | 45 | Yannick HanfmannClay | 21 |  Francisco CerundoloClay | 4-6 6-2 4-2 RET | 3 | 107 | 1 | 3 | 70.0% | 69.4% | 52.4% | 3/6 |
| R32 | 18 |  Lorenzo MusettiClay | 186 |  Elias YmerClay | 6-4 6-1 | 3 | 74 | 4 | 1 | 72.3% | 76.5% | 38.5% | 1/2 |
| R32 | 172 |  Jozef KovalikClay | 123 |  Thiago Seyboth WildClay | 7-6(6) 6-4 | 3 | 111 | 3 | 2 | 72.9% | 74.2% | 56.5% | 2/3 |
| R32 | 228 | Guido PellaClay | 121 | Thiago MonteiroClay | 6-3 4-6 6-4 | 3 | 146 | 8 | 2 | 66.0% | 81.3% | 45.5% | 9/10 |
| R32 | 57 |  Laslo DjereClay | 34 | Tomas Martin EtcheverryClay | 7-6(2) 6-3 | 3 | 106 | 2 | 2 | 56.3% | 75.0% | 67.9% | 1/2 |
| R32 | 39 | Alejandro Davidovich FokinaClay | 49 | Pedro CachinClay | 2-6 7-5 6-2 | 3 | 115 | 2 | 1 | 61.0% | 78.0% | 56.3% | 5/7 |
| R32 | 77 | Luca Van AsscheClay | 81 | Alexandre MullerClay | 7-6(3) 6-4 | 3 | 133 | 6 | 3 | 53.6% | 64.9% | 46.9% | 2/7 |
| R32 | 144 | Maximilian MartererClay | 251 | Rudolf MollekerClay | 7-6(2) 6-2 | 3 | 80 | 16 | 2 | 69.2% | 75.6% | 50.0% | 1/2 |
| R32 | 19 | Alexander ZverevClay | 118 | Alex MolcanClay | 6-0 6-3 | 3 | 61 | 3 | 0 | 81.8% | 72.2% | 75.0% | 0/0 |
| R32 | 60 | Dusan LajovicClay | 40 | Miomir KecmanovicClay | 3-6 6-4 6-3 | 3 | 119 | 2 | 1 | 69.4% | 72.9% | 61.5% | 5/6 |
| R32 | 71 | Arthur FilsClay | 67 |  Daniel Elahi GalanClay | 7-5 7-5 | 3 | 105 | 4 | 3 | 66.7% | 77.1% | 54.2% | 4/5 |
| R32 | 120 |  Cristian GarinClay | 164 |  Hugo DellienClay | 6-7(3) 6-1 6-3 | 3 | 130 | 3 | 2 | 67.5% | 69.6% | 59.3% | 1/3 |
| R32 | 4 |  Casper RuudClay | 64 | Sebastian BaezClay | 6-3 1-6 6-3 | 3 | 116 | 2 | 3 | 70.0% | 59.2% | 61.9% | 1/5 |
| R16 | 61 | Daniel AltmaierClay | 7 | Andrey RublevClay | 6-2 6-2 | 3 | 74 | 7 | 2 | 55.1% | 85.2% | 54.5% | 2/2 |
| R16 | 79 | Zhizhen ZhangClay | 45 | Yannick HanfmannClay | 4-6 6-1 6-4 | 3 | 128 | 2 | 1 | 63.4% | 66.1% | 55.9% | 4/7 |
| R16 | 18 | Lorenzo MusettiClay | 172 | Jozef KovalikClay | 3-6 6-2 6-4 | 3 | 125 | 2 | 0 | 59.7% | 69.8% | 65.5% | 3/5 |
| R16 | 57 | Laslo DjereClay | 228 | Guido PellaClay | 6-2 3-6 6-3 | 3 | 121 | 8 | 3 | 60.2% | 76.0% | 54.5% | 2/3 |
| R16 | 77 | Luca Van AsscheClay | 39 | Alejandro Davidovich FokinaClay | 3-6 7-6(5) 6-4 | 3 | 192 | 6 | 2 | 54.3% | 71.4% | 52.8% | 8/10 |
| R16 | 19 | Alexander ZverevClay | 144 | Maximilian MartererClay | 6-3 7-5 | 3 | 77 | 2 | 2 | 75.0% | 89.7% | 30.8% | 2/3 |
| R16 | 71 | Arthur FilsClay | 60 | Dusan LajovicClay | 7-5 7-5 | 3 | 100 | 3 | 6 | 64.5% | 65.3% | 48.1% | 3/6 |
| R16 | 4 | Casper RuudClay | 120 | Cristian GarinClay | 1-6 6-2 6-2 | 3 | 100 | 4 | 1 | 65.8% | 66.0% | 50.0% | 8/11 |
| QF | 79 | Zhizhen ZhangClay | 61 | Daniel AltmaierClay | 6-4 6-4 | 3 | 83 | 2 | 2 | 72.6% | 75.6% | 64.7% | 2/2 |
| QF | 57 | Laslo DjereClay | 18 | Lorenzo MusettiClay | 7-5 6-3 | 3 | 88 | 6 | 0 | 70.7% | 75.6% | 70.6% | 0/1 |
| QF | 19 | Alexander ZverevClay | 77 | Luca Van AsscheClay | 6-3 6-4 | 3 | 89 | 8 | 1 | 72.9% | 80.0% | 76.9% | 0/1 |
| QF | 71 | Arthur FilsClay | 4 | Casper RuudClay | 6-0 6-4 | 3 | 77 | 4 | 3 | 68.8% | 84.8% | 46.7% | 1/1 |
| SF | 57 | Laslo DjereClay | 79 | Zhizhen ZhangClay | 6-3 6-2 | 3 | 60 | 6 | 1 | 66.7% | 96.4% | 71.4% | 0/0 |
| SF | 19 | Alexander ZverevClay | 71 | Arthur FilsClay | 6-2 6-4 | 3 | 91 | 7 | 2 | 77.3% | 72.5% | 46.7% | 3/3 |
| F | 19 | Alexander ZverevClay | 57 | Laslo DjereClay | 7-5 6-3 | 3 | 110 | 3 | 2 | 64.7% | 77.3% | 54.2% | 4/5 |
