| R32 | 8 |  Andrey RublevClay | 107 |  Ricardas BerankisClay | 6-3 6-4 | 3 | 71 | 12 | 2 | 70.2% | 82.5% | 41.2% | 4/5 |
| R32 | 30 |  Francisco CerundoloClay | 56 |  Daniel AltmaierClay | 2-6 6-4 6-2 | 3 | 132 | 1 | 2 | 59.8% | 67.3% | 54.1% | 8/10 |
| R32 | 113 |  Daniel Elahi GalanClay | 78 | Federico CoriaClay | 7-6(4) 6-4 | 3 | 115 | 5 | 1 | 67.9% | 73.6% | 52.0% | 3/4 |
| R32 | 37 | Aslan KaratsevClay | 28 |  Nikoloz BasilashviliClay | 6-4 6-0 | 3 | 61 | 4 | 1 | 55.3% | 85.7% | 64.7% | 0/1 |
| R32 | 42 |  Emil RuusuvuoriClay | 14 | Diego SchwartzmanClay | 7-5 6-4 | 3 | 142 | 1 | 2 | 67.8% | 62.3% | 55.2% | 7/9 |
| R32 | 62 |  Lorenzo MusettiClay | 75 |  Dusan LajovicClay | 6-7(4) 7-6(4) 6-3 | 3 | 175 | 2 | 1 | 73.2% | 76.8% | 56.7% | 6/7 |
| R32 | 186 |  Jozef KovalikClay | 830 | Max Hans RehbergClay | 3-6 7-5 6-1 | 3 | 135 | 3 | 1 | 78.8% | 62.8% | 33.3% | 7/11 |
| R32 | 35 |  Alejandro Davidovich FokinaClay | 25 |  Botic van de ZandschulpClay | 6-4 6-4 | 3 | 90 | 0 | 0 | 77.8% | 57.1% | 35.7% | 5/9 |
| R32 | 47 | Tallon GriekspoorClay | 27 |  Holger RuneClay | 7-6(8) 7-5 | 3 | 115 | 7 | 1 | 65.3% | 89.4% | 60.0% | 2/3 |
| R32 | 183 |  Borna CoricClay | 69 | Laslo DjereClay | 1-6 7-6(4) 6-3 | 3 | 149 | 7 | 3 | 51.7% | 67.4% | 55.8% | 4/8 |
| R32 | 48 | Alex MolcanClay | 585 | Marko TopoClay | 7-5 6-3 | 3 | 91 | 1 | 3 | 71.7% | 84.2% | 66.7% | 2/2 |
| R32 | 23 | Pablo Carreno BustaClay | 169 | Luca NardiClay | 6-2 6-1 | 3 | 62 | 4 | 1 | 65.7% | 91.3% | 58.3% | 0/0 |
| R32 | 26 | Karen KhachanovClay | 122 | Jan-Lennard StruffClay | 3-6 6-3 7-6(2) | 3 | 136 | 11 | 4 | 66.4% | 71.2% | 45.9% | 12/15 |
| R32 | 61 | Fabio FogniniClay | 285 | SLOAljaz BedeneClay | 6-3 3-6 7-6(5) | 3 | 146 | 3 | 3 | 58.1% | 70.5% | 54.5% | 6/8 |
| R32 | 43 | Filip KrajinovicClay | 32 | Sebastian BaezClay | 6-1 4-6 7-6(6) | 3 | 144 | 3 | 3 | 59.8% | 72.4% | 59.0% | 6/8 |
| R32 | 6 | Carlos AlcarazClay | 259 | Nicola KuhnClay | 3-6 6-1 7-6(3) | 3 | 146 | 1 | 1 | 70.8% | 74.6% | 61.5% | 1/2 |
| R16 | 30 | Francisco CerundoloClay | 8 | Andrey RublevClay | 6-4 6-2 | 3 | 92 | 2 | 1 | 60.3% | 63.2% | 56.0% | 5/7 |
| R16 | 37 | Aslan KaratsevClay | 113 | Daniel Elahi GalanClay | 3-6 6-3 6-4 | 3 | 115 | 6 | 6 | 52.1% | 89.2% | 50.0% | 1/3 |
| R16 | 62 | Lorenzo MusettiClay | 42 | Emil RuusuvuoriClay | 6-4 7-5 | 3 | 111 | 1 | 2 | 62.9% | 70.5% | 46.2% | 4/7 |
| R16 | 35 | Alejandro Davidovich FokinaClay | 186 | Jozef KovalikClay | 6-2 6-2 | 3 | 69 | 5 | 3 | 59.5% | 88.0% | 58.8% | 0/0 |
| R16 | 183 | Borna CoricClay | 47 | Tallon GriekspoorClay | 6-3 6-4 | 3 | 90 | 9 | 2 | 59.0% | 80.6% | 60.0% | 3/3 |
| R16 | 48 | Alex MolcanClay | 23 | Pablo Carreno BustaClay | 6-3 1-6 7-6(5) | 3 | 150 | 2 | 1 | 59.6% | 64.6% | 54.5% | 13/16 |
| R16 | 26 | Karen KhachanovClay | 61 | Fabio FogniniClay | 6-3 7-5 | 3 | 102 | 3 | 1 | 66.2% | 63.3% | 64.0% | 7/8 |
| R16 | 6 | Carlos AlcarazClay | 43 | Filip KrajinovicClay | 7-6(4) 6-3 | 3 | 112 | 3 | 4 | 70.5% | 65.1% | 61.1% | 1/3 |
| QF | 30 | Francisco CerundoloClay | 37 | Aslan KaratsevClay | 6-3 4-6 7-6(4) | 3 | 145 | 5 | 3 | 52.4% | 64.8% | 49.0% | 4/8 |
| QF | 62 | Lorenzo MusettiClay | 35 | Alejandro Davidovich FokinaClay | 6-4 6-3 | 3 | 90 | 2 | 0 | 74.1% | 60.0% | 78.6% | 2/4 |
| QF | 48 | Alex MolcanClay | 183 | Borna CoricClay | 7-6(7) 2-0 RET | 3 | 87 | 1 | 1 | 66.0% | 77.4% | 68.8% | 2/2 |
| QF | 6 | Carlos AlcarazClay | 26 | Karen KhachanovClay | 6-0 6-2 | 3 | 69 | 0 | 0 | 73.8% | 71.0% | 72.7% | 1/1 |
| SF | 62 | Lorenzo MusettiClay | 30 | Francisco CerundoloClay | 6-3 7-6(3) | 3 | 114 | 0 | 0 | 64.0% | 61.8% | 54.8% | 5/8 |
| SF | 6 | Carlos AlcarazClay | 48 | Alex MolcanClay | 7-6(2) 6-1 | 3 | 93 | 2 | 1 | 75.5% | 72.5% | 46.2% | 1/3 |
| F | 62 | Lorenzo MusettiClay | 6 | Carlos AlcarazClay | 6-4 6-7(6) 6-4 | 3 | 166 | 1 | 2 | 59.6% | 78.0% | 52.5% | 3/5 |
