| R32 | 156 |  Daniel Gimeno-TraverClay | 23 |  Benoit PaireClay | 7-5 3-6 6-4 | 3 | 129 | 2 | 6 | 63.3% | 64.5% | 36.4% | 14/21 |
| R32 | 215 |  Daniil MedvedevClay | 86 |  Jan-Lennard StruffClay | 6-4 5-7 6-4 | 3 | 125 | 4 | 1 | 52.7% | 75.5% | 68.2% | 0/1 |
| R32 | - | Louis WesselsClay | 200 |  Steven DiezClay | 5-7 6-2 6-1 | 3 | 116 | 2 | 5 | 69.0% | 71.7% | 48.1% | 3/5 |
| R32 | 47 |  Martin KlizanClay | 116 |  Igor SijslingClay | 6-4 1-6 6-3 | 3 | 104 | 3 | 3 | 64.8% | 63.2% | 38.7% | 4/9 |
| R32 | 82 | Inigo CervantesClay | 27 | Alexander ZverevClay | 7-5 7-6(2) | 3 | 100 | 9 | 1 | 67.1% | 68.6% | 40.0% | 1/5 |
| R32 | 83 | Stephane RobertClay | 109 |  Leonardo MayerClay | 7-6(3) 6-4 | 3 | 98 | 1 | 5 | 46.8% | 88.9% | 46.3% | 4/5 |
| R32 | 151 | SLOGrega ZemljaClay | - | Marvin MoellerClay | 6-1 6-2 | 3 | 62 | 3 | 0 | 52.9% | 77.8% | 62.5% | 3/3 |
| R32 | 56 | Guillermo Garcia-LopezClay | 159 | Kenny De SchepperClay | 5-7 6-2 7-6(6) | 3 | 151 | 2 | 6 | 61.9% | 66.2% | 55.0% | 6/10 |
| R32 | 44 | Nicolas AlmagroClay | 206 |  Jan SatralClay | 6-3 3-6 6-2 | 3 | 103 | 6 | 6 | 55.2% | 79.2% | 53.8% | 5/6 |
| R32 | 66 | Paul-Henri MathieuClay | 108 |  Gerald MelzerClay | 6-4 7-6(5) | 3 | 101 | 7 | 7 | 55.1% | 69.8% | 40.0% | 2/6 |
| R32 | 123 |  Thiago MonteiroClay | 141 | Mischa ZverevClay | 7-6(5) 6-4 | 3 | 90 | 1 | 0 | 59.7% | 73.0% | 56.0% | 0/2 |
| R32 | 24 |  Pablo CuevasClay | 77 | Florian MayerClay | 6-4 6-3 | 3 | 75 | 6 | 2 | 54.0% | 88.9% | 60.9% | 0/0 |
| R32 | 142 | Maximo GonzalezClay | 34 | Jeremy ChardyClay | 6-2 2-6 7-6(4) | 3 | 134 | 3 | 5 | 56.0% | 64.3% | 47.7% | 7/11 |
| R32 | 153 | Renzo OlivoClay | 63 | Mikhail YouzhnyClay | 7-6(5) 2-6 6-1 | 3 | 134 | 7 | 3 | 46.2% | 70.8% | 50.0% | 5/8 |
| R32 | 144 | Nicolas KickerClay | 113 |  Thomas FabbianoClay | 6-3 5-7 6-1 | 3 | 122 | 2 | 6 | 56.7% | 64.7% | 61.5% | 7/10 |
| R32 | 22 | Philipp KohlschreiberClay | 87 | Carlos BerlocqClay | 6-3 6-7(5) 6-3 | 3 | 156 | 6 | 5 | 58.8% | 78.7% | 57.6% | 0/1 |
| R16 | 156 | Daniel Gimeno-TraverClay | 215 | Daniil MedvedevClay | 5-7 7-6(4) 7-6(2) | 3 | 187 | 1 | 6 | 65.1% | 59.8% | 59.6% | 14/18 |
| R16 | 47 | Martin KlizanClay | - | Louis WesselsClay | 6-1 6-1 | 3 | 50 | 4 | 1 | 63.8% | 63.3% | 76.5% | 4/4 |
| R16 | 83 | Stephane RobertClay | 82 | Inigo CervantesClay | 7-5 4-6 6-1 | 3 | 132 | 2 | 3 | 53.4% | 61.8% | 52.1% | 13/17 |
| R16 | 56 | Guillermo Garcia-LopezClay | 151 | SLOGrega ZemljaClay | 6-2 6-2 | 3 | 73 | 3 | 0 | 72.0% | 69.4% | 64.3% | 2/3 |
| R16 | 66 | Paul-Henri MathieuClay | 44 | Nicolas AlmagroClay | 4-6 7-6(4) 7-5 | 3 | 169 | 6 | 11 | 51.9% | 71.3% | 44.6% | 11/14 |
| R16 | 24 | Pablo CuevasClay | 123 | Thiago MonteiroClay | 6-2 6-3 | 3 | 77 | 1 | 0 | 51.3% | 95.0% | 73.7% | 1/1 |
| R16 | 153 | Renzo OlivoClay | 142 | Maximo GonzalezClay | 6-3 6-4 | 3 | 91 | 4 | 2 | 64.1% | 74.0% | 46.4% | 3/3 |
| R16 | 22 | Philipp KohlschreiberClay | 144 | Nicolas KickerClay | 4-6 6-1 6-2 | 3 | 111 | 4 | 2 | 59.5% | 79.5% | 33.3% | 2/5 |
| QF | 47 | Martin KlizanClay | 156 | Daniel Gimeno-TraverClay | 6-4 6-3 | 3 | 76 | 0 | 1 | 64.2% | 70.6% | 57.9% | 2/4 |
| QF | 83 | Stephane RobertClay | 56 | Guillermo Garcia-LopezClay | 7-6(4) 4-6 6-3 | 3 | 148 | 2 | 4 | 55.5% | 68.9% | 55.1% | 6/9 |
| QF | 24 | Pablo CuevasClay | 66 | Paul-Henri MathieuClay | 7-6(7) 6-1 | 3 | 79 | 12 | 2 | 62.7% | 91.9% | 59.1% | 1/1 |
| QF | 153 | Renzo OlivoClay | 22 | Philipp KohlschreiberClay | 1-6 6-0 7-5 | 3 | 110 | 2 | 4 | 53.2% | 71.4% | 37.8% | 6/10 |
| SF | 47 | Martin KlizanClay | 83 | Stephane RobertClay | 6-3 6-4 | 3 | 82 | 2 | 1 | 63.2% | 72.2% | 52.4% | 2/4 |
| SF | 24 | Pablo CuevasClay | 153 | Renzo OlivoClay | 7-5 6-3 | 3 | 100 | 2 | 3 | 55.9% | 78.9% | 70.0% | 6/6 |
| F | 47 | Martin KlizanClay | 24 | Pablo CuevasClay | 6-1 6-4 | 3 | 59 | 1 | 0 | 72.5% | 83.8% | 42.9% | 1/2 |
