| R64 | 83 |  Albert Ramos-VinolasClay | 51 |  Adrian MannarinoClay | 6-2 6-4 | 3 | 69 | 4 | 1 | 64.0% | 84.4% | 50.0% | 2/3 |
| R64 | 57 |  Radek StepanekClay | 132 |  Andreas BeckClay | 7-5 7-6(2) | 3 | 115 | 8 | 2 | 69.9% | 72.3% | 60.7% | 4/4 |
| R64 | 55 |  Jarkko NieminenClay | 62 |  Santiago GiraldoClay | 6-4 6-3 | 3 | 73 | 2 | 2 | 71.7% | 76.3% | 60.0% | 2/3 |
| R64 | 45 |  Sergiy StakhovskyClay | 92 |  Maximo GonzalezClay | 6-2 6-3 | 3 | 64 | 1 | 0 | 62.7% | 65.6% | 78.9% | 2/3 |
| R64 | 80 | Carlos BerlocqClay | 54 |  Robin HaaseClay | 6-2 6-2 | 3 | 85 | 3 | 1 | 58.8% | 73.3% | 47.6% | 1/3 |
| R64 | 155 | Julian ReisterClay | 70 |  Denis IstominClay | 6-3 6-4 | 3 | 74 | 0 | 3 | 54.5% | 70.0% | 68.0% | 1/2 |
| R64 | 187 | Bastian KnittelClay | 41 |  Ivan DodigClay | 6-4 6-3 | 3 | 83 | 0 | 4 | 61.4% | 74.3% | 45.5% | 4/6 |
| R64 | 90 | Tobias KamkeClay | 72 | Pere RibaClay | 6-1 6-1 | 3 | 75 | 0 | 2 | 70.0% | 74.3% | 53.3% | 1/1 |
| R64 | 117 |  Marsel IlhanClay | 78 | Philipp PetzschnerClay | 6-2 4-6 7-6(5) | 3 | 137 | 8 | 1 | 65.5% | 63.9% | 57.9% | 9/12 |
| R64 | 42 | Juan MonacoClay | 119 |  Simone BolelliClay | 6-3 7-5 | 3 | 102 | 1 | 0 | 71.7% | 74.4% | 52.9% | 0/2 |
| R64 | 43 | Philipp KohlschreiberClay | 46 |  Andrey GolubevClay | 7-5 6-3 | 3 | 97 | 3 | 4 | 50.8% | 75.0% | 61.3% | 3/4 |
| R64 | 71 | Lukas RosolClay | 53 | Potito StaraceClay | 7-6(5) 6-1 | 3 | 71 | 4 | 1 | 61.7% | 81.1% | 43.5% | 3/4 |
| R64 | 44 | Pablo AndujarClay | 109 | Julien BenneteauClay | 6-2 6-2 | 3 | 80 | 2 | 1 | 64.2% | 70.6% | 63.2% | 2/2 |
| R64 | 168 | Cedrik-Marcel StebeClay | 64 | Juan Carlos FerreroClay | 6-3 6-2 | 3 | 76 | 3 | 1 | 58.5% | 71.0% | 63.6% | 4/5 |
| R64 | 194 |  Victor CrivoiClay | 167 | Guillermo OlasoClay | 6-4 6-3 | 3 | 77 | 12 | 0 | 72.5% | 83.8% | 42.9% | 0/0 |
| R64 | 69 | Daniel Gimeno-TraverClay | 47 | Marcel GranollersClay | 6-3 RET | 3 | 34 | 1 | 0 | 52.0% | 84.6% | 75.0% | 0/0 |
| R32 | 7 | Gael MonfilsClay | 83 | Albert Ramos-VinolasClay | 6-4 6-2 | 3 | 73 | 5 | 1 | 58.2% | 84.4% | 60.9% | 5/5 |
| R32 | 57 | Radek StepanekClay | 39 | Andreas SeppiClay | 6-1 7-5 | 3 | 88 | 2 | 4 | 57.1% | 66.7% | 59.3% | 3/5 |
| R32 | 55 | Jarkko NieminenClay | 27 | Alexandr DolgopolovClay | 6-3 1-6 6-4 | 3 | 86 | 3 | 1 | 59.4% | 61.0% | 57.1% | 1/5 |
| R32 | 18 | Gilles SimonClay | 45 | Sergiy StakhovskyClay | 6-2 6-1 | 3 | 63 | 0 | 1 | 55.6% | 70.0% | 50.0% | 0/2 |
| R32 | 17 |  Mikhail YouzhnyClay | 80 | Carlos BerlocqClay | 7-5 7-6(7) | 3 | 139 | 6 | 1 | 54.1% | 80.0% | 58.8% | 1/2 |
| R32 | 155 | Julian ReisterClay | 37 | Guillermo Garcia-LopezClay | 7-6(5) 6-2 | 3 | 107 | 2 | 2 | 67.1% | 72.5% | 48.0% | 8/10 |
| R32 | 32 | Marin CilicClay | 187 | Bastian KnittelClay | 6-3 6-7(4) 6-4 | 3 | 180 | 16 | 5 | 56.6% | 78.3% | 49.1% | 10/12 |
| R32 | 90 | Tobias KamkeClay | 21 | Juan Ignacio ChelaClay | 6-1 6-4 | 3 | 91 | 0 | 2 | 66.7% | 75.0% | 55.6% | 2/3 |
| R32 | 20 | Florian MayerClay | 117 | Marsel IlhanClay | 6-4 7-6(5) | 3 | 88 | 8 | 1 | 49.2% | 72.4% | 53.3% | 0/3 |
| R32 | 42 | Juan MonacoClay | 23 |  Janko TipsarevicClay | 6-2 6-4 | 3 | 95 | 4 | 1 | 70.6% | 80.6% | 66.7% | 4/4 |
| R32 | 43 | Philipp KohlschreiberClay | 49 | Albert MontanesClay | 6-1 3-2 RET | 3 | 46 | 5 | 1 | 54.8% | 76.5% | 78.6% | 0/0 |
| R32 | 14 | Nicolas AlmagroClay | 71 | Lukas RosolClay | 6-4 6-4 | 3 | 67 | 7 | 2 | 48.3% | 79.3% | 54.8% | 3/4 |
| R32 | 22 | Fernando VerdascoClay | 44 | Pablo AndujarClay | 6-2 6-3 | 3 | 86 | 1 | 2 | 80.4% | 51.1% | 54.5% | 3/7 |
| R32 | 168 | Cedrik-Marcel StebeClay | 29 | Nikolay DavydenkoClay | 6-3 7-6(5) | 3 | 112 | 5 | 0 | 59.8% | 65.3% | 42.4% | 6/9 |
| R32 | 38 | Fabio FogniniClay | 194 | Victor CrivoiClay | 6-1 7-5 | 3 | 81 | 6 | 2 | 76.8% | 69.8% | 46.2% | 4/6 |
| R32 | 12 |  Jurgen MelzerClay | 69 | Daniel Gimeno-TraverClay | 6-3 5-7 6-1 | 3 | 110 | 3 | 1 | 68.7% | 66.7% | 53.8% | 5/8 |
| R16 | 7 | Gael MonfilsClay | 57 | Radek StepanekClay | 6-4 6-4 | 3 | 83 | 10 | 3 | 54.5% | 75.0% | 53.3% | 5/6 |
| R16 | 18 | Gilles SimonClay | 55 | Jarkko NieminenClay | 7-6(4) 3-6 6-4 | 3 | 140 | 6 | 1 | 63.9% | 67.7% | 40.0% | 10/16 |
| R16 | 17 | Mikhail YouzhnyClay | 155 | Julian ReisterClay | 6-3 6-3 | 3 | 85 | 1 | 0 | 63.3% | 87.1% | 66.7% | 0/0 |
| R16 | 32 | Marin CilicClay | 90 | Tobias KamkeClay | 3-6 6-3 6-2 | 3 | 124 | 7 | 3 | 56.5% | 72.9% | 51.4% | 2/4 |
| R16 | 20 | Florian MayerClay | 42 | Juan MonacoClay | 7-5 7-5 | 3 | 108 | 1 | 2 | 65.8% | 63.5% | 51.9% | 4/7 |
| R16 | 14 | Nicolas AlmagroClay | 43 | Philipp KohlschreiberClay | 6-3 7-5 | 3 | 85 | 7 | 1 | 63.0% | 82.4% | 65.0% | 0/1 |
| R16 | 22 | Fernando VerdascoClay | 168 | Cedrik-Marcel StebeClay | 7-5 6-2 | 3 | 93 | 2 | 2 | 87.7% | 70.0% | 28.6% | 1/3 |
| R16 | 12 | Jurgen MelzerClay | 38 | Fabio FogniniClay | 6-2 6-3 | 3 | 71 | 0 | 0 | 71.4% | 71.4% | 57.1% | 0/0 |
| QF | 18 | Gilles SimonClay | 7 | Gael MonfilsClay | 6-4 3-6 6-0 | 3 | 125 | 2 | 0 | 63.2% | 69.1% | 46.9% | 4/6 |
| QF | 17 | Mikhail YouzhnyClay | 32 | Marin CilicClay | 4-6 6-3 7-6(6) | 3 | 181 | 2 | 2 | 65.8% | 64.6% | 51.2% | 2/5 |
| QF | 14 | Nicolas AlmagroClay | 20 | Florian MayerClay | 7-6(5) 7-6(3) | 3 | 108 | 13 | 1 | 70.9% | 67.2% | 64.0% | 0/1 |
| QF | 22 | Fernando VerdascoClay | 12 | Jurgen MelzerClay | 6-3 2-6 6-4 | 3 | 129 | 1 | 1 | 85.7% | 55.1% | 69.2% | 8/12 |
| SF | 18 | Gilles SimonClay | 17 | Mikhail YouzhnyClay | 3-6 6-3 6-1 | 3 | 124 | 6 | 2 | 61.0% | 70.0% | 43.8% | 10/13 |
| SF | 14 | Nicolas AlmagroClay | 22 | Fernando VerdascoClay | 6-4 6-1 | 3 | 84 | 7 | 0 | 70.0% | 82.9% | 60.0% | 1/1 |
| F | 18 | Gilles SimonClay | 14 | Nicolas AlmagroClay | 6-4 4-6 6-4 | 3 | 158 | 6 | 1 | 58.9% | 68.5% | 45.1% | 15/18 |
